Kinetic study of cyclooctene epoxidation with aqueous hydrogen peroxide over silica-supported calixarene-Ta(V)

Applied Catalysis A: General

Volumn 387, Issue 1-2, 2010, Pages 45-54

  Morlanes, Natalia ^a   Notestein, Justin M ^a  

^a Northwestern University   (United States)

Author keywords

Epoxidation; Hydrogen peroxide; Organic inorganic hybrid; Tantalum

Indexed keywords

CALIXARENES; CAPPING LIGANDS; CATALYTIC CYCLES; CYCLOOCTENE; EXPERIMENTAL DATA; FIRST-ORDER DEPENDENCE; FREE SOLUTIONS; HYDROPEROXIDES; INITIAL RATE; KINETIC EXPRESSION; KINETIC MODELING; KINETIC STUDY; LEWIS ACIDIC; MOLAR BASIS; NUCLEOPHILIC ATTACK; ONE-POT PROCEDURES; ORGANIC-INORGANIC HYBRID; OXIDE CATALYSTS; OXIDE DISPERSIONS; PHENOLATE LIGANDS; RATE-LIMITING STEPS; SELECTIVE CATALYSTS; SURFACE DENSITY; SURFACE SPECIES; TA CONTENT; TURNOVER RATE;

CALCINATION; CATALYST SELECTIVITY; EPOXIDATION; HYDROGEN; HYDROGEN PEROXIDE; HYDROLYSIS; KINETIC THEORY; LEAD OXIDE; LIGANDS; OLEFINS; OXIDATION; OXYGEN; SILICA; TANTALUM; TANTALUM OXIDES;

CATALYST SUPPORTS;

EID: 78149414149     PISSN: 0926860X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcata.2010.07.063     Document Type: Article

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