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36849021014
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Alternatively, we developed in our laboratory a new Fe-catalyzed method to access 1,2-bis(trimethylsilyl)benzenes:
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Bettinger, H. F.; Filthaus, M. J. Org. Chem. 2007, 72, 9750 Alternatively, we developed in our laboratory a new Fe-catalyzed method to access 1,2-bis(trimethylsilyl)benzenes:
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3N) to yield a colorless oil (28.4 mg, 42%)
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3N) to yield a colorless oil (28.4 mg, 42%).
-
-
-
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46
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0000469763
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The elimination of the pyrrolidine was completed using m -CPBA
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The elimination of the pyrrolidine was completed using m -CPBA: Chenard, B. L.; Ronau, R. T.; Schulte, G. K. J. Org. Chem. 1988, 53, 5175
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77956583818
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For an example of an IEDDA with 1,2,4-triazenes with enamines, generated in situ, see
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For an example of an IEDDA with 1,2,4-triazenes with enamines, generated in situ, see
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-
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50
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0002673332
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Boger, D. L.; Panek, J. S.; Meier, M. M. J. Org. Chem. 1982, 47, 895
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The mixture of regioisomers in Table 1, entry 8, is caused by isomerization of the double bond to the exo -position
-
The mixture of regioisomers in Table 1, entry 8, is caused by isomerization of the double bond to the exo -position
-
-
-
-
53
-
-
77956583303
-
-
The elimination to the aromatic product was completed using UV irradiation
-
The elimination to the aromatic product was completed using UV irradiation
-
-
-
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54
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Sauer, J.; Baöuerlein, P.; Ebenbeck, W.; Fuöllhuber, H.; Gousetis, C.; Wernthaler, K. Eur. J. Org. Chem. 2001, 3999
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