메뉴 건너뛰기




Volumn 83, Issue 3, 2011, Pages 1285-1292

Expedient, accurate methods for the determination of the degree of substitution of cellulose carboxylic esters: Application of UV-vis spectroscopy (dye solvatochromism) and FTIR

Author keywords

Cellulose esters; Degree of substitution; DRIFTS; FTIR; Solvatochromic probes; Solvatochromism; UV vis spectroscopy

Indexed keywords

CELLULOSE ESTERS; DEGREE OF SUBSTITUTION; DRIFTS; FTIR; SOLVATOCHROMIC PROBES; SOLVATOCHROMISMS; UV-VIS SPECTROSCOPY;

EID: 78650271338     PISSN: 01448617     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbpol.2010.09.035     Document Type: Article
Times cited : (25)

References (41)
  • 1
    • 0034499168 scopus 로고    scopus 로고
    • Vibrational stark effects of nitriles I. Methods and experimental results
    • DOI 10.1021/jp002242r
    • S.S. Andrews, and S.G. Boxer Vibrational stark effects of nitriles I. Methods and experimental results Journal of Physical Chemistry A 104 2000 11853 11863 (Pubitemid 32036159)
    • (2000) Journal of Physical Chemistry A , vol.104 , Issue.51 , pp. 11853-11863
    • Andrews, S.S.1    Boxer, S.G.2
  • 5
    • 0034853064 scopus 로고    scopus 로고
    • Development of NMR and Raman spectroscopic methods for the determination of the degree of substitution of maleate in modified starches
    • C.K. Chong, J. Xing, D.L. Phillips, and H. Corke Development of NMR and Raman spectroscopic methods for the determination of the degree of substitution of maleate in modified starches Journal of Agricultural and Food Chemistry 49 2001 2702 2708 (Pubitemid 32826056)
    • (2001) Journal of Agricultural and Food Chemistry , vol.49 , Issue.6 , pp. 2702-2708
    • Chong, C.K.1    Xing, J.2    Phillips, D.L.3    Corke, H.4
  • 6
    • 0002719381 scopus 로고
    • Diffuse reflectance infrared spectroscopy: Sampling techniques for qualitative/quantitative analysis of solids
    • S.R. Culler Diffuse reflectance infrared spectroscopy: Sampling techniques for qualitative/quantitative analysis of solids P.B. Coleman, Practical sampling techniques for infrared analysis 1993 CRC Press Boca Raton 93 105
    • (1993) Practical Sampling Techniques for Infrared Analysis , pp. 93-105
    • Culler, S.R.1
  • 8
    • 60649106227 scopus 로고    scopus 로고
    • Ionic-liquid-based method to determine the degree of esterification in cellulose fibers
    • P. Dominguez de Maria, and A. Martinsson Ionic-liquid-based method to determine the degree of esterification in cellulose fibers Analyst 134 2009 493 496
    • (2009) Analyst , vol.134 , pp. 493-496
    • Dominguez De Maria, P.1    Martinsson, A.2
  • 9
    • 34250633574 scopus 로고    scopus 로고
    • Solvation in pure and mixed solvents: Some recent developments
    • O.A. El Seoud Solvation in pure and mixed solvents: Some recent developments Pure and Applied Chemistry 79 2007 1135 1151
    • (2007) Pure and Applied Chemistry , vol.79 , pp. 1135-1151
    • El Seoud, O.A.1
  • 11
    • 77953532177 scopus 로고    scopus 로고
    • Surface properties of calcinated titanium dioxide probed by solvatochromic indicators: Relevance to catalytic applications
    • O.A. El Seoud, A.R. Ramadan, B.M. Sato, and P.A.R. Pires Surface properties of calcinated titanium dioxide probed by solvatochromic indicators: Relevance to catalytic applications Journal of Physical Chemistry C 114 2010 10436 10443
    • (2010) Journal of Physical Chemistry C , vol.114 , pp. 10436-10443
    • El Seoud, O.A.1    Ramadan, A.R.2    Sato, B.M.3    Pires, P.A.R.4
  • 12
    • 0002493110 scopus 로고
    • Possibilities and limits of FTIR spectroscopy in characterization of cellulose. Part 1. Comparison of various cellulose fibers and bacterial cellulose
    • D. Fengel, and M. Ludwig Possibilities and limits of FTIR spectroscopy in characterization of cellulose. Part 1. Comparison of various cellulose fibers and bacterial cellulose Papier 45 1991 45 51
    • (1991) Papier , vol.45 , pp. 45-51
    • Fengel, D.1    Ludwig, M.2
  • 13
    • 70049086601 scopus 로고    scopus 로고
    • Application of 1-allyl-3-(1-butyl)imidazolium chloride in the synthesis of cellulose esters: Properties of the ionic liquid, and comparison with other solvents
    • L.C. Fidale, S. Possidonio, and O.A. El Seoud Application of 1-allyl-3-(1-butyl)imidazolium chloride in the synthesis of cellulose esters: Properties of the ionic liquid, and comparison with other solvents Macromolecular Bioscience 9 2009 813 821
    • (2009) Macromolecular Bioscience , vol.9 , pp. 813-821
    • Fidale, L.C.1    Possidonio, S.2    El Seoud, O.A.3
  • 14
    • 0038038282 scopus 로고    scopus 로고
    • Probing the polarity of various cellulose derivatives with genuine solvatochromic indicators
    • K. Fischer, T. Heinze, and S. Spange Probing the polarity of various cellulose derivatives with genuine solvatochromic indicators Macromolecular Chemistry and Physics 204 2003 1315 1322
    • (2003) Macromolecular Chemistry and Physics , vol.204 , pp. 1315-1322
    • Fischer, K.1    Heinze, T.2    Spange, S.3
  • 16
    • 0036320679 scopus 로고    scopus 로고
    • Probing the surface polarity of native cellulose using genuine solvatochromic dyes
    • DOI 10.1023/A:1015896629947
    • K. Fischer, S. Spange, S. Fischer, C. Bellmann, and A. Joerg Probing the surface polarity of native celluloses using genuine solvatochromic dyes Cellulose 9 2002 31 40 (Pubitemid 34817267)
    • (2002) Cellulose , vol.9 , Issue.1 , pp. 31-40
    • Fischer, K.1    Spange, S.2    Fischer, S.3    Bellmann, C.4    Adams, J.5
  • 17
    • 0018032338 scopus 로고
    • Diffuse reflectance measurements by infrared Fourier transform spectrometry
    • M.P. Fuller, and P.R. Griffiths Diffuse reflectance measurements by infrared Fourier transform spectrometry Analytical Chemistry 50 1978 1906 1910
    • (1978) Analytical Chemistry , vol.50 , pp. 1906-1910
    • Fuller, M.P.1    Griffiths, P.R.2
  • 18
    • 0035506023 scopus 로고    scopus 로고
    • Unconventional methods in cellulose functionalization
    • DOI 10.1016/S0079-6700(01)00022-3, PII S0079670001000223
    • T. Heinze, and T. Liebert Unconventional methods in cellulose functionalization Progress in Polymer Science 26 2001 1689 1762 (Pubitemid 33089086)
    • (2001) Progress in Polymer Science (Oxford) , vol.26 , Issue.9 , pp. 1689-1762
    • Heinze, T.1    Liebert, T.2
  • 20
    • 0024556004 scopus 로고
    • T(33), a solvatochromic polarity and micellar probe for neutral aqueous solutions
    • T(33), a solvatochromic polarity and micellar probe for neutral aqueous solutions Chemistry and Physics of Lipids 50 1989 51 60
    • (1989) Chemistry and Physics of Lipids , vol.50 , pp. 51-60
    • Kessler, M.A.1    Wolfbeis, O.S.2
  • 21
    • 0024131770 scopus 로고
    • Determination of the distribution of the substituent group in cellulose acetate by full assignment of all carbonyl carbon peaks of carbon-13 (proton-decoupled) NMR spectra
    • K. Kowsaka, K. Okajima, and K. Kamide Determination of the distribution of the substituent group in cellulose acetate by full assignment of all carbonyl carbon peaks of carbon-13 (proton-decoupled) NMR spectra Polymer Journal 20 1988 827 836
    • (1988) Polymer Journal , vol.20 , pp. 827-836
    • Kowsaka, K.1    Okajima, K.2    Kamide, K.3
  • 22
    • 4644355337 scopus 로고
    • Determination of the degree of substitution in highly substituted cellulose esters (acetates)
    • A.N. Krasovskii, D.N. Polyakov, and S.S. Mnatsakanov Determination of the degree of substitution in highly substituted cellulose esters (acetates) Russian Journal of Applied Chemistry 66 1993 918 924
    • (1993) Russian Journal of Applied Chemistry , vol.66 , pp. 918-924
    • Krasovskii, A.N.1    Polyakov, D.N.2    Mnatsakanov, S.S.3
  • 23
    • 0033452603 scopus 로고    scopus 로고
    • Role of hydrophobic effects in mechanistic QSAR
    • DOI 10.1023/A:1008762321231
    • A.J. Leo, and C. Hansch Role of hydrophobic effects in mechanistic QSAR Perspectives in Drug Discovery and Design 17 1999 1 25 (Pubitemid 30043049)
    • (1999) Perspectives in Drug Discovery and Design , vol.17 , pp. 1-25
    • Leo, A.J.1    Hansch, C.2
  • 24
    • 0000640464 scopus 로고
    • Infrared spectra of crystalline polysaccharides. I. Hydrogen bonds in native celluloses
    • C.Y. Liang, and R.H. Marchessault Infrared spectra of crystalline polysaccharides. I. Hydrogen bonds in native celluloses Journal of Polymer Science 37 1959 385 395
    • (1959) Journal of Polymer Science , vol.37 , pp. 385-395
    • Liang, C.Y.1    Marchessault, R.H.2
  • 26
    • 0001262052 scopus 로고
    • Infrared spectra of crystalline polysaccharides. III. Mercerized cellulose
    • R.H. Marchessault, and C.Y. Liang Infrared spectra of crystalline polysaccharides. III. Mercerized cellulose Journal of Polymer Science 43 1960 71 84
    • (1960) Journal of Polymer Science , vol.43 , pp. 71-84
    • Marchessault, R.H.1    Liang, C.Y.2
  • 27
    • 0033312451 scopus 로고    scopus 로고
    • A novel, efficient procedure for acylation of cellulose under homogeneous solution conditions
    • G.A. Marson, and O.A. El Seoud A novel, efficient procedure for acylation of cellulose under homogeneous solution conditions Journal of Applied Polymer Science 74 1999 1355 1360
    • (1999) Journal of Applied Polymer Science , vol.74 , pp. 1355-1360
    • Marson, G.A.1    El Seoud, O.A.2
  • 28
    • 33845215914 scopus 로고    scopus 로고
    • Thermosolvatochromism of merocyanine polarity indicators in pure and aqueous solvents: Relevance of solvent lipophilicity
    • C.T. Martins, M.S. Lima, and O.A. El Seoud Thermosolvatochromism of merocyanine polarity indicators in pure and aqueous solvents: Relevance of solvent lipophilicity Journal of Organic Chemistry 71 2006 9068 9079
    • (2006) Journal of Organic Chemistry , vol.71 , pp. 9068-9079
    • Martins, C.T.1    Lima, M.S.2    El Seoud, O.A.3
  • 29
    • 33947462858 scopus 로고
    • Infrared spectrophotometric procedure for analysis of cellulose and modified cellulose
    • R.T. O'Connor, E.F. DuPre, and E.R. McCall Infrared spectrophotometric procedure for analysis of cellulose and modified cellulose Analytical Chemistry 29 1957 998 1005
    • (1957) Analytical Chemistry , vol.29 , pp. 998-1005
    • O'Connor, R.T.1    Dupre, E.F.2    McCall, E.R.3
  • 33
    • 7644244313 scopus 로고    scopus 로고
    • Pyridinium N-phenoxide betaine dyes and their application to the determination of solvent polarities. Part XXVIII
    • C. Reichardt Pyridinium N-phenoxide betaine dyes and their application to the determination of solvent polarities. Part XXVIII Pure and Applied Chemistry 76 2004 1903 1919
    • (2004) Pure and Applied Chemistry , vol.76 , pp. 1903-1919
    • Reichardt, C.1
  • 34
    • 49149126732 scopus 로고    scopus 로고
    • Pyridinium N-phenoxide betaine dyes and their application to the determination of solvent polarities. Part XXX. Pyridinium-N-phenolate betaine dyes as empirical indicators of solvent polarity: Some new findings
    • C. Reichardt Pyridinium N-phenoxide betaine dyes and their application to the determination of solvent polarities. Part XXX. Pyridinium-N-phenolate betaine dyes as empirical indicators of solvent polarity: Some new findings Pure and Applied Chemistry 80 2008 1415 1432
    • (2008) Pure and Applied Chemistry , vol.80 , pp. 1415-1432
    • Reichardt, C.1
  • 35
    • 0031171327 scopus 로고    scopus 로고
    • Preparation, characterization and biodegradation studies on cellulose acetates with varying degrees of substitution
    • DOI 10.1016/S0032-3861(96)00868-3, PII S0032386196008683
    • E. Samios, R.K. Dart, and J.V. Dawkins Preparation, characterization and biodegradation studies on cellulose acetates with varying degrees of substitution Polymer 38 1997 3045 3054 (Pubitemid 27437372)
    • (1997) Polymer , vol.38 , Issue.12 , pp. 3045-3054
    • Samios, E.1    Dart, R.K.2    Dawkins, J.V.3
  • 36
    • 0013585450 scopus 로고
    • Thermochemical estimation of destabilization energies of 1,2-, 1,3- and 1,4-dicyanobenzenes due to interactions between substituents. Appendix: Dipole moments in solution of the dicyanobenzenes
    • T. Sato-Toshima, M. Sakiyama, and S. Seki Thermochemical estimation of destabilization energies of 1,2-, 1,3- and 1,4-dicyanobenzenes due to interactions between substituents. Appendix: Dipole moments in solution of the dicyanobenzenes Bulletin of the Chemical Society of Japan 53 1980 2762 2767
    • (1980) Bulletin of the Chemical Society of Japan , vol.53 , pp. 2762-2767
    • Sato-Toshima, T.1    Sakiyama, M.2    Seki, S.3
  • 37
    • 0035916329 scopus 로고    scopus 로고
    • Enzymatic acylation of hydroxypropyl cellulose in organic media and determination of ester formation by Diffuse Reflectance Infrared Fourier Transform (DRIFT) spectroscopy
    • DOI 10.1002/1097-0290(20010220)72:4<495::AID-BIT1012>3.0.CO;2-T
    • V. Sereti, H. Stamatis, C. Pappas, M. Polissiou, and F.N. Kolisis Enzymatic acylation of hydroxypropyl cellulose in organic media and determination of ester formation by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy Biotechnology and Bioengineering 72 2001 495 500 (Pubitemid 32142451)
    • (2001) Biotechnology and Bioengineering , vol.72 , Issue.4 , pp. 495-500
    • Sereti, V.1    Stamatis, H.2    Pappas, C.3    Polissiou, M.4    Kolisis Biotechnology Laboratory, F.N.5
  • 39
    • 0000307251 scopus 로고    scopus 로고
    • Solvatochromism in pure and binary solvent mixtures: Effects of the molecular structure of the zwitterionic probe
    • E.B. Tada, L.P. Novaki, and O.A. El Seoud Solvatochromism in pure and binary solvent mixtures: Effects of the molecular structure of the zwitterionic probe Journal of Physical Organic Chemistry 13 2000 679 687
    • (2000) Journal of Physical Organic Chemistry , vol.13 , pp. 679-687
    • Tada, E.B.1    Novaki, L.P.2    El Seoud, O.A.3
  • 40
    • 0001518698 scopus 로고
    • Infrared spectrum and crystal structure of cellulose
    • M. Tsuboi Infrared spectrum and crystal structure of cellulose Journal of Polymer Science 25 1957 159 171
    • (1957) Journal of Polymer Science , vol.25 , pp. 159-171
    • Tsuboi, M.1
  • 41
    • 0030173689 scopus 로고    scopus 로고
    • Infrared spectroscopy studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. II. Comparison of different polycarboxylic acids
    • C.Q. Yang, and X. Wang Infrared spectroscopy studies of the cyclic anhydride as the intermediate for the ester crosslinking of cotton cellulose by polycarboxylic acids. II. Comparison of different polycarboxylic acids Journal of Polymer Science, Part A: Polymer Chemistry 34 1996 1573 1580 (Pubitemid 126556488)
    • (1996) Journal of Polymer Science, Part A: Polymer Chemistry , vol.34 , Issue.8 , pp. 1573-1580
    • Yang, C.Q.1    Wang, X.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.