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Volumn 12, Issue 16, 2010, Pages 3626-3629

Stereocontrol in radical cyclization: Change in rate-determining step

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EID: 77955671975     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol101370x     Document Type: Article
Times cited : (4)

References (34)
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  • 2
    • 78149354516 scopus 로고    scopus 로고
    • Gans̈auer, A., Ed. Springer: Verlag
    • Gans̈auer, A., Ed. Radicals in Synthesis; Springer: Verlag, 2006; I and II.
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    • Gansäuer, A., Ed.; Springer: Verlag
    • Zimmerman, J.; Sibi, M. P. Radicals in Synthesis; Gansäuer, A., Ed.; Springer: Verlag, 2006; I, pp 107 -162.
    • (2006) Radicals in Synthesis , vol.1 , pp. 107-162
    • Zimmerman, J.1    Sibi, M.P.2
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    • For selected recent examples, see
    • For selected recent examples, see
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    • See also
    • See also Newcomb, M. Tetrahedron 1993, 49, 1151-1176
    • (1993) Tetrahedron , vol.49 , pp. 1151-1176
    • Newcomb, M.1
  • 30
    • 77955699987 scopus 로고    scopus 로고
    • note
    • Conformation of the radical intermediate generated from 1b is confirmed to be independent of the configuration at the bromide carbon. That is, the reaction with stereochemically pure 1b prepared from (S)-α-bromoisovaleric acid gave the same diastereomer ratio of 31% de (54% yield) as those with the diastereomeric mixture, and thus, chirality in 1b is not transferred to 2b.
  • 31
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    • For other conformation-controlled radical reactions, see
    • For other conformation-controlled radical reactions, see


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.