Self-assembly of nanometer-sized macrotricyclic complexes from ten small component molecules

Angewandte Chemie - International Edition

Volumn 37, Issue 15, 1998, Pages 2082-2085

  Fujita, Makoto ^a   Yu, Shu Yan ^a   Kusukawa, Takahiro ^a   Funaki, Hidenori ^b   Ogura, Katsuyuki ^b   Yamaguchi, Kentaro ^b  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^b CHIBA UNIVERSITY   (Japan)

Author keywords

Metallacycles; Molecular recognition; N ligands; Palladium; Supramolecular chemistry

Indexed keywords

EID: 0032541262     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980817)37:15<2082::AID-ANIE2082>3.0.CO;2-0     Document Type: Article

References (24)

1. Reviews: a) P.N.W. Baxter in Comprehensive Supramoleculur Chemistry, Vol. 9 (Ed.: J.-M. Lehn), Pergamon, Oxford, 1996, chap. 5; b) J. R. Fredericks, A. D. Hamilton in Supramolecular Control of Structure and Reactivity (Ed.: A. D. Hamilton), Wiley, New York, 1996, chap. 1.
2. Reviews: a) P.N.W. Baxter in Comprehensive Supramoleculur Chemistry, Vol. 9 (Ed.: J.-M. Lehn), Pergamon, Oxford, 1996, chap. 5; b) J. R. Fredericks, A. D. Hamilton in Supramolecular Control of Structure and Reactivity (Ed.: A. D. Hamilton), Wiley, New York, 1996, chap. 1.
3. a) M. Fujita in Comprehensive Supramolecular Chemistry, Vol. 9 (Ed.: J.-M. Lehn), Pergamon, Oxford, 1996, chap. 7;
4. b) M. Fujita, K. Ogura, Coord. Chem. Rev. 1996, 148, 249-264;
5. c) M. Fujita, K. Ogura, Bull. Chem. Soc. Jpn. 1996, 69, 1471-1482.
6. a) M. Fujita, J. Yazaki, K. Ogura, J. Am. Chem. Soc. 1990, 112., 5645-5647;
7. b) M. Fujita, J. Yazaki, K. Ogura, Tetrahedron Lett. 1991, 32, 5589-5592;
8. c) M. Fujita, J. Yazaki, K. Ogura, Chem. Lett. 1991, 1031-1032;
9. d) M. Fujita, O. Sasaki, T. Mitsuhashi, T. Fujita, J. Yazaki, K. Yamaguchi, K. Ogura, Chem. Commun. 1996, 1535-1536.
10. Phosphine-protected analogues: a) P. J. Stang, D. H. Cao, J. Am. Chem. Soc. 1994, 116, 4981-4982; b) P. J. Stang, B. Olenyuk, Acc. Chem. Res. 1997, 30, 502-518.
11. Phosphine-protected analogues: a) P. J. Stang, D. H. Cao, J. Am. Chem. Soc. 1994, 116, 4981-4982; b) P. J. Stang, B. Olenyuk, Acc. Chem. Res. 1997, 30, 502-518.
12. 4 complex: M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura. Nature 1995, 378, 469-471;
13. 6 complex: R. W. Saalfrank, A. Stark, K. Peters, H. G. von Schnering, Angew. Chem. 1988, 100, 878-880; Angew. Chem. Int. Ed. Engl. 1988, 27, 851-853; R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Müther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
14. 6 complex: R. W. Saalfrank, A. Stark, K. Peters, H. G. von Schnering, Angew. Chem. 1988, 100, 878-880; Angew. Chem. Int. Ed. Engl. 1988, 27, 851-853; R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Müther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
15. 6 complex: R. W. Saalfrank, A. Stark, K. Peters, H. G. von Schnering, Angew. Chem. 1988, 100, 878-880; Angew. Chem. Int. Ed. Engl. 1988, 27, 851-853; R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Müther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
16. 6 complex: R. W. Saalfrank, A. Stark, K. Peters, H. G. von Schnering, Angew. Chem. 1988, 100, 878-880; Angew. Chem. Int. Ed. Engl. 1988, 27, 851-853; R. W. Saalfrank, R. Burak, A. Breit, D. Stalke, R. Herbst-Irmer, J. Daub, M. Porsch, E. Bill, M. Müther, A. X. Trautwein, Angew. Chem. 1994, 106, 1697-1699; Angew. Chem. Int. Ed. Engl. 1994, 33, 1621-1623.
17. 3) δ = 8.41 (d, J = 6.0 Hz, 6H), 7.09 (d, 7 = 6.0 Hz, 6H), 2.17 (s, 3H).
18. B. Hasenknopf, J.-M. Lehn, N. Boumediene, A. Dupont-Gervais, A. Van Dorsselaer, B. Kneisel, D. Fenske, J. Am. Chem. Soc. 1997, 119, 10956-10962.
19. J. Manna, J. A. Whiteford, P. J. Stang, J. Am. Chem. Soc. 1996, 118, 8731-8732.
20. 3OD) that the self-assembly event occurs immediately at room temperature under homogeneous conditions.
21. M. Fujita, M. Aoyagi, K. Ogura, Inorg. Chim. Acta 1996, 246, 53-57.
22. [13]
23. M. Fujita, S. Nagao, K. Ogura, J. Am. Chem. Soc. 1995, 117, 1649-1650.
24. Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata @fiz-karlsruhe.de), on quoting the depository numbers CSD-408575, CSD-408576, and CSD-408577.