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Volumn 132, Issue 33, 2010, Pages 11461-11463
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Stopped-flow NMR: Determining the kinetics of [ rac -(C2H 4(1-indenyl)2)ZrMe][MeB(C6F5) 3]-catalyzed polymerization of 1-hexene by direct observation
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Author keywords
[No Author keywords available]
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Indexed keywords
1-HEXENE;
ALKENE POLYMERIZATION;
CATALYZED POLYMERIZATION;
CHAIN GROWTH;
COLLINS;
DIRECT OBSERVATION;
DRIVE SYSTEMS;
EFFICIENT METHOD;
FUNCTION OF TIME;
HIGH EFFICIENCY;
HIGH RATE;
HIGH SENSITIVITY;
HYDRIDE ELIMINATION;
IMPRECISE KNOWLEDGE;
INDENYL;
KINETIC MODELING;
KINETIC MODELS;
LOW CONCENTRATIONS;
METALLOCENES;
NMR MEASUREMENTS;
NMR SPECTROSCOPY;
ROOM TEMPERATURE;
SIMULTANEOUS MEASUREMENT;
STOPPED FLOW;
SUBSTRATE CONCENTRATIONS;
TIME-SCALES;
CATALYSIS;
CATALYSTS;
NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;
OLEFINS;
ORGANOMETALLICS;
POLYMERIZATION;
POLYMERS;
RATE CONSTANTS;
ZIRCONIUM;
REACTION KINETICS;
1 HEXENE;
ARTICLE;
CATALYST;
CHEMICAL REACTION KINETICS;
KINETICS;
MEASUREMENT;
NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;
POLYMERIZATION;
SPECIES DIFFERENTIATION;
ALKENES;
CATALYSIS;
COORDINATION COMPLEXES;
KINETICS;
MAGNETIC RESONANCE SPECTROSCOPY;
MOLECULAR STRUCTURE;
POLYVINYLS;
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EID: 77955800060
PISSN: 00027863
EISSN: 15205126
Source Type: Journal
DOI: 10.1021/ja105107y Document Type: Article |
Times cited : (83)
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References (16)
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