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Volumn 80, Issue 7, 2008, Pages 1415-1432

Pyridinium-N-phenolate betaine dyes as empirical indicators of solvent polarity: Some new findings

Author keywords

Betaine dye; Perichromism; Solvatochromism; Solvent polarity; Solvent polarity parameters; Thermochromism

Indexed keywords


EID: 49149126732     PISSN: 00334545     EISSN: None     Source Type: Journal    
DOI: 10.1351/pac200880071415     Document Type: Conference Paper
Times cited : (140)

References (148)
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    • E. M. Kosower, Tel Aviv University, Tel Aviv/Israel; private communication to C. R.; see also ref. [12b].
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    • P. Rao. Resonance (Indian Academy of Sciences, Bangalore) 2, 69 (1997), title page of the May issue;
    • (e) P. Rao. Resonance (Indian Academy of Sciences, Bangalore) 2, 69 (1997), title page of the May issue;
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    • for X-ray structure determinations of other pyridinium-N-phenolate betaine dyes, see (b) K. Stadnicka, P. Milart, A. Olech, P. K. Olszewski. J. Mol. Struct. 604, 9 (2002);
    • for X-ray structure determinations of other pyridinium-N-phenolate betaine dyes, see (b) K. Stadnicka, P. Milart, A. Olech, P. K. Olszewski. J. Mol. Struct. 604, 9 (2002);
  • 52
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    • For another recent calculation of the solvatochromism of betaine dye 1 by means of the DFT and COSMO method, see (b) A. Masternak, G. Wenska, J. Milecki, B. Skalski, St. Franzen. J. Phys. Chem. A 109, 759 (2005), particularly the Supporting Information.
    • For another recent calculation of the solvatochromism of betaine dye 1 by means of the DFT and COSMO method, see (b) A. Masternak, G. Wenska, J. Milecki, B. Skalski, St. Franzen. J. Phys. Chem. A 109, 759 (2005), particularly the Supporting Information.
  • 72
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    • Betaine dyes 1 and 4 are commercially available by Sigma-Aldrich (1: order no. 27,244-2) and Fluka (1: order no. 43358; 4: order no. 36567).
    • Betaine dyes 1 and 4 are commercially available by Sigma-Aldrich (1: order no. 27,244-2) and Fluka (1: order no. 43358; 4: order no. 36567).
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    • C. Reichardt. In Molecular Interactions, 3, p. 241ff., Table 5.4, H. Ratajczak, W. J. Orville-Thomas (Eds.) Wiley-Interscience, Chichester (1982).
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    • alcohols/formamides Part 8 of a series of papers dealing with the polarity of binary solvent mixtures
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    • C. Koopmans, H. Ritter. J. Am. Chem. Soc. 129, 3502 2007, the polymer-bound solvatochromic pyridinium-phenolate dye described in this paper is in fact not Reichardt's dye but is rather Brooker's merocyanine dye
    • C. Koopmans, H. Ritter. J. Am. Chem. Soc. 129, 3502 (2007); the polymer-bound solvatochromic pyridinium-phenolate dye described in this paper is in fact not "Reichardt's dye" but is rather "Brooker's merocyanine dye".


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