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Volumn 10, Issue 10, 2010, Pages 4227-4230

Polyoxometalate-based porous framework with perovskite topology

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION BEHAVIOR; N-DONOR LIGANDS; PEROVSKITE STRUCTURES; POLYOXOMETALATES; PYRIDYL; TOPOLOGICAL ANALYSIS; WELLS-DAWSON;

EID: 77957715263     PISSN: 15287483     EISSN: 15287505     Source Type: Journal    
DOI: 10.1021/cg100783w     Document Type: Conference Paper
Times cited : (42)

References (61)
  • 47
    • 77957698458 scopus 로고    scopus 로고
    • note
    • The number of crystallized water molecules in the formula of 1 was established by elemental analysis and TG analysis. The elemental analysis found: C, 8.48; H, 1.94; N, 1.57% (calcd: C, 8.25; H, 1.81; N, 1.48%). The ICP analysis showed that 1 contained 58.95% W, 3.22% Ni and 1.18% P (calcd: W, 58.31; Ni, 3.10; P, 1.09%). The TG curve of 1 (Figure S8, Supporting Information) shows a total weight loss of 20.22% in the range of 46-685 °C, which agrees with the calculated value of 19.99%. The weight loss of 9.64% at 46-320 °C corresponds to the loss of all crystallized water molecules and coordinated water molecules (calc. 9.52%). The weight loss of 10.58% at 340-685 °C arises from the loss of bpp ligands (calc. 10.47%).
  • 48
    • 77957693041 scopus 로고    scopus 로고
    • note
    • -1): 3394 (br), 1614 (s), 1558 (w), 1504 (w), 1425 (m), 1224 (w), 1081 (vs), 1025 (w), 948 (s), 881 (w), 784 (vs) and 520 (m) (Figure S9, Supporting Information).
  • 49
    • 77957698994 scopus 로고    scopus 로고
    • note
    • 2. All calculations were performed using the SHELX97 program package. The hydrogen atoms attached to carbon atoms were fixed in calculated positions. CCDC 733909 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.