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85088231423
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note
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10 is apparent at the end of the reaction.
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43
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2 (X = halides) is well-established, there has been no report of such a complex for X = OMe. We are still trying to isolate this proposed intermediate both from the reaction mixture and by another independent synthetic route. Further results will be reported in due course.
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47
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5244258444
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note
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-1 (2027s, 2010 m, 1924 m, 1893 w, 1885 (sh)). This band is the strongest band in our spectrum. From the reported NMR data, the methylene protons of dppm (3.71 ppm) are more deshielded compared to those of our complex (3.14 ppm). These differences are, however, sufficiently minor that both data sets could infer the structure proposed. Presumably the differences, if any, are conformational in nature.
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