Coverage- and temperature-dependent site occupancy of carbon monoxide on Rh(111) studied by high-resolution core-level photoemission

Surface Science

Volumn 396, Issue 1-3, 1998, Pages 117-136

  Beutler, A ^a   Lundgren, E ^a   Nyholm, R ^a   Andersen, J N ^a   Setlik, B J ^b   Heskett, D ^b  

^a LUND UNIVERSITY   (Sweden)

^b UNIVERSITY OF RHODE ISLAND   (United States)

Author keywords

Carbon monoxide; Chemisorption; Photoelectron diffraction; Rhodium; Single crystal surfaces; Soft x ray photoelectron spectroscopy; Surface structure; Surface thermodynamics

Indexed keywords

ADSORPTION; BINDING ENERGY; CARBON MONOXIDE; ELECTRON DIFFRACTION; MOLECULES; ORDER DISORDER TRANSITIONS; RHODIUM; SINGLE CRYSTALS; THERMAL EFFECTS; THERMODYNAMIC PROPERTIES; X RAY PHOTOELECTRON SPECTROSCOPY;

MOLECULAR ADSORPTION; SINGLE CRYSTAL SURFACE;

SURFACE STRUCTURE;

EID: 0031703044     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0039-6028(97)00664-X     Document Type: Article

References (30)

1. See, for example, J. Campuzano, in: D.A. King, D.P. Woodruff (Eds.), The Chemical Physics of Solid Surfaces and Heteregeneous Catalysis, vol. 3, part A, Elsevier, Amsterdam, 1990, p. 389, and references therein.
2. D.G. Castner, B.A. Sexton, G.A. Somorjai, Surf. Sci. 71 (1978) 519.
3. P.A. Thiel, E.D. Williams, J.T. Yates, W.H. Weinberg, Surf. Sci. 84 (1979) 54.
4. R.J. Koestner, M.A. Van Hove, G.A. Somorjai, Surf. Sci. 107 (1981) 439.
5. M.A. Van Hove, R.J. Koestner, J.C. Frost, G.A. Somorjai, Surf. Sci. 129 (1983) 482.
6. M. Gierer, A. Barbieri, M.A. Van Hove, G.A. Somorjai, to be published.
7. H. Over, S. Schwegmann, G. Ertl, D. Cvetko, V. De Renzi, L. Floreano, R. Gotter, A. Morgante, M. Peloi, F. Tommasini, S. Zennaro, Surf. Sci. 376 (1997) 177.
8. L.A. DeLouise, E.J. White, N. Winograd, Surf. Sci. 147 (1984) 252.
9. L.H. Dubois, G.A. Somorjai, Surf. Sci. 91 (1980) 514.
10. A. Beutler, E. Lundgren, R. Nyholm, J.N. Andersen, B. Setlik, D. Heskett, Surf. Sci. 371 (1997) 382.
11. E. Lundgren, J. Alvarez, S. Ferrer, A. Beutler, J.N. Andersen, H. Over, to be published.
12. R. Nyholm, S. Svensson, J. Nordgren, S.A. Flodström, Nucl. Instrum. Methods A 246 (1986) 267.
13. J.N. Andersen, O. Björneholm, A. Sandell, R. Nyholm, J. Forsell, L. Thånell, A. Nilsson, N. Mårtensson, Synchrotron Radiat. News 4 (4) (1991) 15.
14. J.J. Yeh, I. Lindau, Atom. Data Nucl, Data Tables 32 (1985) 1.
15. J.N. Andersen, D. Hennig, E. Lundgren, M. Methfessel, R. Nyholm, M. Scheffler, Phys. Rev. B 50 (1994) 17525.
16. S. Donjiac, M. Šunjić, J. Phys. C 3 (1970) 285.
17. H. Antonsson, A. Nilsson, N. Mårtensson, I. Panas, P.E.M. Siegbahn, J. Electron Spectrosc. Relat. Phenom. 54/55 (1990) 601.
18. J.N. Andersen, M. Quarford, R. Nyholm, S.L. Sörensen, C. Wigren, Phys. Rev. Lett. 67 (1991) 2822.
19. O. Björneholm, A. Nilsson, E.O.F. Zdansky, A. Sandell, B. Hernnäs, H. Tillborg, J.N. Andersen, N. Mårtensson, Phys. Rev. B 46 (1992) 10353.
20. J.A. Jaworowski, A. Beutler, F. Strisland, R. Nyholm, D. Heskett, B. Setlik, J.N. Andersen, to be published.
21. F. Strisland, A. Beutler, J.A. Jaworowski, R. Nyholm, J.N. Andersen, D. Heskett, B. Setlik, to be published.
22. M. Zacchigna, C. Astaldi, K.C. Prince, M. Sastry, C. Comicioli, R. Rosei, C, Quaresima, C. Ottaviani, C. Crotti, A. Antonini, M. Matteucci, P. Perfetti, Surf. Sci. 347 (1996) 53.
23. A. Borg, C. Berg, S. Raaen, H.J. Venvik, J. Phys. Condens. Matter 6 (1994) L7.
24. This line of reasoning of course implicitly assumes that the CO overlayer structures do not develop via island growth. From the development of the LEED patterns this is known to be the case (see, e.g., Refs. [2,3]).
25. A. Nilsson, N. Mårtensson, Solid State Commun. 70 (1989) 923.
26. S.L. Tang, M.B. Lee, Q,Y. Yang, J.D. Beckerle, S.T. Ceyer, J. Chem. Phys. 84 (1986) 1876.
27. B.A. Gurney, L.J. Richter, J.S. Villarrubia, W. Ho, J. Chem. Phys. 87 (1987) 6710.
28. J. Yoshinobu, N. Tagaki, M. Kawai, Chem. Phys. Lett. 211 (1993) 48.
29. A. Grossmann, W. Erley, H. Ibach, Phys. Rev. Lett. 71 (1993) 2078.
30. J. Yoshinobu, N. Tagaki, M. Kawai, Phys. Rev. B 49 (1994) 16670.