Insertion of pyridine into the calcium allyl bond: Regioselective 1,4-dihydropyridine formation and C-H bond activation

Angewandte Chemie - International Edition

Volumn 49, Issue 42, 2010, Pages 7795-7798

  Jochmann, Phillip ^a   Dols, Thomas S ^a   Spaniol, Thomas P ^a   Perrin, Lionel ^b   Maron, Laurent ^b   Okuda, Jun ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

Allyl ligands; C C coupling; C H activation; Calcium; Density functional calculations

Indexed keywords

ALLYL LIGANDS; C-C COUPLING; C-H ACTIVATION; CH-BOND ACTIVATION; DENSITY-FUNCTIONAL CALCULATIONS; DIHYDROPYRIDINES; NUCLEOPHILICITIES; ORGANOLITHIUMS; ORGANOMAGNESIUM; REGIO-SELECTIVE;

ACTIVATION ANALYSIS; BIOACTIVITY; LIGANDS; PYRIDINE; REGIOSELECTIVITY;

CALCIUM;

1,4 DIHYDROPYRIDINE; 1,4-DIHYDROPYRIDINE; ALLYL COMPOUND; CALCIUM; DIHYDROPYRIDINE DERIVATIVE; ORGANOMETALLIC COMPOUND; PYRIDINE; PYRIDINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; HYDROGEN BOND; STEREOISOMERISM; SYNTHESIS;

ALLYL COMPOUNDS; CALCIUM; DIHYDROPYRIDINES; HYDROGEN BONDING; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PYRIDINES; STEREOISOMERISM;

EID: 78249256363     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201003704     Document Type: Article

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