A coordination network that catalyzes O2-based oxidations

Journal of the American Chemical Society

Volumn 129, Issue 49, 2007, Pages 15094-15095

  Jong, Woo Han ^a   Hill, Craig L ^a  

^a EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SOLVENT;

ARTICLE; CATALYSIS; ENVIRONMENTAL TEMPERATURE; INFRARED RADIATION; OXIDATION; OXIDATION REDUCTION REACTION; POROSITY; THERMOGRAVIMETRY; THERMOSTABILITY; X RAY POWDER DIFFRACTION;

EID: 37049020478     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja069319v     Document Type: Article

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25. As is the usual case for highly porous materials, the pores of Tb1 contain many disordered and dynamic solvent molecules which significantly impact the R value. To improve the refinement, the SQUEEZE routine of PLATON was applied to treat the diffuse electron density. Crystal data for Tb1: monoclinic P21/c, a = 13.102(4) Å, b = 26.279(9) Å, c = 26.104(6) Å, β = 93.923(5)°, V = 8967(5) Å, Z = 4, Mo Kα (0.71073 Å) radiation (T = 100 K), R1 = 0.1378 [0.0879], wR2 = 0.3474 [0.2295] with I > 2σ(I). Statistics after using SQUEEZE are bracketed.
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