Functional electrospun polystyrene nanofibers incorporating α-, β-, and γ-cyclodextrins: Comparison of molecular filter performance

ACS Nano

Volumn 4, Issue 9, 2010, Pages 5121-5130

  Uyar, Tamer ^a,b   Havelund, Rasmus ^a   Hacaloglu, Jale ^c   Besenbacher, Flemming ^a   Kingshott, Peter ^a  

^a AARHUS UNIVERSITY   (Denmark)

^b BILKENT UNIVERSITY   (Turkey)

^c MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

cyclodextrin; electrospinning; molecular filter; nanofiber; nanoweb; polystyrene

Indexed keywords

CDS; COMPARATIVE EFFICIENCIES; DIFFERENT SIZES; ELECTROSPUNS; FIBER DIAMETERS; FIBER SURFACE; FRAGMENT IONS; INTERACTION STRENGTH; MOLECULAR FILTERS; MOLECULAR IONS; NANOWEB; ORGANIC MOLECULES; POLYSTYRENE NANOFIBERS; PYROLYSIS MASS SPECTROMETRY; RELATIVE BINDING; SELECTIVE INCLUSION; SEM; SEPARATION PROCESS; STATIC TIME; TOF SIMS; UV-VIS SPECTROMETRY;

CYCLODEXTRINS; ELECTROSPINNING; IONS; MOLECULAR OXYGEN; MOLECULES; NANOFIBERS; POLYSTYRENES; PYROLYSIS; SCANNING ELECTRON MICROSCOPY; SECONDARY ION MASS SPECTROMETRY; SILANES; SPECTROMETRY; X RAY PHOTOELECTRON SPECTROSCOPY;

DATA STORAGE EQUIPMENT;

ALPHA CYCLODEXTRIN DERIVATIVE; BETA CYCLODEXTRIN DERIVATIVE; CYCLODEXTRIN; GAMMA CYCLODEXTRIN DERIVATIVE; NANOFIBER; PHENOLPHTHALEIN; POLYSTYRENE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; COMPARATIVE STUDY; CONFORMATION; FILTRATION; MASS SPECTROMETRY; METHODOLOGY; NANOTECHNOLOGY; SOLUTION AND SOLUBILITY; SURFACE PROPERTY; ULTRAVIOLET SPECTROPHOTOMETRY; X RAY PHOTOELECTRON SPECTROSCOPY;

ALPHA-CYCLODEXTRINS; BETA-CYCLODEXTRINS; CYCLODEXTRINS; FILTRATION; GAMMA-CYCLODEXTRINS; MASS SPECTROMETRY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NANOFIBERS; NANOTECHNOLOGY; PHENOLPHTHALEIN; PHOTOELECTRON SPECTROSCOPY; POLYSTYRENES; SOLUTIONS; SPECTROPHOTOMETRY, ULTRAVIOLET; SURFACE PROPERTIES;

EID: 77957312500     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn100954z     Document Type: Article

References (42)

1. Greiner, A.; Wendorff, J. H. Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers Angew. Chem., Int. Ed. 2007, 46, 5670-5703
2. Li, D.; Xia, Y. N. Electrospinning of Nanofibers: Reinventing the Wheel Adv. Mater. 2004, 16, 1151-1170
3. Lu, X.; Wang, C.; Wei, Y. One-Dimensional Composite Nanomaterials: Synthesis by Electrospinning and Their Applications Small 2009, 5, 2349-2370
4. He, D.; Hu, B.; Yao, Q.-F.; Wang, K.; Yu, S.-H. Large-Scale Synthesis of Flexible Free-Standing SERS Substrates with High Sensitivity: Electrospun PVA Nanofibers Embedded with Controlled Alignment of Silver Nanoparticles ACS Nano 2009, 3, 3993-4002
5. Barhate, R. S.; Ramakrishna, S. Nanofibrous Filtering Media: Filtration Problems and Solutions from Tiny Materials J. Membr. Sci. 2007, 296, 1-8
6. Barhate, R. S.; Loong, C. K.; Ramakrishna, S. Preparation and Characterization of Nanofibrous Filtering Media J. Membr. Sci. 2006, 283, 209-218
7. Bjorge, D.; Daels, N.; De Vrieze, S.; Dejans, P.; Van Camp, T.; Audenaert, W.; Hogie, J.; Westbroek, P.; Clerck, K. D.; Hulle, S. W. H. V. Performance Assessment of Electrospun Nanofibers for Filter Applications Desalination 2009, 249, 942-948
8. Ramakrishna, S.; Fujihara, K.; Teo, W. E.; Yong, T.; Ma, Z.; Ramaseshan, R. Electrospun Nanofibers: Solving Global Issues Mater. Today 2006, 9, 40-50
9. Szejtli, J. Cyclodextrins in the Textile Industry Starch/Staerke 2003, 55, 191-196
10. Crini, G.; Morcellet, M. Synthesis and Applications of Adsorbents Containing Cyclodextrins J. Sep. Sci. 2002, 25, 789-813
11. Aoki, N.; Nishikawa, M. Synthesis of Chitosan Derivatives Bearing Cyclodextrin and Adsorption of p -Nonylphenol and Bisphenol A Carbohydr. Polym. 2003, 52, 219-223
12. Olah, J.; Cserhati, T.; Szejtli, J. β-Cyclodextrin Enhanced Biological Detoxification of Industrial Waste Waters Water Res. 1988, 22, 1345-1351
13. Uyar, T.; Hunt, M. A.; Gracz, H. S.; Tonelli, A. E. Crystalline Cyclodextrin Inclusion Compounds Formed with Aromatic Guests: Guest-Dependent Stoichiometries and Hydration-Sensitive Crystal Structures Cryst. Growth Des. 2006, 6, 1113-1119
14. Uyar, T.; Havelund, R.; Nur, Y.; Hacaloglu, J.; Besenbacher, F.; Kingshott, P. Molecular Filters Based on Cyclodextrin Functionalized Electrospun Fibers J. Membr. Sci. 2009, 332, 129-137
15. Kaur, S.; Kotaki, M.; Ma, Z.; Gopal, R.; Ramakrishna, S. Oligosaccharide Functionalized Nanofibrous Membrane Int. J. Nanosci. 2006, 5, 1-11
16. Szejtli, J. Introduction and General Overview of Cyclodextrin Chemistry Chem. Rev. 1998, 98, 1743-1753
17. Hedges, A. R. Industrial Applications of Cyclodextrins Chem. Rev. 1998, 98, 2035-2044
18. Wenz, G.; Han, B.-H.; Muller, A. Cyclodextrin Rotaxanes and Polyrotaxanes Chem. Rev. 2006, 106, 782-817
19. Del Valle, E. M. M. Cyclodextrins and Their Uses: A Review Process Biochem. 2004, 39, 1033-1046
20. Saenger, W.; Jacob, J.; Gessler, K.; Steiner, T.; Hoffmann, D.; Sanbe, H.; Koizumi, K.; Smith, S. M.; Takaha, T. Structures of the Common Cyclodextrins and Their Larger Analogues-Beyond the Doughnut Chem. Rev. 1998, 98, 1787-1802
21. Connors, K. A. The Stability of Cyclodextrin Complexes in Solution Chem. Rev. 1997, 97, 1325-1357
22. Rekharsky, M. V.; Inoue, Y. Complexation Thermodynamics of Cyclodextrins Chem. Rev. 1998, 98, 1875-1917
23. Uyar, T.; Kingshott, P.; Besenbacher, F. Electrospinning of Cyclodextrin-Pseudopolyrotaxane Nanofibers Angew. Chem., Int. Ed. 2008, 47, 9108-9111
24. Uyar, T.; Balan, A.; Toppare, L.; Besenbacher, F. Electrospinning of Cyclodextrin Functionalized Poly(methyl methacrylate) (PMMA) Nanofibers Polymer 2008, 50, 475-480
25. Uyar, T.; Besenbacher, F. Electrospinning of Cyclodextrin Functionalized Polyethylene Oxide (PEO) Nanofibers Eur. Polym. J. 2009, 45, 1032-1037
26. Uyar, T.; Havelund, R.; Hacaloglu, J.; Zhou, X.; Besenbacher, F.; Kingshott, P. Formation and Characterization of Cyclodextrin Functionalized Polystyrene Nanofibers Produced by Electrospinning Nanotechnology 2009, 20, 125605-125618
27. Uyar, T.; Hacaloglu, J.; Besenbacher, F. Electrospun Polystyrene Fibers Containing High Temperature Stable Volatile Fragrance/Flavor Facilitated by Cyclodextrin Inclusion Complexes React. Funct. Polym. 2009, 69, 145-150
28. Uyar, T.; Nur, Y.; Hacaloglu, J.; Besenbacher, F. Electrospinning of Functional Poly(methyl methacrylate) (PMMA) Nanofibers Containing Cyclodextrin-Menthol Inclusion Complexes Nanotechnology 2009, 20, 125703-125712
29. Hunley, M. T.; Harber, A.; Orlicki, J. A.; Rawlett, A. M.; Long, T. E. Effect of Hyperbranched Surface-Migrating Additives on the Electrospinning Behavior of Poly(methyl methacrylate) Langmuir 2008, 24, 654-657
30. Walton, D. G.; Soo, P. P.; Mayes, A. M.; Sofia Allgor, S. J.; Fujii, J. T.; Griffith, L. G.; Ankner, J. F.; Kaiser, H.; Johansson, J.; Smith, G. D.; Barker, J. G.; Satija, S. K. Creation of Stable Poly(ethylene oxide) Surfaces on Poly(methyl methacrylate) Using Blends of Branched and Linear Polymers Macromolecules 1997, 30, 6947-6956
31. Hariharan, A.; Kumar, S. K.; Russell, T. P. A Lattice Model for the Surface Segregation of Polymer Chains Due to Molecular Weight Effects Macromolecules 1990, 23, 3584-3592
32. Walton, D. G.; Mayes, A. M. Entropically Driven Segregation in Blends of Branched and Linear Polymers Phys. Rev. E 1996, 54, 2811-2815
33. Hunt, M. A.; Jung, D.-W.; Shamsheer, M.; Uyar, T.; Tonelli, A. E. Polystyrenes in Channels Polymer 2004, 45, 1345-1347
34. Uyar, T.; Gracz, H. S.; Rusa, M.; Shin, I. D.; El-Shafei, A.; Tonelli, A. E. Polymerization of Styrene in γ-Cyclodextrin Channels: Lightly Rotaxanated Polystyrenes with Altered Stereosequences Polymer 2006, 47, 6948-6955
35. Taguchi, K. Transient Binding of Phenolphthalein-β-Cyclodextrin Complex: An Example of Induced Geometrical Distortion J. Am. Chem. Soc. 1986, 108, 2705-2709
36. Buvári, Á.; Barcza, L.; Kajtár, M. J. Complex Formation of Phenolphthalein and Some Related Compounds with β-Cyclodextrin J. Chem. Soc., Perkin Trans. 2 1988, 168, 7-1690
37. Meier, M. M.; Bordignon Luiz, M. T.; Farmer, P. J.; Szpoganicz, B. The Influence of β- and γ-Cyclodextrin Cavity Size on the Association Constant with Decanoate and Octanoate Anions J. Inclusion Phenom. 2001, 40, 291-295
38. Mohamed, M. H.; Wilson, L. D.; Headley, J. V. Estimation of the Surface Accessible Inclusion Sites of β-Cyclodextrin Based Copolymer Materials Carbohydr. Polym. 2010, 80, 186-196
39. Uyar, T.; El-Shafei, A.; Wang, X.; Hacaloglu, J.; Tonelli, A. E. The Solid Channel Structure Inclusion Complex Formed between Guest Styrene and Host γ-Cyclodextrin J. Incl. Phenom. Macrocycl. Chem. 2006, 55, 109-121
40. Uyar, T.; Tonelli, A. E.; Hacaloglu, J. Thermal Degradation of Polycarbonate, Poly(vinyl acetate) and Their Blends Polym. Degrad. Stab. 2006, 91, 2960-2967
41. Uyar, T.; Rusa, C. C.; Tonelli, A. E.; Hacaloglu, J. Pyrolysis Mass Spectrometry Analysis of Polycarbonate/Poly(methyl methacrylate)/Poly(vinyl acetate) Ternary Blends Polym. Degrad. Stab. 2007, 92, 32-43
42. Uyar, T.; Toppare, L.; Hacaloglu, J. Thermal and Structural Characterization of Polypyrrole by Direct-Insertion Probe Pyrolysis Mass Spectrometry Synth. Met. 2001, 119, 307-308 (Pubitemid 32475291)