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Organometallics

Volumn 23, Issue 12, 2004, Pages 2822-2834

Heteronuclear heavy alkenes E=E′ (E, E′ = Group 14 elements): Germasilenes, silastannenes, germastannenes...Next stop?

(2) Lee, Vladimir Ya a Sekiguchi, Akira a

a UNIVERSITY OF TSUKUBA (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BONDING; CHEMICAL BONDS; CRYSTAL STRUCTURE; DIMERIZATION; ORGANOMETALLICS; REACTION KINETICS; RESONANCE; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION ANALYSIS;

BONDING MODES; HOMONUCLEAR SPECIES; PAULI REPULSION; QUANTUM NUMBERS;

OLEFINS;

EID: 3042663682 PISSN: 02767333 EISSN: None Source Type: Journal
DOI: 10.1021/om040027h Document Type: Review

Times cited : (134)

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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1987) Angew. Chem., Int. Ed. Engl. , vol.26 , pp. 1201
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23
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- See ref 2i
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.

24
- 3042675341
- See ref 2j
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.

25
- 33748240837
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1991) Angew. Chem., Int. Ed. Engl. , vol.30 , pp. 902
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26
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28
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1998) Adv. Organomet. Chem. , vol.39 , pp. 275
- Baines, K.M.¹ Stibbs, W.G.²

29
- 0003426786
- Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., Chapter 5
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1998) The Chemistry of Organic Silicon Compounds , vol.2 , Issue.PART 1
- Kaftory, M.¹ Kapon, M.² Botoshansky, M.³

30
- 0032282981
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1998) Coord. Chem. Rev. , vol.178-180 , pp. 565
- Escudié, J.¹ Couret, C.² Ranaivonjatovo, H.³

31
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1998) J. Chem. Soc., Dalton Trans. , pp. 2939
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
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33
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1999) Eur. J. Inorg. Chem. , pp. 373
- Weidenbruch, M.¹

34
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (1999) Adv. Organomet. Chem. , vol.44 , pp. 113
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35
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (2000) J. Organomet. Chem. , vol.611 , pp. 236
- Kira, M.¹ Iwamoto, T.²

36
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- Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., Chapter 5
- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (2001) The Chemistry of Organic Silicon Compounds , vol.3
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37
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- (2002) J. Organomet. Chem. , vol.646 , pp. 39
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- (2002) Polyhedron , vol.21 , pp. 467
- West, R.¹

39
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (2002) The Chemistry of Organic Germanium, Tin and Lead Compounds , vol.2 , Issue.PART 1
- Klinkhammer, K.W.¹

40
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- Rappoport, Z., Ed.; Wiley: Chichester, U.K., Chapter 13
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- (2002) The Chemistry of Organic Germanium, Tin and Lead Compounds , vol.2 , Issue.PART 1
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41
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (2003) Organometallics , vol.22 , pp. 4348
- Weidenbruch, M.¹

42
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- Reviews on metallenes >E=C< and dimetallenes >E=E< of group 14 elements: (a) West, R. Angew. Chem., Int. Ed. Engl. 1987, 26, 1201. (b) See ref 2i. (c) See ref 2j. (d) Tsumuraya, T.; Batcheller, S. A.; Masamune, S. Angew. Chem., Int. Ed. Engl. 1991, 30, 902. (e) Escudié, J.; Couret, C.; Ranaivonjatovo, H.; Satgé, J. Coord. Chem. Rev. 1994, 130, 427. (f) Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231. (g) Baines, K. M.; Stibbs, W. G. Adv. Organomet. Chem. 1998, 39, 275. (h) Kaftory, M.; Kapon, M.; Botoshansky, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 1, Chapter 5. (i) Escudié, J.; Couret, C.; Ranaivonjatovo, H. Coord. Chem. Rev. 1998, 178-180, 565. (j) Power, P. P. J. Chem. Soc., Dalton Trans. 1998, 2939. (k) Power, P. P. Chem. Rev. 1999, 99, 3463. (l) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373. (m) Escudié, J.; Ranaivonjatovo, H. Adv. Organomet. Chem. 1999, 44, 113. (n) Kira, M.; Iwamoto, T. J. Organomet. Chem. 2000, 611, 236. (o) Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, Chapter 5. (p) Weidenbruch, M. J. Organomet. Chem. 2002, 646, 39. (q) West, R. Polyhedron 2002, 21, 467. (r) Klinkhammer, K. W. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 4. (s) Tokitoh, N.; Okazaki, R. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 13. (t) Weidenbruch, M. Organometallics 2003, 22, 4348. Reviews on the cyclic trimetallenes of heavier group 14 elements (heavy cyclopropenes): (u) Lee, V. Ya.; Sekiguchi, A. In The Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: Chichester, U.K., 2002; Vol. 2, Part 1, Chapter 14. (v) Sekiguchi, A.; Lee, V. Ya. Chem. Rev. 2003, 103, 1429. (w) Sekiguchi, A.; Lee, V. Ya. In Organosilicon Chemistry V: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 2003; p 92.
- (2002) The Chemistry of Organic Germanium, Tin and Lead Compounds , vol.2 , Issue.PART 1
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