Chemistry of butadienesulfinate salts with (Cp*RhCl2) 2 and the reactivity of their derivatives with tertiary phosphines

Organometallics

Volumn 29, Issue 17, 2010, Pages 3709-3721

  Paz Michel, Brenda A ^a   González Bravo, Felipe J ^a   Hernández Muñoz, Lindsay S ^a   Paz Sandoval, M Angeles ^a  

^a DEPARTAMENTO DE FÍSICA   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

DINUCLEAR; ION PAIRS; NEUTRAL COMPOUNDS; RUTHENIUM COMPLEXES; SPECTROSCOPIC EVIDENCE; TERTIARY PHOSPHINES; THERMODYNAMIC PRODUCTS;

DYES; LIGANDS; LITHIUM; MIXTURES; ORGANOMETALLICS; PHOSPHORUS COMPOUNDS; RHODIUM COMPOUNDS; RUTHENIUM; RUTHENIUM COMPOUNDS; SPECTROSCOPY;

RHODIUM;

EID: 77956418823     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om901108y     Document Type: Article

References (33)

1. Paz-Michel, B. A.; Cervantes-Vasquez, M.; Paz-Sandoval, M. A. Inorg. Chim. Acta 2008, 361, 3094
2. Gamero-Melo, P.; Cervantes-Vasquez, M.; Sanchez-Castro, M. E.; Ramirez-Monroy, A.; Paz-Sandoval, M. A. Organometallics 2004, 23, 3290
3. Gamero-Melo, P.; Villanueva-Garcia, M.; Robles, J.; Contreras, R.; Paz-Sandoval, M. A. J. Organomet. Chem. 2005, 690, 1379
4. Paz-Michel, B. A.; Gonzalez-Bravo, F. J.; Hernandez-Muñoz, L. S.; Paz-Sandoval, M. A. Organometallics, 2010, DOI: 10.1021/om901107n.
5. Paz-Sandoval, M. A.; Rangel-Salas, I. I. Coord. Chem. Rev. 2006, 250, 1071
6. Cervantes-Vasquez, M.; Paz-Sandoval, M. A. Unpublished results
7. 1H NMR to be a mixture of 5-K-Ir, 6-Ir, and 12 in 1.7:6.3:2.0 ratio, respectively. If a higher excess (10 equiv) of 2-K is used, the mixture of products is in a 2.1:4.9:3.0 ratio.
8. 31P NMR showed a nonseparable mixture of 8-S-Ir and 9-Ir.
9. 3 (27.0 μL, 0.250 mmol) at -110 °C. The spectroscopic evidence showed formation of compounds 10- S -Ir, 11, and 12.
10. 3/hexane at room temperature.
11. Yamamoto, Y.; Miyauchi, F. Inorg. Chim. Acta 2002, 334, 77
12. Berenguer, J. R.; Bernechea, M.; Fornies, J.; Gomez, J.; Lalinde, E. Organometallics 2002, 21, 2314
13. Yamamotoa, Y.; Suzuki, H.; Tajima, N.; Tatsumi, K. Chem. - Eur. J. 2002, 8, 372
14. Gauthier, S.; Quebatte, L.; Scopelliti, R.; Severin, K. Chem. - Eur. J. 2004, 11, 2811
15. Gauthier, S.; Scopelliti, R.; Severin, K. Helv. Chim. Acta 2005, 88, 435
16. Ara, I.; Berenguer, J. R.; Eguizabal, E.; Fornies, J.; Lalinde, E.; Martin, A. Eur. J. Inorg. Chem. 2001, 1631
17. Valderrama, M.; Contreras, R.; Boys, D. J. Organomet. Chem. 2003, 665, 7
18. Gonzalez Bravo, F. J., unpublished results. In the case of tetrabutylammonium carboxylates in acetonitrile, it has been observed in our research group that the oxidation wave is enlarged and shifted toward more positive values when alkaline metal salts are added to the solution, which suggests that the negative charge on the carboxylic function is ion-pairing stabilized, and consequently this is less available for electron transfer. This ion-pairing phenomenon falls in line with the low solubility of the alkaline metal salts of carboxylic acids in polar solvents.
19. Jones, W. D.; Kuykendall, V. L. Inorg. Chem. 1991, 30, 2615
20. Kang, J. W.; Moseley, K.; Maitlis, P. M. J. Am. Chem. Soc. 1969, 91, 5970
21. Singh, S. K.; Trivedi, M.; Chandra, M.; Pandey, S. J. Organomet. Chem. 2005, 690, 647
22. Isobe, K.; Bailey, P. M.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1981, 2003
23. Paneque, M.; Maitlis, P. M. J. Chem. Soc., Chem. Commun. 1989, 105
24. Jones, W. D.; Partridge, M. G.; Perutz, R. N. J. Chem. Soc., Chem. Commun. 1991, 264
25. Booth, B. L.; Haszeldine, R. N.; Hill, M. J. Organomet. Chem. 1969, 16, 491
26. Bleeke, J. R.; Shokeen, M.; Wise, E. S.; Rath, N. P. Organometallics 2006, 25, 2486
27. Le Bras, J.; Amouri, H.; Vaisserman, J. J. Organomet. Chem. 1997, 548, 305
28. White, C.; Yates, A.; Maitlis, P. M. Inorg. Synth. 1992, 29, 228
29. Gottlieb, H. E.; Kotlyar, V.; Nudelman, A. J. Org. Chem. 1977, 62, 7512
30. Low, P. M. N.; Yong, Y. L.; Yan, Y. K.; Hor, T. S. A.; Lam, S.-L.; Chan, K. K.; Wu, C.; Au-Yeung, C. F. S.; Wen, Y.-S.; Liu, L.-K. Organometallics 1996, 15, 1369
31. http://www.malvern.com.
32. Sheldrick, G. M. SHELXL, Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1998.
33. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837