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Volumn 352, Issue 14-15, 2010, Pages 2405-2410

One-pot desilylation/dimerization of terminal alkynes by ruthenium and acid-promoted (RAP) catalysis

Author keywords

alkyne dimerization; C C coupling; enynes; polyaddition; ruthenium catalysts

Indexed keywords


EID: 78349236153     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000347     Document Type: Article
Times cited : (20)

References (38)
  • 8
    • 78349267370 scopus 로고    scopus 로고
    • Selected references concerning the catalytic dimerization of 1-alkynes
    • Selected references concerning the catalytic dimerization of 1-alkynes
  • 17
    • 78349252466 scopus 로고    scopus 로고
    • By contrast, the dimerization of 1-alkynes is feasible in aqueous media by ruthenium catalysis
    • By contrast, the dimerization of 1-alkynes is feasible in aqueous media by ruthenium catalysis
  • 21
    • 78349266270 scopus 로고    scopus 로고
    • in:, Vol. 1, (Ed.: G. Dyker) Wiley-VCH, Weinheim, Chapter II.
    • H. Plenio, A. Datta, in: Handbook of C-H Transformations, Vol. 1, (Ed.:, G. Dyker,) Wiley-VCH, Weinheim, 2005, Chapter II.
    • (2005) Handbook of C-H Transformations
    • Plenio, H.1    Datta, A.2
  • 24
    • 0034604562 scopus 로고    scopus 로고
    • 2657, and references cited therein.
    • Angew. Chem. Int. Ed. 2000, 39, 2632 - 2657, and references cited therein.
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 2632
  • 31
    • 78349274740 scopus 로고    scopus 로고
    • The deprotection of the trimethylsilylethynyl substrate needs to be complete before addition of the dimerization promoters, since excess acetic acid consumes the hydroxide or quenches the nucleophilicity of the fluoride ions.
    • The deprotection of the trimethylsilylethynyl substrate needs to be complete before addition of the dimerization promoters, since excess acetic acid consumes the hydroxide or quenches the nucleophilicity of the fluoride ions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.