Exploiting conformational dynamics to facilitate formation and trapping of electron-transfer photoproducts in metal complexes

Journal of the American Chemical Society

Volumn 132, Issue 33, 2010, Pages 11464-11466

  Meylemans, Heather A ^a   Hewitt, Joshua T ^a   Abdelhaq, Mirvat ^a   Vallett, Paul J ^a   Damrauer, Niels H ^a  

^a UNIVERSITY OF COLORADO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARYL SUBSTITUENTS; BACK ELECTRON TRANSFER; BIPYRIDINES; BIPYRIDINIUM; CHARGE-SEPARATED STATE; CONFORMATIONAL DYNAMICS; DIHEDRAL ANGLES; DRIVING FORCES; ELECTROCHEMICAL MEASUREMENTS; ELECTRON DELOCALIZATION; ELECTRON-TRANSFER; ELECTRONIC COUPLING; EMISSION SPECTRUMS; FRANCK-CONDON ANALYSIS; FS LASER PULSE; MODEL COMPLEXES; NEW STRATEGY; PHOTO-INDUCED ELECTRON TRANSFER; PHOTOINDUCED ELECTRONS; PHOTOPRODUCTS; STERIC BULK; STERIC CONTROL; STERIC REPULSIONS; SUBSTITUTED BIPYRIDINE LIGAND; SUBSTITUTION PATTERNS; TIME CONSTANTS; TORSIONAL DYNAMICS;

DYNAMICS; ELECTRON TRANSITIONS; EMISSION SPECTROSCOPY; LIGANDS; METAL COMPLEXES; PHOTOEXCITATION; PULSED LASER APPLICATIONS; SUBSTITUTION REACTIONS;

EXCITED STATES;

METAL COMPLEX; PYRIDINE DERIVATIVE; PYRIDINIUM DERIVATIVE; RUTHENIUM;

ARTICLE; CONFORMATION; ELECTRON TRANSPORT; EXCITATION; GEOMETRY; HUMAN; LASER; MECHANICAL TORSION; MOLECULAR DYNAMICS; STEREOSPECIFICITY; SUBSTITUTION REACTION;

COMPUTER SIMULATION; ELECTROCHEMISTRY; ELECTRONS; LIGANDS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHOTOCHEMISTRY; PYRIDINIUM COMPOUNDS; STEREOISOMERISM; THERMODYNAMICS;

EID: 77955795024     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1055559     Document Type: Article

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