메뉴 건너뛰기




Volumn , Issue 23, 2010, Pages 3577-3585

Molybdenum dithiolene complexes as structural models for the active sites of molybdenum(IV) sulfide hydrodesulfurization catalysts

Author keywords

Desulfurization; Heterogeneous catalysis; Molybdenum; Sulfur

Indexed keywords

CATALYST ACTIVITY; HYDRODESULFURIZATION; LAYERED SEMICONDUCTORS; LIGANDS; MOLYBDENUM COMPOUNDS; SYNTHESIS (CHEMICAL); THIOPHENE;

EID: 77955969883     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201000269     Document Type: Article
Times cited : (12)

References (56)
  • 10
    • 85152984484 scopus 로고    scopus 로고
    • This simple picture is based on the structure of bulk material and neglects surface reconstruction
    • This simple picture is based on the structure of bulk material and neglects surface reconstruction.
  • 11
    • 0004120037 scopus 로고    scopus 로고
    • (based on Johnson, C. K.; Burnett, M. N. ORTEP-3 Version 1.0.3)
    • ORTEP-3 for Windows, Version 1.08 (based on Johnson, C. K.; Burnett, M. N. ORTEP-3 Version 1.0.3)
    • ORTEP-3 for Windows Version 1.08
  • 33
    • 85152991511 scopus 로고    scopus 로고
    • Note
    • [30]. but inversely scaled so that trigonal prismatic character is 100% while octahedral is 0%.
  • 34
    • 85153003169 scopus 로고    scopus 로고
    • [31] and by taking the difference between the smallest and largest angles in the remaining six
    • [31] and by taking the difference between the smallest and largest angles in the remaining six.
  • 36
    • 85152997158 scopus 로고    scopus 로고
    • 2g orbitals (in an octahedral fielare destabilized
    • 2g orbitals (in an octahedral fielare destabilized.
  • 41
    • 85152985098 scopus 로고    scopus 로고
    • A variety of resonance forms can be envisioned for neutral group VI metal trisdithiolenes: the most reasonable contributors, in light of computational and spectroscopic evidence, have metal oxidation states of IV or V (singlet diradical character for the latter case)
    • A variety of resonance forms can be envisioned for neutral group VI metal trisdithiolenes: the most reasonable contributors, in light of computational and spectroscopic evidence, have metal oxidation states of IV or V (singlet diradical character for the latter case).
  • 42
    • 33947335405 scopus 로고
    • For early MO calculations on metal trisdithiolenes, see. For more recent discussions on the electronic structures of metal trisdithiolenes
    • For early MO calculations on metal trisdithiolenes, see: E. I. Stiefel, R. Eisenberg, R. Rosenberg, H. B. Gray, J. Am. Chem. Soc. 1966, 88, 2956-2966. For more recent discussions on the electronic structures of metal trisdithiolenes, see:
    • (1966) J. Am. Chem. Soc. , vol.88 , pp. 2956-2966
    • Stiefel, E.I.1    Eisenberg, R.2    Rosenberg, R.3    Gray, H.B.4
  • 50
    • 0004090012 scopus 로고    scopus 로고
    • Organometallic modeling of the hydrodesulfurization and hydrodenitrogenation reactions
    • D. Reidel, Dordrecht, Holland
    • R. A. Sánchez-Delgado, "Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions" in Catalysis by Metal Complexes, D. Reidel, Dordrecht, Holland, 2004, vol. 24, pp. 95-137.
    • (2004) Catalysis by Metal Complexes , vol.24 , pp. 95-137
    • Sánchez-Delgado, R.A.1
  • 56
    • 0000766887 scopus 로고    scopus 로고
    • Effective core potentials
    • John von Neuman Institute for Computing, Jülich
    • M. Dolg, "Effective Core Potentials" In Modern Methods and Algorithms of Quantum Chemistry, John von Neuman Institute for Computing, Jülich, 2000, vol. 1, p. 479.
    • (2000) Modern Methods and Algorithms of Quantum Chemistry , vol.1 , pp. 479
    • Dolg, M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.