Catalytic conversion of fructose into 5-hydroxymethylfurfural with sulfonic group bearing ionic liquid immobilized on micro-ball silica-gel

Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities

Volumn 24, Issue 5, 2010, Pages 824-829

  Zhang, Yuan Yuan ^a   Deng, Jun Hui ^a   Shan, Yu Hua ^a   Zhou, Yong Sheng ^a   Wang, Gui Min ^a   Li, Ming Shi ^a  

^a CHANGZHOU UNIVERSITY   (China)

Author keywords

5 hydroxymethylfurfural (HMF); Fructose; Immobilization; Micro ball silica gel; Sulfonic group bearing ionic liquid

Indexed keywords

5 HYDROXYMETHYL FURFURALS; ACIDITY MEASUREMENT; CATALYTIC CONVERSION; CATALYTIC PERFORMANCE; COKE DEPOSITION; COKE FORMATION; EFFICIENT CATALYSTS; ELEMENTAL ANALYSIS; HYDRATION REACTION; IMMOBILIZATION; MICRO-BALL SILICA-GEL; PORE VOLUME; SULFONIC ACID; SULFONIC GROUP; SURFACE ACIDITY;

ACIDS; ADSORPTION; CATALYSTS; CHLORINE COMPOUNDS; COKE; COUPLING AGENTS; DEHYDRATION; DEWATERING; FRUCTOSE; GELS; IONS; SILICA; SPHERES; SYNTHESIS (CHEMICAL);

IONIC LIQUIDS;

EID: 78649378607     PISSN: 10039015     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. Lewkowski J. Synthesis, chemistry and applications of 5-hydroxymethylfurfural and its derivatives[J]. Arkivoc, 2001, (1): 17-54.
2. WANG Jun, ZHANG Chun-peng, OUYANG Ping-kai. Advances in production and application of 5-hydroxymethyl furfural[J]. Chemical Industry and Engineering Progress(China), 2008, 27(5): 702-707.
3. Huber G W, Chheda J N, Barrett C J et al. Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates[J]. Science, 2005, 308(5727): 1446-1450.
4. KOU Yuan, HE Ling. Ionic liquids in green chemistry: Today's solvent or tomorrow's solution?[J]. Progress in Chemistry (China), 2008, 20(1): 5-10.
5. Lansalot-Matras C, Moreau C. Dehydration of fructose into 5-hydroxymethylfurfural in the presence of ionic liquids[J]. Catalysis Communications, 2003, 4(10): 517-520.
6. Moreau C, Finiels A, Vanoye L. Dehydration of fructose and sucrose into 5-hydroxymethylfurfural in the presence of 1-H-3-methyl imidazolium chloride acting both as solvent and catalyst[J]. Journal of Molecular Catalysis A: Chemical, 2006, 253(1-2): 165-169.
7. Yong Gen, Zhang Yugen, Ying J Y. Efficient catalyic system for the selective production of 5-hydroxymethylfurfural from glucose and fructose[J]. Angew Chem Int Ed, 2008, 47(48): 9345-9348.
8. Zhao H, Holladay J E, Brown H et al. Metal chlorides in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural[J]. Science, 2007, 316(5831): 1597-1600.
9. Su Y, Brown H M, Huang Xiwen et al. Single-Step conversion of cellulose to 5-hydroxymethylfurfural (HMF), a versatile platform chemical[J]. Applied Catalysis A: General, 2009, 361(1-2): 117-122.
10. Valkenberg M H, De Castro C, HÊlderich W F. Immobilisation of ionic liquids on solid supports[J]. Green Chem, 2002, 4(2): 88-93.
11. HUANG Yong, WEI Zuo-jun, LIU Ying-xin et al. Study on alcoholysis of isoflavone catalyzed by acidic ionic liquids[J]. J Chem Eng of Chinese Univ, 2008, 22(4): 720-724.
12. Lai Guoqiao, Peng Jiajian, Li Jiayun et al. Ionic liquid functionalized silica gel: Novel catalyst and fixed solvent[J]. Tetrahedron Letters, 2006, 47(39): 6951-6953.
13. Gui Jianzhou, Cong Xiaohui, Liu Dan et al. Novel Brøsted acidic ionic liquid as efficient and reusable catalyst system for esterification[J]. Catalysis Communications, 2004, 5(9): 473-477.
14. PENG Xin-Wen, Lü Xiu-Yang. Decomposition kinetics of 5-hydroxymethylfurfural catalyzed by dilute sulfuric acid[J]. J Chem Ind and Eng (China), 2008, 59(5): 1150-1155.
15. Tarabanko V E, Chernyak M Y, Nepomnyashchiy I V et al. High temperature 5-hydroxymethylfurfural synthesis in a flow reactor[J]. Chemistry for Sustainable Development, 2006, 14(1): 49-53.