Magnetic anisotropy in the octanuclear Re4II Mn4II cluster exhibiting Single-Molecule Magnet behavior: Quantum-spin and classical-spin approaches

Inorganica Chimica Acta

Volumn 360, Issue 13, 2007, Pages 3915-3924

  Palii, A V ^a   Ostrovsky, S M ^a   Klokishner, S I ^a   Tsukerblat, B S ^b   Schelter, E J ^c   Prosvirin, A V ^c   Dunbar, K R ^c  

^a INSTITUTE OF CHEMISTRY   (Moldova)

^b BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

^c TEXAS A AND M UNIVERSITY   (United States)

Author keywords

Magnetic anisotropy; Single molecule magnets; Unquenched orbital angular momentum

Indexed keywords

HAMILTONIANS; IONS; MAGNETIC ANISOTROPY; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION REVERSAL; MAGNETS; MANGANESE COMPOUNDS; MOLECULES; SPIN ORBIT COUPLING; TEMPERATURE DISTRIBUTION;

DC MAGNETIC SUSCEPTIBILITY; FIRST ORDER EFFECT; MAGNETIZATION DATA; ORBITAL ANGULAR MOMENTUM; SINGLE-MOLECULE MAGNET; SPIN-ORBIT SPLITTINGS; TEMPERATURE DEPENDENCE; THEORETICAL MODELING;

RHENIUM COMPOUNDS;

EID: 34548478106     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2007.03.039     Document Type: Article

References (25)

1. Gatteschi D., and Sessoli R. Angew. Chem., Int. Ed. 42 (2003) 268
2. Christou G., Gatteschi D., Hendrickson D.N., and Sessoli R. MRS Bull. 25 (2000) 66
3. Aubin S.M.J., Wemple M.W., Adams D.M., Tsai H.-L., Christou G., and Hendrickson D.N. J. Am. Chem. Soc. 118 (1996) 7746
4. Barra A.L., De Brunner P., Gatteschi D., Schultz C.E., and Sessoli R. Europhys. Lett. 35 (1996) 133
5. Castro S.L., Sun Z., Grant C.M., Bollinger J.C., Hendrickson D.N., and Christou G. J. Am. Chem. Soc. 120 (1998) 2365
6. Andres H., Basler R., Güdel H.-U., Aromi G., Christou G., Büttner H., and Ruffle B. J. Am. Chem. Soc. 122 (2000) 12469
7. Brechin E.K., Soler M., Davidson J., Hendrickson D.N., Parsons S., and Christou G. Chem. Commun. (2002) 2252
8. Murrie M., Teat S.J., Stoeckli-Evans H., and Güdel H.U. Angew. Chem., Int. Ed. 42 (2003) 4653
9. Sokol J.J., Hee A.G., and Long J.R. J. Am. Chem. Soc. 124 (2002) 7656
10. Berlinguette C.P., Vaughn D., Cańada-Vilalta C., Galán-Mascarós J.-R., and Dunbar K.R. Angew. Chem., Int. Ed. 42 (2003) 1523
11. Choi H.J., Sokol J.J., and Long J.R. Inorg. Chem. 43 (2004) 1606
12. Palii A.V., Ostrovsky S.M., Klokishner S.I., Tsukerblat B.S., Berlinguette C.P., Dunbar K.R., and Galán-Mascarós J.R. J. Am. Chem. Soc. 126 (2004) 16860
13. Tsukerblat B.S., Palii A.V., Ostrovsky S.M., Kunitsky S.V., Klokishner S.I., and Dunbar K.R. J. Chem. Theory Comput. 1 (2005) 668
14. Schelter E.J., Prosvirin A.V., and Dunbar K.R. J. Am. Chem. Soc. 126 (2004) 15004
15. Coronado E., Drillon M., Nugteren P.R., de Jongh L.J., and Beltran D. J. Am. Chem. Soc. 110 (1988) 3907
16. Clemente J.M., Andres H., Aebersold M., Borrás-Almenar J.J., Coronado E., Güdel H.U., Büttner H., and Kearly G. Inorg. Chem. 36 (1997) 2244
17. Andres H., Aebersold M., Güdel H.U., Clemente J.M., Coronado E., Büttner H., Kearly G., and Zolliker M. Chem. Phys. Lett. 289 (1998) 224
18. Andres H., Clemente-Juan J.M., Aebersold M., Güdel H.U., Coronado E., Büttner H., Kearly G., Melero J., and Burriel R. J. Am. Chem. Soc. 121 (1999) 10028
19. Andres H., Clemente-Juan J.M., Basler R., Aebersold M., Güdel H.U., Borrás-Almenar J.J., Gaita A., Coronado E., Büttner H., and Janssen S. Inorg. Chem. 40 (2001) 1943
20. Palii A.V., Tsukerblat B.S., Coronado E., Clemente-Juan J.M., and Borrás-Almenar J.J. Inorg. Chem. 42 (2003) 2455
21. Palii A.V., Tsukerblat B.S., Coronado E., Clemente-Juan J.M., and Borrás-Almenar J.J. J. Chem. Phys. 118 (2003) 5566
22. Palii A.V., Ostrovsky S.M., Klokishner S.I., Reu O.S., Sun Z.-M., Prosvirin A.V., Zhao H.-H., Mao J.-G., and Dunbar K.R. J. Phys. Chem. A 110 (2006) 14003
23. Varshalovich D.A., Moskalev A.N., and Khersonskii V.K. Quantum Theory of Angular Momentum (1988), World Scientific, Singapore
24. Georges R., Borrás-Almenar J.J., Coronado E., Curély J., and Drillon M. One-dimensional magnetism: an overview of the models. In: Miller J., and Drillon M. (Eds). Magnetoscience: From Molecules to Materials (2001), Villey-VCH 1-47
25. Dunbar K.R., Schelter E.J., Palii A.V., Ostrovsky S.M., Mirovitskii V.Yu., Hudson J.M., Omary M.A., Klokishner S.I., and Tsukerblat B.S. J. Phys. Chem. A 107 (2003) 11102