Enhancing the blocking temperature in single-molecule magnets by incorporating 3d-5d exchange interactions

Chemistry - A European Journal

Volumn 16, Issue 45, 2010, Pages 13458-13464

  Pedersen, Kasper S ^a   Schau Magnussen, Magnus ^a   Bendix, Jesper ^a   Weihe, Høgni ^a   Palii, Andrei V ^b   Klokishner, Sophia I ^b   Ostrovsky, Serghei ^b   Reu, Oleg S ^b   Mutka, Hannu ^c   Tregenna Piggott, Philip L W ^d  

^a UNIVERSITY OF COPENHAGEN   (Denmark)

^b INSTITUTE OF APPLIED PHYSICS   (Moldova)

^c INSTITUT LAUE LANGEVIN   (France)

^d PAUL SCHERRER INSTITUTE   (Switzerland)

Author keywords

anisotropy; magnetic properties; manganese; osmium; single molecule magnets

Indexed keywords

ALTERNATING CURRENT; ANISOTROPIC EXCHANGE INTERACTION; ARRHENIUS EXPRESSIONS; BLOCKING TEMPERATURE; BOLTZMANN CONSTANTS; FREQUENCY-DEPENDENT; INELASTIC NEUTRONS; IRON AGE; ISOSTRUCTURAL; KRAMERS DOUBLET; MAGNETIC ORBITALS; ORBITAL ANGULAR MOMENTUM; ORBITAL CONTRIBUTION; OUT OF PHASE; SINGLE ION ANISOTROPY; SINGLE-MOLECULE MAGNET; SPIN-ORBIT COUPLINGS; THEORETICAL PREDICTION;

CRYSTALLOGRAPHY; CYANIDES; ELECTRONIC EQUIPMENT MANUFACTURE; EXCHANGE INTERACTIONS; IONS; MAGNETIC ANISOTROPY; MAGNETIC SUSCEPTIBILITY; MAGNETS; MANGANESE; MOLECULES; SINGLE CRYSTALS;

OSMIUM;

EID: 78649850484     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001259     Document Type: Article

References (46)

1. G. S. Girolami, W. R. Entley, Science 1995, 268, 397-400.
2. D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278-309
3. Angew. Chem. Int. Ed. 2003, 42, 268-297.
4. R. Sessoli, D. Gatteschi, A. Caneschi, M. A. Novak, Nature 1993, 365, 141-143.
5. M. N. Leuenberger, D. Loss, Nature 2001, 410, 789-793.
6. O. Waldmann, Inorg. Chem. 2007, 46, 10035-10037.
7. C. P. Berlinguette, D. Vaughn, C. Cañada-Vilalta, J.-R. Galán-Mascarós, K. R. Dunbar, Angew. Chem. 2003, 115, 1561-1564
8. Angew. Chem. Int. Ed. 2003, 42, 1523-1526.
9. A. V. Palii, S. M. Ostrovsky, S. I. Klokishner, B. S. Tsukerblat, C. S. Berlinguette, K. R. Dunbar, J. R. Galan-Mascaros, J. Am. Chem. Soc. 2004, 126, 16860-16867.
10. B. S. Tsukerblat, A. V. Palii, S. M. Ostrovsky, S. V. Kunitsky, S. I. Klokishner, K. R. Dunbar, J. Chem. Theory Comput. 2005, 1, 668-673.
11. A. V. Palii, S. M. Ostrovsky, S. I. Klokishner, B. S. Tsukerblat, K. R. Dunbar, ChemPhysChem 2006, 7, 871-879.
12. M. Atanasov, C. Busche, F. Ela Hallah, B. Martin, G. Rajaraman, J. vana Slageren, H. Wadepohl, Inorg. Chem. 2008, 47, 8112-8125.
13. N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 2003, 125, 8694-8695.
14. N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, Y. Kaizu, J. Phys. Chem. B 2004, 108, 11265-11271.
15. N. Ishikawa, M. Sugita, W. Wernsdorfer, J. Am. Chem. Soc. 2005, 127, 3650-3651.
16. N. Ishikawa, M. Sugita, W. Wernsdorfer, Angew. Chem. 2005, 117, 2991-2995
17. Angew. Chem. Int. Ed. 2005, 44, 2931-2935.
18. M. A. AlDamen, J. M. Clemente-Juan, E. Coronado, C. Martí- Gastaldo, A. Gaita-Ariño, J. Am. Chem. Soc. 2008, 130, 8874-8875.
19. M. A. AlDamen, S. Cordona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Arino, C. Marti-Gastaldo, F. Luis, O. Montero, Inorg. Chem. 2009, 48, 3467-3479.
20. S. Osa, T. Kido, N. Matsumoto, N. Re, A. Pochaba, J. Mrozinski, J. Am. Chem. Soc. 2004, 126, 420-421.
21. S. I. Klokishner, S. M. Ostrovsky, O. S. Reu, A. V. Palii, P. L. W. Tregenna-Piggott, T. Brock-Nannestad, J. Bendix, H. Mutka, J. Phys. Chem. C 2009, 113, 8573-8582.
22. J. Bendix, P. Steenberg, I. Søtofte, Inorg. Chem. 2003, 42, 4510-4512.
23. E. J. Schelter, A. V. Prosvirin, K. R. Dunbar, J. Am. Chem. Soc. 2004, 126, 15004-15005.
24. A. V. Palii, S. M. Ostrovsky, S. I. Klokishner, B. Tsukerblat, E. J. Schelter, A. V. Prosvirin, K. R. Dunbar, Inorg. Chim. Acta 2007, 360, 3915-3923.
25. E. J. Schelter, F. Karadas, C. Avendano, A. V. Prosvirin, W. Wernsdorfer, K. R. Dunbar, J. Am. Chem. Soc. 2007, 129, 8139-8149.
26. D. E. Freedman, D. M. Jenkins, A. T. Iavarone, J. R. Long, J. Am. Chem. Soc. 2008, 130, 2884-2885.
27. Y. Song, P. Zhang, X.-M. Ren, X.-F. Shen, Y.-Z. Li, X.-Z. You, J. Am. Chem. Soc. 2005, 127, 3708-3709.
28. J. H. Yoon, J. H. Lim, H. C. Kim, C. S. Hong, Inorg. Chem. 2006, 45, 9613-9615.
29. J. J. Sokol, A. G. Hee, J. R. Long, J. Am. Chem. Soc. 2002, 124, 7656-7657.
30. P. Albores, L. P. Slep, L. M. Baraldo, R. Baggio, M. T. Garland, E. Rentschler, Inorg. Chem. 2006, 45, 2361-2363.
31. V. S. Mironov, Dokl. Phys. Chem. 2007, 415, 199-204.
32. M. Hilfiger, M. Shatruk, A. Prosvirin, K. R. Dunbar, Chem. Commun. 2008, 44, 5752-5754.
33. M. G. Hilfiger, M. Chen, T. V. Brinzari, T. M. Nocera, M. Shatruk, D. T. Petasis, J. L. Musfeldt, C. Achim, K. R. Dunbar, Angew. Chem. 2010, 122, 1410-1413.
34. A. V. Palii, O. S. Reu, S. M. Ostrovsky, S. I. Klokishner, B. Tsukerblat, M. Hilfiger, M. Shatruk, A. Prosvirin, K. R. Dunbar, J. Phys. Chem. A 2009, 113, 6886-6890.
35. H. Miyasaka, N. Matsumoto, H. Ökawa, N. Re, E. Gallo, C. Floriani, J. Am. Chem. Soc. 1996, 118, 981-994.
36. H. J. Choi, J. J. Sokol, J. R. Long, Inorg. Chem. 2004, 43, 1606-1608.
37. P. L. W. Tregenna-Piggott, D. Sheptyakov, L. Keller, S. I. Klokishner, S. M. Ostrovsky, A. V. Palii, O. S. Reu, J. Bendix, T. Brock-Nannestad, K. Pedersen, H. Weihe, H. Mutka, Inorg. Chem. 2009, 48, 128-134.
38. M. Ferbinteanu, H. Miyasaka, W. Wernsdorfer, K. Nakata, K.-i. Sugiura, M. M. Yamashita, C. Coulon, R. Clérac, J. Am. Chem. Soc. 2005, 127, 3090-3099.
39. J. S. Griffith, The Theory of Transition-Metal Ions, Cambridge University Press, Cambridge, 1961, p. 365.
40. P. L. W. Tregenna-Piggott, Available in the DAVE program suite.
41. Q. Scheifele, C. Riplinger, F. Neese, H. Weihe, A.-L. Barra, F. Juranyi, A. Podlesnyak, P. L. W. Tregenna-Piggott, Inorg. Chem. 2008, 47, 439-447.
42. J. Villain, F. Hartman-Boutron, R. Sessoli, A. Rettori, Europhys. Lett. 1994, 27, 159.
43. Prepared by condensation of 2a equiv 5-bromosalicylic aldehyde with 1a equiv ethylenediamine in hot methanol.
44. P. Mascharak, Inorg. Chem. 1986, 25, 245-247.
45. G. M. Sheldrick, Acta Crystallogr. 2008, ## A64, 112-122.
46. R. Azuah, J. Copley, R. Dimeo, S. Park, S.-H. Lee, A. Munter, L. Kneller, Y. Qiu, I. Peral, C. Brown, P. Kienzle, P. L. W. Tregenna-Piggott, Dave 1.4 Beta. (http://www.ncnr.nist.gov/dave).