Alkane oxidation on Rh(111) single-crystal surfaces under high-temperature, short-contact-time conditions: A molecular beam kinetic study

Journal of Physical Chemistry C

Volumn 114, Issue 40, 2010, Pages 16946-16954

  Wilson, Jarod N ^a,b   Zaera, Francisco ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Watercare Laboratory Services   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED OXYGEN; ALKANE ACTIVATION; ALKANE OXIDATION; ATOMIC OXYGEN; DIRECT MECHANISM; HIGH TEMPERATURE; KINETIC STUDY; PARTIAL OXIDATIONS; SURFACE INTERMEDIATES; SYN-GAS; TIME CONDITION; ULTRAHIGH VACUUM CONDITIONS;

CARBON DIOXIDE; CARBON MONOXIDE; MOLECULAR BEAMS; OXIDATION; PARAFFINS; REACTION INTERMEDIATES; RHODIUM; SINGLE CRYSTAL SURFACES; SYNTHESIS GAS;

MOLECULAR OXYGEN;

EID: 77957860977     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp1006507     Document Type: Article

References (48)

1. Iordanoglou, D. I.; Bodke, A. S.; Schmidt, L. D. J. Catal. 1999, 187, 400
2. Cavani, F.; Ballarini, N.; Cericola, A. Catal. Today 2007, 127, 113
3. Choudhary, V. R.; Mammon, A. S.; Sansare, S. D. Angew. Chem., Int. Ed. 1992, 31, 1189
4. Hickman, D. A.; Schmidt, L. D. Science 1993, 259, 343
5. Enger, B. C.; Lødeng, R.; Holmen, A. Appl. Catal., A 2008, 346, 1
6. Fathi, M.; Hofstad, K. H.; Sperle, T.; Rokstad, O. A.; Holmen, A. Catal. Today 1998, 42, 205
7. Williams, K. A.; Leclerc, C. A.; Schmidt, L. D. AIChE J. 2005, 51, 247
8. Roychoudhury, S.; Castaldi, M.; Lyubovsky, M.; LaPierre, R.; Ahmed, S. J. Power Sources 2005, 152, 75
9. Neumann, D.; Veser, G. AIChE J. 2005, 51, 210
10. Burke, N. R.; Trimm, D. L. Catal. Today 2006, 117, 248
11. Vlachos, D. G.; Mhadeshwar, A. B.; Kaisare, N. S. Comput. Chem. Eng. 2006, 30, 1712
12. Choudhary, T. V.; Choudhary, V. R. Angew. Chem., Int. Ed. 2008, 47, 1828
13. Horn, R.; Williams, K. A.; Degenstein, N. J.; Schmidt, L. D. J. Catal. 2006, 242, 92
14. York, A. P. E.; Xiao, T. C.; Green, M. L. H.; Claridge, J. B. Catal. Rev.-Sci. Eng. 2007, 49, 511
15. Liu, T.; Snyder, C.; Veser, G. Ind. Eng. Chem. Res. 2007, 46, 9045
16. Donazzi, A.; Beretta, A.; Groppi, G.; Forzatti, P. J. Catal. 2008, 255, 241
17. Maestri, M.; Vlachos, D.; Beretta, A.; Forzatti, P.; Groppi, G.; Tronconi, E. Top. Catal. 2009, 52, 1983
18. Bitsch-Larsen, A.; Horn, R.; Schmidt, L. D. Appl. Catal., A 2008, 348, 165
19. Wilson, J. N.; Pedigo, R. A.; Zaera, F. J. Am. Chem. Soc. 2008, 130, 15796
20. The numerical values of the temperatures in the reference above were mistakenly reported in °C, even though the units indicate K.
21. Liu, J.; Xu, M.; Nordmeyer, T.; Zaera, F. J. Phys. Chem. 1995, 99, 6167
22. Zaera, F. Int. Rev. Phys. Chem. 2002, 21, 433
23. Uñac, R. O.; Bustos, V.; Wilson, J.; Zgrablich, G.; Zaera, F. J. Chem. Phys. 2006, 125 074705 ASAP
24. Thiel, P. A.; Williams, E. D.; Yates, J. T., Jr.; Weinberg, W. H. Surf. Sci. 1979, 84, 54
25. Yates, J. T., Jr.; Thiel, P. A.; Weinberg, W. H. Surf. Sci. 1979, 84, 427
26. Guevremont, J. M.; Sheldon, S.; Zaera, F. Rev. Sci. Instrum. 2000, 71, 3869
27. Gopinath, C. S.; Zaera, F. J. Catal. 1999, 186, 387
28. Gopinath, C. S.; Zaera, F. J. Catal. 2001, 200, 270
29. Zaera, F.; Liu, J.; Xu, M. J. Chem. Phys. 1997, 106, 4204
30. Öfner, H.; Zaera, F. J. Phys. Chem. 1997, 101, 396
31. Summers, R. L. Empirical observations on the sensitivity of hot cathode ionization type vacuum gages; NASA: Washington, DC, 1969; Report No. NASA-TN-D-5285.
32. Nakayama, K.; Hojo, H. Jpn. J. Appl. Phys. 1974, 2 (1) 113
33. Beutler, A.; Lundgren, E.; Nyholm, R.; Andersen, J. N.; Setlik, B. J.; Heskett, D. Surf. Sci. 1998, 396, 117
34. Fukuoka, M.; Okada, M.; Matsumoto, M.; Ogura, S.; Fukutani, K.; Kasai, T. Phys. Rev. B 2007, 75, 235434
35. Peterlinz, K. A.; Sibener, S. J. J. Phys. Chem. 1995, 99, 2817
36. Wilson, J.; Guo, H.; Morales, R.; Podgornov, E.; Lee, I.; Zaera, F. Phys. Chem. Chem. Phys. 2007, 9, 3830
37. Wheeler, C.; Jhalani, A.; Klein, E. J.; Tummala, S.; Schmidt, L. D. J. Catal. 2004, 223, 191
38. Matolin, V.; Masek, K.; Elyakhloufi, M. H.; Gillet, E. J. Catal. 1993, 143, 492
39. CRC Handbook of Chemistry and Physics, 85 th ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, FL, 2004.
40. Zangwill, A. Physics at Surfaces; Cambridge University Press: Cambridge, 1988.
41. Thiel, P. A.; Yates, J. T., Jr.; Weinberg, W. H. Surf. Sci. 1979, 82, 22
42. Root, T. W.; Schmidt, L. D.; Fisher, G. B. Surf. Sci. 1983, 134, 30
43. Wehner, S.; Paffett, M. T.; Zaera, F. J. Phys. Chem. B 2004, 108, 18683
44. Wider, J.; Greber, T.; Wetli, E.; Kreutz, T. J.; Schwaller, P.; Osterwalder, J. Surf. Sci. 1998, 417, 301
45. Lyubovsky, M.; Roychoudhury, S.; LaPierre, R. Catal. Lett. 2005, 99, 113
46. Dalle Nogare, D.; Degenstein, N. J.; Horn, R.; Canu, P.; Schmidt, L. D. J. Catal. 2008, 258, 131
47. Ganduglia-Pirovano, M. V.; Reuter, K.; Scheffler, M. Phys. Rev. B 2002, 65, 2454261
48. Liu, J.; Xu, M.; Zaera, F. Catal. Lett. 1996, 37, 9