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note
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Conformation of the radical intermediate generated from 1b is confirmed to be independent of the configuration at the bromide carbon. That is, the reaction with stereochemically pure 1b prepared from (S)-α-bromoisovaleric acid gave the same diastereomer ratio of 31% de (54% yield) as those with the diastereomeric mixture, and thus, chirality in 1b is not transferred to 2b.
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