Hockey-puck micelles from oligo(p-benzamide)-b-PEG rod-coil block copolymers

Angewandte Chemie - International Edition

Volumn 45, Issue 18, 2006, Pages 2969-2975

  Schleuss, Tobias W ^a   Abbel, Robert ^a   Gross, Michael ^a   Schollmeyer, Dieter ^a   Frey, Holger ^a   Maskos, Michael ^a   Berger, Rüdiger ^b   Kilbinger, Andreas F M ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

Author keywords

Aggregation; Block copolymers; Micelles; Nanostructures; Scanning probe microscopy

Indexed keywords

AGGLOMERATION; BLOCK COPOLYMERS; NANOSTRUCTURED MATERIALS; NITROGEN COMPOUNDS; OLIGOMERS; SCANNING ELECTRON MICROSCOPY; SOLVENTS;

ARAMIDE; ETHYLENE GLYCOL; NONPOLAR SOLVENTS; SFM IMAGE;

MICELLES;

EID: 33746255381     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200503514     Document Type: Article

References (48)

1. M. Lee, B.-K. Cho, W.-C. Zin, Chem. Rev. 2001, 101, 3869-3892.
2. H.-A. Klok, S. Lecommandoux, Adv. Mater. 2001, 13, 1217-1229.
3. M. Lee, Y.-S. Yoo, J. Mater. Chem. 2002, 12, 2161-2168.
4. See, for example: D. Vernino, D. Tirrell, M. Tirrell, Polym. Mater. Sci. Eng. 1994, 71, 496-497.
5. See for example: J. T. Chen, E. L. Thomas, C. K. Ober, G.-P. Mao, Science 1996, 273, 343-346.
6. See, for example: J. J. L. M. Cornelissen, M. Fischer, R. J. M. Nolte, Science 1998, 280, 1427-1430.
7. J. L. David, S. P. Gido, B. M. Novak, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem. 1998, 39, 433-434.
8. X. F. Zhong, B. Francois, Makromol. Chem. 1991, 192, 2277-2291.
9. B. Francois, X. F. Zhong, Synth. Met. 1991, 41, 955-958.
10. T. Olinga, B. Francois, Makromol. Chem. Rapid Commun. 1991, 12, 575-582;
11. T. Olinga, B. Francois, J. Chim. Phys. Phys.-Chim. Biol. 1992, 89, 1079-1084;
12. B. Francois, T. Olinga, Synth. Met. 1993, 57, 3489-3494.
13. S. A. Jenekhe, X. L. Chen, Science 1998, 279, 1903-1907.
14. H.-A. Klok, J. F. Langenwalter, S. Lecommandoux, Macromolecules 2000, 33, 7819-7826.
15. E. R. Zubarev, M. U. Pralle, E. D. Sone, S. I. Stupp, J. Am. Chem. Soc. 2001, 123, 4105-4106.
16. S. I. Stupp, V. LeBonheur, K. Walker, L. S. Li, K. E. Huggins, M. Keser, A. Amstutz, Science 1997, 276, 384-389.
17. Y. L. Jin, J.-H. Anh, M. Lee, J. Am. Chem. Soc. 2004, 126, 12 208-12 209.
18. M. Lee, C.-J. Jang, J.-H. Ryu, J. Am. Chem. Soc. 2004, 126, 8082-8083.
19. A. P. H. J. Schenning, A. F. M. Kilbinger, F. Biscarini, M. Cavallini, H. J. Cooper, P. J. Derrick, W. J. Feast, R. Lazzaroni, P. Leclere, L. A. McDonell, E. W. Meijer, S. C. J. Meskers, J. Am. Chem. Soc. 2002, 124, 1269-1275.
20. J. T. Chen, E. L. Thomas, C. K. Ober, S. S. Hwang, Macromolecules 1995, 28, 1688;
21. J. T. Chen, E. L. Thomas, C. K. Ober, G.-P. Mao, Science 1996, 273, 343-346.
22. Y. Tu, X. Wan, D. Zhang, Q. Zhou, C. Wu, J. Am. Chem. Soc. 2000, 122, 10 201-10 205.
23. D. M. Vriezema, J. Hoogboom, K. Velonia, K. Takazawa, P. C. M. Christianen, J. C. Maan, A. E. Rowan, R. J. M. Nolte, Angew. Chem. 2003, 115, 796-800;
24. Angew. Chem. Int. Ed. 2003, 42, 772-776.
25. F. Checot, A. Brulet, J. Oberdisse, Y. Gnanou, O. Mondain-Monval, S. Lecommandoux, Langmuir 2005, 21, 4308-4315.
26. J. Rodriguez-Hernandez, S. Lecommandoux, J. Am. Chem. Soc. 2005, 127, 2026-2027.
27. E. Bellomo, M. D. Wyrsta, L. Pakstis, D. J. Pochan, T. Deming, J. Nat. Mater. 2004, 3, 244-248.
28. P. Leclere, A. Calderone, D. Marsitzky, V. Francke, Y. Geerts, K. Müllen, J. Bredas, R. Lazzaroni, Adv. Mater. 2000, 12, 1042-1046.
29. R. Abbel, H. Frey, D. Schollmeyer, A. F. M. Kilbinger, Chem. Eur. J. 2005, 11, 2170-2176.
30. R. Abbel, T. W. Schleuss, H. Frey, A. F. M. Kilbinger, Macromol. Chem. Phys. 2005, 206, 2067-2074.
31. M. Pope, Electronic Processes in Organic Chrystals and Polymers, Oxford University Press, New York, 1999.
32. R. Pecora, Dynamic Light Scattering, Plenum, New York, 1985.
33. The refractive index increment was measured with a home-built Michelson interferometer as described in A. Becker, W. Köhler, B. Müller, Ber. Bunsenges. Phys. Chem. 1995, 99, 600.
34. S. N. Magonov, Encycl. Anal. Chem. 2000, 7432-7491.
35. G. Reiter, J. U. Sommer, Phys. Rev. Lett. 1998, 80, 3771-3774;
36. G. Reiter, J. U. Sommer, J. Chem. Phys. 2000, 112, 4376-4393;
37. M. Wang, H.-G. Braun, E. Meyer, Macromol. Rapid Commun. 2002, 23, 853-858.
38. D. R. M. Williams, G. H. Fredrickson, Macromolecules 1992, 25, 3561-3568.
39. T. Mori, T. Watanabe, K. Minagawa, M. Tanaka, J. Polym. Sci. 2005, 43, 1569-1578.
40. "Simultaneous Static and Dynamic Light Scattering: Application to Polymer Structure Analysis": M. Schmidt in Dynamic Light Scattering, The Method and Some Applications (Ed.: W. Brown), Clarendon Press, Oxford, 1993, p. 372.
41. A detailed analysis of the light-scattering data will be published elsewhere.
42. H. Wang, W. You, P. Jiang, L. Yu, H. H. Wang, Chem. Eur. J. 2004, 10, 986-993.
43. See, for example: R. Luginbühl, A. Szuchmacher, M. D. Garrison, J.-B. Lhoest, R. M. Overney, B. D. Ratner, Ultramicroscopy 2000, 82, 171-179.
44. In particular, we have observed for lower setpoint ratios of around 0.6-0.7 that the micelles are deformed and that topography is altered. We observed that this deformation is reversible and that the micelle returned to its initial shape after the setpoint ratio was set again to 0.98.
45. [41]
46. G. M. Sheldrick, SHELXL-97, Program for Structure Refinement, University of Göttingen, Germany, 1997.
47. CCDC-283302 (3) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
48. B. J. Berne, R. Pecora, Dynamic Light Scattering, J. Wiley, New York, 1976.