InCl3/CyNH2 cocatalyzed carbocyclization reaction: An entry to α-disubstituted exo -methylene cyclopentanes

Journal of Organic Chemistry

Volumn 75, Issue 23, 2010, Pages 8322-8325

  Montaignac, Benjamin ^a   Vitale, Maxime R ^a   Ratovelomanana Vidal, Virginie ^a   Michelet, Véronique ^a  

^a PSL RESEARCH UNIVERSITY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOCYCLIZATION REACTIONS; COCATALYST; COOPERATIVE CATALYTIC SYSTEMS; FUNCTIONALIZED; MECHANISTIC STUDIES; SYNTHETIC APPROACH;

ACETYLENE;

ORGANIC COMPOUNDS;

ALKYNE DERIVATIVE; AMINE; CARBENE; CYCLOPENTANE DERIVATIVE; INDIUM;

ARTICLE; CARBOCYCLIZATION; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CYCLIZATION; METALLATION; MOLECULAR MECHANICS; SUBSTITUTION REACTION; SYNTHESIS;

EID: 78650298803     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1018552     Document Type: Article

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35. Alkene geometry was determined by NOESY NMR experiments. Please see the Supporting Information for more details.
36. 3. Thus, the scrambling may result from an acid-base equilibrium.