Solid-state 55Mn NMR spectroscopy of bis(μ-oxo) dimanganese(IV) [Mn2O2(salpn)2], a model for the oxygen evolving complex in photosystem II

Journal of the American Chemical Society

Volumn 132, Issue 47, 2010, Pages 16727-16729

  Ellis, Paul D ^a   Sears, Jesse A ^b   Yang, Ping ^b   Dupuis, Michel ^a   Boron, Thaddeus T ^c   Pecoraro, Vincent L ^c   Stich, Troy A ^d   Britt, R David ^d   Lipton, Andrew S ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF MICHIGAN   (United States)

^d UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRY PARAMETER; BROKEN SYMMETRY; CRYOGENIC TEMPERATURES; ELECTRIC FIELD GRADIENTS; ELECTRON LEVELS; EXPERIMENTAL OBSERVATION; FIRST-PRINCIPLE THEORY; NMR SPECTROSCOPY; OXYGEN-EVOLVING COMPLEXES; PHOTOSYSTEM II; QUADRUPOLE COUPLING CONSTANTS; SOLID STATE NMR;

ELECTRIC FIELDS; MANGANESE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN;

DENSITY FUNCTIONAL THEORY;

MANGANESE DERIVATIVE; OXYGEN;

ANISOTROPY; ARTICLE; DENSITY FUNCTIONAL THEORY; ELECTRIC FIELD; ELECTRON; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOSYSTEM II; POLARIZATION; SOLID STATE; TEMPERATURE;

BIOMIMETIC MATERIALS; MAGNETIC RESONANCE SPECTROSCOPY; MANGANESE COMPOUNDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; OXIDES; OXYGEN; PHOTOSYSTEM II PROTEIN COMPLEX; TEMPERATURE;

EID: 78649509423     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1054252     Document Type: Article

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