Metal-organic frameworks with functional pores for recognition of small molecules

Accounts of Chemical Research

Volumn 43, Issue 8, 2010, Pages 1115-1124

  Chen, Banglin ^a   Xiang, Shengchang ^a   Qian, Guodong ^b  

^a UNIVERSITY OF TEXAS AT SAN ANTONIO   (United States)

^b ZHEJIANG UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 77955696750     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar100023y     Document Type: Article

References (57)

1. Hoskins, B. F.; Robson, R. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments J. Am. Chem. Soc. 1989, 111, 5962-5964
2. n (M = Co, Ni, Zn) Angew. Chem., Int. Ed. Engl. 1997, 36, 1725-1727
3. Li, H.; Eddaoudi, M.; O'Keeffe, M.; Yaghi, M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework Nature 1999, 402, 276-279
4. n Science 1999, 283, 1148-1150
5. Chen, B.; Eddaoudi, M.; Hyde, S. T.; O'Keeffe, M.; Yaghi, O. M. Interwoven metal-organic framework on a periodic minimal surface with extra-large pores Science 2001, 291, 1021-1023
6. Ferey, G. Materials science: The simplicity of complexity-Rational design of giant pores Science 2001, 291, 994-995
7. Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y. J.; Kim, K. A homochiral metal-organic porous material for enantioselective separation and catalysis Nature 2000, 404, 982-986
8. Eddaoudi, M.; Kim, J.; Rosi, N.; Vodak, D.; Wachter, J.; O'Keeffe, M.; Yaghi, O. M. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage Science 2002, 295, 469-472
9. Hu, A.; Ngo, H. L.; Lin, W. Chiral porous hybrid solids for practical heterogeneous asymmetric hydrogenation of aromatic ketones J. Am. Chem. Soc. 2003, 125, 11490-11491
10. Zhao, X.; Xiao, B.; Fletcher, A. J.; Thomas, K. M.; Bradshaw, D.; Rosseinsky, M. J. Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks Science 2004, 306, 1012-1015
11. Ferey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour, J.; Surble, S.; Margiolaki, I. A chromium terephthalate-based solid with unusually large pore volumes and surface area Science 2005, 309, 2040-2042
12. Park, Y. K.; Choi, S. B.; Kim, H.; Kim, K.; Won, B.-H.; Choi, K.; Choi, J.-S.; Ahn, W.-S.; Won, N.; Kim, S.; Jung, D. H.; Choi, S.-H.; Kim, G.-H.; Cha, S.-S.; Jhon, Y. H.; Yang, J. K.; Kim, J. Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter Angew. Chem., Int. Ed. 2007, 46, 8230-8233
13. Serre, C.; Mellot-Draznieks, C.; Surble, S.; Audebrand, N.; Filinchuk, Y.; Ferey, G. Role of solvent-host interactions that lead to very large swelling of hybrid frameworks Science 2007, 315, 1828-1831
14. Horike, S.; Shimomura, S.; Kitagawa, S. Soft porous crystals Nat. Chem. 2009, 1, 695-704
15. Long, J. R.; Yaghi, O. M. The pervasive chemistry of metal-organic frameworks Chem. Soc. Rev. 2009, 38, 1213-1214
16. Lin, W.; Zhou, H.-C. MOFs, What are they good for? Presented at the MOF symposium of 235th ACS National Meeting, New Orleans, LA, United States, April 6-10, 2008.
17. Chen, S.; Zhang, J.; Wu, T.; Feng, P.; Bu, X. Multiroute synthesis of porous anionic frameworks and size-tunable extraframework organic cation-controlled gas sorption properties J. Am. Chem. Soc. 2009, 131, 16027-16029
18. Lin, X.; Telepeni, I.; Blake, A. J.; Dailly, A.; Brown, C. M.; Simmons, J. M.; Zoppi, M.; Walker, G. S.; Thomas, K. M.; Mays, T. J.; Hubberstey, P.; Champness, N. R.; Schroder, M. High capacity hydrogen adsorption in Cu(II) tetracarboxylate framework materials: The role of pore size, ligand functionalization, and exposed metal sites J. Am. Chem. Soc. 2009, 131, 2159-2171
19. Zhang, J.-P.; Chen, X.-M. Optimized acetylene/carbon dioxide sorption in a dynamic porous crystal J. Am. Chem. Soc. 2009, 131, 5516-5521
20. Ma, S.; Sun, D.; Yuan, D.; Wang, X.-S.; Zhou, H.-C. Preparation and gas adsorption studies of three mesh-adjustable molecular sieves with a common structure J. Am. Chem. Soc. 2009, 131, 6445-6451
21. Mulfort, K. L.; Farha, O. K.; Stern, C. L.; Sarjeant, A. A.; Hupp, J. T. Post-synthesis alkoxide formation within metal-organic framework materials: A strategy for incorporating highly coordinatively unsaturated metal ions J. Am. Chem. Soc. 2009, 131, 3866-3868
22. 2 capture in flexible 3D coordination polymer networks Angew. Chem., Int. Ed. 2009, 48, 6865-6869
23. Fang, Q.-R.; Zhu, G.-S.; Jin, Z.; Ji, Y.-Y.; Ye, J.-W.; Xue, M.; Yang, H.; Wang, Y.; Qiu, S.-L. Mesoporous metal-organic framework with rare etb topology for hydrogen storage and dye assembly Angew. Chem., Int. Ed. 2007, 46, 6638-6642
24. Lan, A.; Li, K.; Wu, H.; Olson, D. H.; Emge, T. J.; Ki, W.; Hong, M.; Li, J. A luminescent microporous metal-organic framework for the fast and reversible detection of high explosives Angew. Chem., Int. Ed. 2009, 48, 2334-2338
25. Bradshaw, D.; Claridge, J. B.; Cussen, E. J.; Prior, T. J.; Rosseinsky, M. J. Design, chirality, and flexibility in nanoporous molecule-based materials Acc. Chem. Res. 2005, 38, 273-282
26. Nouar, F.; Eubank, J. F.; Bousquet, T.; Wojtas, L.; Zaworotko, M. J.; Eddaoudi, M. Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks J. Am. Chem. Soc. 2008, 130, 1833-1835
27. 2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine-and amino-decorated pores J. Am. Chem. Soc. 2010, 132, 38-39
28. 4 J. Am. Chem. Soc. 2009, 131, 15120-15121
29. 2(dhtp): The important role of open metal sites J. Am. Chem. Soc. 2009, 131, 4995-5000
30. Dybtsev, D. N.; Chun, H.; Kim, K. Rigid and flexible: A highly porous metal-organic framework with unusual guest-dependent dynamic behavior Angew. Chem., Int. Ed. 2004, 43, 5033-5036
31. Ma, B.-Q.; Mulfort, K. L.; Hupp, J. T. Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions Inorg. Chem. 2005, 44, 4912-4914
32. Chen, B.; Ma, S.; Zapata, F.; Fronczek, F. R.; Lobkovsky, E. B.; Zhou, H.-C. Rationally designed micropores within a porous metal-organic framework for selective sorption of gas molecules Inorg. Chem. 2007, 46, 1233-1236
33. Chen, B.; Liang, C.; Yang, J.; Contreras, D. S.; Clancy, Y. L.; Lobkovsky, E. B.; Yaghi, O. M.; Dai, S. A Microporous metal-organic framework for gas chromatographic separation of alkanes Angew. Chem., Int. Ed. 2006, 45, 1390-1393
34. Chen, B.; Ma, S.; Zapata, F.; Lobkovsky, E. B.; Yang, J. Hydrogen adsorption in an interpenetrated dynamic metal-organic framework Inorg. Chem. 2006, 45, 5718-5720
35. Chen, B.; Fronczek, F. R.; Courtney, B. H.; Zapata, F. α-Po nets of copper(II)-trans-1,4-cyclohexanedicarboxylate frameworks based on a paddle-wheel building block and its enlarged dimer Cryst. Growth Des. 2006, 6, 825-828
36. Chen, B.; Ma, S.; Hurtado, E. J.; Lobkovsky, E. B.; Zhou, H.-C. A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules Inorg. Chem. 2007, 46, 8490-8492
37. Chen, B.; Ji, Y.; Xue, M.; Fronczek, F. R.; Hurtado, E. J.; Mondal, J. U.; Liang, C.; Dai, S. Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol Inorg. Chem. 2008, 47, 5543-5545
38. 2 storage density Inorg. Chem. 2008, 47, 6825-6828
39. Chen, B.; Ma, S.; Hurtado, E. J.; Lobkovsky, E. B.; Liang, C.; Zhu, H.; Dai, S. Selective gas sorption within a dynamic metal-organic framework Inorg. Chem. 2007, 46, 8705-8709
40. Chen, Z.; Xiang, S.; Zhao, D.; Chen, B. Reversible two-dimensional-three dimensional framework transformation within a prototype metal-organic framework Cryst. Growth Des. 2009, 9, 5293-5296
41. 2 adsorption in a microporous metal-organic framework with open metal sites Angew. Chem., Int. Ed. 2005, 44, 4745-4749
42. Xiang, S.; Zhou, W.; Gallegos, J. M.; Liu, Y.; Chen, B. Exceptionally high acetylene uptake in a microporous metal-organic framework with open metal sites J. Am. Chem. Soc. 2009, 131, 12415-12419
43. Xiang, S.; Zhou, W.; Zhang, Z.; Liu, Y.; Chen, B. Open metal sites within isostructural metal-organic frameworks for differential recognition of acetylene and extraordinarily high acetylene storage at room temperature. Angew. Chem., Int. Ed. 2010, 49, DOI: 10.1002/anie.201000094.
44. Matsuda1, R.; Kitaura, R.; Kitagawa, S.; Kubota, Y.; Belosludov, R. V.; Kobayashi, T. C.; Sakamoto, H.; Chiba, T.; Takata, M.; Kawazoe, Y.; Mita, Y. Highly controlled acetylene accommodation in a metal-organic microporous material Nature 2005, 436, 238
45. Chen, B.; Yang, Y.; Zapata, F.; Lin, G.; Qian, G.; Lobkovsky, E. B. Luminescent open metal sites within a metal-organic framework for sensing of small molecules Adv. Mater. 2007, 19, 1693-1696
46. Chen, B.; Wang, L.; Xiao, Y.; Fronczek, F. R.; Xue, M.; Cui, Y.; Qian, G. A luminescent metal-organic framework with Lewis basic pyridyl sites for sensing of metal ions Angew. Chem., Int. Ed. 2009, 48, 500-503
47. Chen, B.; Wang, L.; Zapata, F.; Qian, G.; Lobkovsky, E. B. A luminescent microporous metal-organic framework for the recognition and sensing of anions J. Am. Chem. Soc. 2008, 130, 6718-6719
48. Kitaura, R.; Onoyama, G.; Sakamoto, H.; Matsuda, R.; Noro, S.; Kitagawa, S. Immobilization of a metallo Schiff base into a microporous coordination polymer Angew. Chem., Int. Ed. 2004, 43, 2684-2687
49. 2 {bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)} Inorg. Chem. 2004, 43, 8209-8211
50. Cho, S.-H.; Ma, B.; Nguyen, S. T.; Hupp, J. T.; Albrecht-Schmitt, T. E. A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation Chem. Commun. 2006, 2563-2565
51. Sakamoto, H.; Matsuda, R.; Bureekaew, S.; Tanaka, D.; Kitagawa, S. A porous coordination polymer with accessible metal sites and its complementary coordination action Chem.-Eur. J. 2009, 15, 4985-4989
52. Xie, Z.; Ma, L.; de Krafft, K. E.; Jin, A.; Lin, W. Porous phosphorescent coordination polymers for oxygen sensing J. Am. Chem. Soc. 2010, 132, 922-923
53. 2 confined in metal-organic framework pores J. Am. Chem. Soc. 2008, 130, 6411-6423
54. 4 by fixed-bed adsorption J. Phys. Chem. C 2008, 112, 1575-1581
55. Bárcia, P. S.; Zapata, F.; Silva, J. A. C.; Rodrigues, A. E.; Chen, B. Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework J. Phys. Chem. B 2007, 111, 6101-6103
56. Lin, W.; Rieter, J. W.; Taylor, K. M. L. Modular synthesis of functional nanoscale coordination polymers Angew. Chem., Int. Ed. 2009, 48, 650-658
57. Thomas, K. M. Adsorption and desorption of hydrogen on metal-organic framework materials for storage applications: comparison with other nanoporous materials Dalton Trans. 2009, 1487-1505