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Volumn 29, Issue 14, 2010, Pages 3179-3186

Spectra and synthetic-time-scale substitution reactions of electrochemically produced [Cr(CO)3(η6-arene)] + complexes

Author keywords

[No Author keywords available]

Indexed keywords

APPLIED POTENTIALS; BULK ELECTROLYSIS; CHEMICAL CHARACTERISTIC; ELECTROCHEMICAL BEHAVIORS; ELECTROCHEMICAL SWITCH; ESR SPECTROSCOPY; IN-SITU; LIGAND SUBSTITUTION; METAL CARBONYL; RADICAL CATIONS; SUBSTITUTION PRODUCTS; SUPPORTING ELECTROLYTE; SYNTHETIC ROUTES; SYNTHETIC-TIME; SYSTEMATIC STUDY;

EID: 77955874050     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100318q     Document Type: Article
Times cited : (25)

References (70)
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    • 3 arene complexes are given in ref 8 of this paper
    • 3 (arene) complexes are given in ref 8 of this paper.
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    • + were confirmed by an in situ spectroelectrochemical experiment based on the fiber-optic technique described earlier
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    • frequency of the doubly degenerate asymmetric band is counted twice in the weighted average
    • The frequency of the doubly degenerate asymmetric band is counted twice in the weighted average.
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    • See
    • See pp 5756-5759.
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    • 6, measured under these conditions was-0.22 V
    • 6), measured under these conditions was-0.22 V.
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    • See caption of Figure 6 for details
    • See caption of Figure 6 for details.
  • 56
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    • coulomb counts for the oxidation were consistently less than the theoretical quantity expected for a one-electron process. The reason for this is unclear. We cannot rule out the possibility that some of the complex 2 underwent thermal or photochemical decomposition during the preparation of the solution and the completion of the electrolysis
    • The coulomb counts for the oxidation were consistently less than the theoretical quantity expected for a one-electron process. The reason for this is unclear. We cannot rule out the possibility that some of the complex 2 underwent thermal or photochemical decomposition during the preparation of the solution and the completion of the electrolysis.
  • 57
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    • 6-estradiol at about-0.4 V
    • 6-estradiol) at about-0.4 V.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.