Bipolar patterning of conducting polymers by electrochemical doping and reaction

Angewandte Chemie - International Edition

Volumn 49, Issue 52, 2010, Pages 10136-10139

  Inagi, Shinsuke ^a   Ishiguro, Yutaka ^a   Atobe, Mahito ^a   Fuchigami, Toshio ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

conducting materials; doping; electrochemistry; polymers; thin films

Indexed keywords

BIPOLAR ELECTRODES; COMPOSITION GRADIENT; CONDUCTING MATERIALS; DOPING; ELECTROCHEMICAL DOPING; POLY (3-METHYLTHIOPHENE); POTENTIAL GRADIENTS; PT FILMS; SUPPORTING ELECTROLYTE;

CONDUCTING POLYMERS; DOPING (ADDITIVES); ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; ORGANIC CONDUCTORS; PHOTOGRAPHY; THIN FILMS;

CONDUCTIVE FILMS;

EID: 78650499330     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201005671     Document Type: Article

References (33)

1. A. Arora, J. C. T. Eijkel, W. E. Morf, A. Manz, Anal. Chem. 2001, 73, 3282-3288
2. W. Zhan, J. Alvarez, R. M. Crooks, J. Am. Chem. Soc. 2002, 124, 13265-13270
3. K. F. Chow, F. Mavré, R. M. Crooks, J. Am. Chem. Soc. 2008, 130, 7544-7545
4. F. Mavré, K. F. Chow, E. Sheridan, B. Y. Chang, J. A. Crooks, R. M. Crooks, Anal. Chem. 2009, 81, 6218-6225.
5. C. Ulrich, O. Andersson, L. Nyholm, F. Björefors, Angew. Chem. 2008, 120, 3076-3078
6. Angew. Chem. Int. Ed. 2008, 47, 3034-3036
7. C. Ulrich, O. Andersson, L. Nyholm, F. Björefors, Anal. Chem. 2009, 81, 453-459.
8. R. Terrill, K. Balss, Y. Zhang, P. W. Bohn, J. Am. Chem. Soc. 2000, 122, 988-989
9. K. M. Balss, B. D. Coleman, C. H. Lansford, R. T. Haasch, P. W. Bohn, J. Phys. Chem. B 2001, 105, 8970-8978
10. X. Wang, P. W. Bohn, J. Am. Chem. Soc. 2004, 126, 6825-6832
11. S. Jayaraman, A. C. Hillier, Langmuir 2001, 17, 7857-7864.
12. J. Bradley, Z. Ma, Angew. Chem. 1999, 111, 1768-1771
13. Angew. Chem. Int. Ed. 1999, 38, 1663-1666
14. J. Bradley, S. Babu, P. Ndungu, Fullerenes Nanotubes Carbon Nanostruct. 2005, 13, 227-237
15. J. Bradley, H. Chen, J. Crawford, J. Eckert, K. Ernazarova, T. Kurzeja, M. Lin, M. McGee, W. Nadler, S. Stephens, Nature 1997, 389, 268-271
16. C. Warakulwit, T. Nguyen, J. Majimel, M. Delville, V. Lapeyre, P. Garrigue, V. Ravaine, J. Limtrakul, A. Kuhn, Nano Lett. 2008, 8, 500-504
17. S. Ramakrishnan, C. Shannon, Langmuir 2010, 26, 4602-4606.
18. S. Morgenthaler, C. Zink, N. D. Spencer, Soft Matter 2008, 4, 419-434
19. J. Genzer, R. R. Bhat, Langmuir 2008, 24, 2294-2317.
20. For books and recent reviews in this area, see for example Encyclopedia of Electrochemistry, Vol. 8 (Eds.:, A. J. Bard, M. Stratmann, H. J. Schäfer,), Wiley-VCH, Weinheim, 2004
21. Organic Electrochemistry, 4 th ed., (Eds.: H. Lund, O. Hammerich,), Marcel Dekker, New York, 2001
22. J. B. Sperry, D. J. Wright, Chem. Soc. Rev. 2006, 35, 605-621
23. J. Yoshida, K. Kataoka, R. Horcajada, A. Nagaki, Chem. Rev. 2008, 108, 2265-2299.
24. S. Inagi, S. Hayashi, T. Fuchigami, Chem. Commun. 2009, 1718-1720
25. S. Hayashi, S. Inagi, T. Fuchigami, Macromolecules 2009, 42, 3755-3760
26. S. Hayashi, S. Inagi, T. Fuchigami, Electrochemistry 2010, 78, 114-117.
27. S. Inagi, S. Hayashi, K. Hosaka, T. Fuchigami, Macromolecules 2009, 42, 3881-3883
28. S. Hayashi, S. Inagi, K. Hosaka, T. Fuchigami, Synth. Met. 2009, 159, 1792-1795
29. S. Inagi, K. Hosaka, S. Hayashi, T. Fuchigami, J. Electrochem. Soc. 2010, 157, E 88 -E 91.
30. Z. Qi, N. G. Rees, P. G. Pickup, Chem. Mater. 1996, 8, 701-707
31. P. Soudan, P. Lucas, L. Breau, D. Bélanger, Langmuir 2000, 16, 4362-4366.
32. P. M. Beaujuge, J. R. Reynolds, Chem. Rev. 2010, 110, 268-320.
33. The anodically doped PT film was stable and kept its charged state and the dopant, even when rinsed with acetonitrile under open-circuit conditions. The PT film could also be cathodically doped at the cathodic side on the bipolar electrode; however, no color change was observed during electrolysis. The main reaction at the cathodic side on the bipolar electrode is probably reduction of a trace of contaminating water.