Reversible, solvent-induced chirality switch in atrane structure: Control of the unidirectional motion of the molecular propeller

Journal of the American Chemical Society

Volumn 132, Issue 47, 2010, Pages 16733-16734

  Martinez, Alexandre ^a   Guy, Laure ^a   Dutasta, Jean Pierre ^a  

^a UNIVERSITÉ DE LYON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOTRIVERATRYLENES; DIASTEREOMERIC; ETHER GROUP; HELICAL STRUCTURES; INDUCED CHIRALITY; INTERCONVERSION PROCESS; INVERSION PROCESS; MOLECULAR SWITCHES; REVERSIBLE CHANGE; ROTATIONAL MOTION; TILTING MOTION; UNIDIRECTIONAL MOTION;

CHIRALITY; ENANTIOMERS; ETHERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROPELLERS; STEREOCHEMISTRY;

SOLVENTS;

ATRANE; CYCLOTRIVERATRYLENE; ETHER DERIVATIVE; HEMICRYPTOPHANE; OXIDOVANADIUM 5; PROPELLANT; SOLVENT; UNCLASSIFIED DRUG; VANADIUM DERIVATIVE; VANATRANE;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; CONFORMATIONAL TRANSITION; CONTROLLED STUDY; DIASTEREOISOMER; HANDEDNESS; MIXER; MOLECULAR PROPELLER; MOTION; MOTION ANALYSIS SYSTEM; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; TILTING;

EID: 78649504906     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja102873x     Document Type: Article

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