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24
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0001320889
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For previous eT studies of DSAs in which through-solvent coupling has been implicated, see: (a) Oliver, A. M.; Craig, D. C.; Paddon-Row, M. N : Kroon, J.; Verhoeven. J. W. Chem. Phys. Lett. 1988, 150, 366. (b) Liu, J.-y.; Schmidt, J. A.; Bolton, J. R. J. Phys. Chem. 1991, 95, 6924. (c) Lawson, J. M., et al. J. Phys. Chem. 1993, 97, 13099. (d) Sakata, Y.; et al. J. Am. Chem. Soc. 1994, 116, 6904.
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25
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0000703203
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For previous eT studies of DSAs in which through-solvent coupling has been implicated, see: (a) Oliver, A. M.; Craig, D. C.; Paddon-Row, M. N : Kroon, J.; Verhoeven. J. W. Chem. Phys. Lett. 1988, 150, 366. (b) Liu, J.-y.; Schmidt, J. A.; Bolton, J. R. J. Phys. Chem. 1991, 95, 6924. (c) Lawson, J. M., et al. J. Phys. Chem. 1993, 97, 13099. (d) Sakata, Y.; et al. J. Am. Chem. Soc. 1994, 116, 6904.
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Lawson, J.M.1
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26
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For previous eT studies of DSAs in which through-solvent coupling has been implicated, see: (a) Oliver, A. M.; Craig, D. C.; Paddon-Row, M. N : Kroon, J.; Verhoeven. J. W. Chem. Phys. Lett. 1988, 150, 366. (b) Liu, J.-y.; Schmidt, J. A.; Bolton, J. R. J. Phys. Chem. 1991, 95, 6924. (c) Lawson, J. M., et al. J. Phys. Chem. 1993, 97, 13099. (d) Sakata, Y.; et al. J. Am. Chem. Soc. 1994, 116, 6904.
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-
40
-
-
85033864177
-
-
note
-
-A. where S is solvent or spacer.
-
-
-
-
41
-
-
85033840653
-
-
note
-
6e
-
-
-
-
42
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0000338046
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Kumar, K.; Tepper, R.; Zeng, Y.; Zimmt, M. B. J. Org. Chem. 1995. 60, 4051.
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Kumar, K.1
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Zimmt, M.B.4
-
45
-
-
85033845877
-
-
note
-
15
-
-
-
-
46
-
-
85033849064
-
-
note
-
s(295 K) are listed in Table 1.
-
-
-
-
47
-
-
0004078543
-
-
Weissberger, A., ed ; Wiley Interscience: New York
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(b) Riddick, J. A.; Bunger, W. B.; Sakano, T. K. Techniques of Chemistry, 4th ed.; Weissberger, A., ed ; Wiley Interscience: New York, 1986; Vol. II.
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Riddick, J.A.1
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48
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33750193907
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Kestner, N. R.; Logan, J.; Jortner, J. J. Phys. Chem. 1974, 78, 2148.
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-
49
-
-
85033851536
-
-
note
-
(a) The H atoms directed toward the clamp interior on C2, C5, and CS of the bridge (anthracenonorbornene bridgehead is C1) are separated by 1.95 and 2.03 Å, pairwise respectively,
-
-
-
-
50
-
-
85033855736
-
-
CAChe Scientific
-
(b) Distances, energies, and geometry optimizations performed using the MM2 force field implemented in CAChe Mechanics, Version 3.6. CAChe Scientific, 1994.
-
(1994)
CAChe Mechanics, Version 3.6
-
-
-
52
-
-
85033857949
-
-
note
-
15 |V|'s are not scaled. The corresponding "experimental" |V| at this geometry is not known.
-
-
-
-
54
-
-
85033835453
-
-
note
-
14b
-
-
-
-
55
-
-
85033838950
-
-
CAChe Scientific.
-
19b LUMO energies are 0.66, 1.67, and 1.66 eV for PhCN. MeCN, and DMA, respectively (MOPAC Version 94.1 in CAChe, Version 3.6. CAChe Scientific. 1994).
-
(1994)
MOPAC Version 94.1 in CAChe, Version 3.6
-
-
-
60
-
-
85033839188
-
-
note
-
+) ].
-
-
-
-
61
-
-
85033849588
-
-
note
-
-)A mediating state energy for 4 in the higher refractive index solvent, PhCN, will be lower. The eT activation energy for 4 in PhCN is 0.06 eV.
-
-
-
-
65
-
-
85033862712
-
-
note
-
The solvent dependence of |V| in DSA 3 suggests some contribution of solvent-mediated couplina.
-
-
-
|