Chitosan-mediated synthesis of mesoporous α-Fe2O 3 nanoparticles and their applications in catalyzing selective oxidation of cyclohexane

Science China Chemistry

Volumn 53, Issue 7, 2010, Pages 1502-1508

  Huang, Changliang ^a,b   Zhang, Hongye ^a,b   Sun, Zhenyu ^a,b   Liu, Zhimin ^a,b  

^a PEKING UNIVERSITY   (China)

^b INSTITUTE OF CHEMISTRY   (China)

Author keywords

Fe2O3; chitosan; cyclohexane; mesoporous nanoparticles; oxidation

Indexed keywords

CYCLOHEXANE OXIDATION; CYCLOHEXANOL; CYCLOHEXANONES; FOURIER TRANSFORM INFRARED; HEMATITE NANOPARTICLES; HIGH SELECTIVITY; HYBRID NANOPARTICLE; MESOPOROUS; MESOPOROUS NANOPARTICLE; MESOPOROUS NANOPARTICLES; METAL OXIDES; NANO-CATALYST; PD NANO PARTICLE; PH VALUE; POROUS IRON; POROUS STRUCTURES; REACTION SOLUTIONS; SELECTIVE OXIDATION; THERMAL GRAVIMETRIC ANALYSIS;

CALCINATION; CHITIN; CHITOSAN; CYCLOHEXANE; FOURIER TRANSFORMS; IRON ORES; IRON OXIDES; NANOPARTICLES; OXIDATION; OXIDE MINERALS; PALLADIUM; SCANNING ELECTRON MICROSCOPY; SORPTION; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; WAVELET TRANSFORMS; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS;

GOLD;

EID: 77955542337     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-010-4004-1     Document Type: Article

References (26)

1. S.C. Warren L.C. Messina L.S. Slaughter M. Kamperman Q. Zhou S.M. Gruner F.J. DiSalvo U. Wiesner 2008 Ordered mesoporous materials from metal nanoparticle-block copolymer self-assembly Science 320 1748 1752 10.1126/science.1159950 (Pubitemid 351931284)
2. M. Poliakoff J.M. Fitzpatrick T.R. Farren P.T. Anastas 2002 Green chemistry: science and politics of change Science 297 807 810 10.1126/science.297.5582.807 (Pubitemid 34839624)
3. F. Schuth 2003 Endo- and exotemplating to create high-surface-area inorganic materials Angew Chem Int Ed 42 3604 3622 10.1002/anie.200300593 (Pubitemid 37010642)
4. 3 nanotubes in gas sensor and lithium-ion battery applications Adv Mater 17 582 585 10.1002/adma.200401101 (Pubitemid 40448711)
5. Z.C. Wu K. Yu S.D. Zhang 2008 Hematite hollow spheres with a mesoporous shell: controlled synthesis and applications in gas sensor and lithium ion batteries J Phys Chem C 112 11307 11313 10.1021/jp803582d
6. S.Y. Zeng K.B. Tang T.W. Li 2008 Facile route for the fabrication of porous hematite nanoflowers: Its synthesis, growth mechanism, application in the lithium ion battery, and magnetic and photocatalytic properties J Phys Chem C 112 4836 4843 10.1021/jp0768773
7. 4 nanowires by a vapor-solid process Adv Funct Mater 16 2243 2251 10.1002/adfm.200600499 (Pubitemid 44759508)
8. 3 nanobelts and nanowires J Phys Chem B 109 215 220 10.1021/jp0461448 (Pubitemid 40120967)
9. 3 nanotubes and nanorods with shape-dependent magnetic properties J Phys Chem B 110 15218 15223 10.1021/jp0627473 (Pubitemid 44318489)
10. J.H. Bang K.S. Suslick 2007 Sonochemical synthesis of nanosized hollow hematite J Am Chem Soc 129 2242 2243 10.1021/ja0676657 (Pubitemid 46362533)
11. X.L. Gou G.X. Wang J. Park 2008 Monodisperse hematite porous nanospheres: Synthesis, characterization, and applications for gas sensors Nanotechnology 19 125606 10.1088/0957-4484/19/12/125606 (Pubitemid 351588270)
12. 3 nanotubes fabricated using carbon nanotube templates Adv Mater 17 2993 2997 10.1002/adma.200501562 (Pubitemid 43026706)
13. 3 with crystalline walls J Am Chem Soc 128 5468 5474 10.1021/ja0584774
14. 3 nanorods and their application in ethanol sensors J Phys Chem C 112 17804 17808 10.1021/jp806430f
15. X.L. Gou G.X. Wang X.Y. Kong 2008 Flutelike porous hematite nanorods and branched nanostructures: Synthesis, characterisation and application for gas-sensing Chem Eur J 14 5996 6002 10.1002/chem.200701705
16. 3 and its application as absorbents J Phys Chem C 112 13378 13382 10.1021/jp8044466
17. 3 J Alloys Comp 425 384 389 10.1016/j.jallcom.2006.01.066 (Pubitemid 44666370)
18. J.A. Dahl B.L.S. Maddux J.E. Hutchison 2007 Toward greener nanosynthesis Chem Rev 107 2228 2269 10.1021/cr050943k (Pubitemid 47029093)
19. K. Ogawa K. Oka T. Yui 1993 X-ray study of chitosan-transition metal complexes Chem Mater 5 726 728 10.1021/cm00029a026
20. F. Quignard A. Choplin A. Domard 2000 Chitosan: A natural polymeric support of catalysts for the synthesis of fine chemicals Langmuir 16 9106 9108 10.1021/la000937d (Pubitemid 32032870)
21. M. Bengisu E. Yilmaz 2002 Oxidation and pyrolysis of chitosan as a route for carbon fiber derivation Carbohydr Polymer 50 165 175 10.1016/S0144-8617(02) 00018-8 (Pubitemid 34661465)
22. 3 substrates Adv Mater 18 3261 3265 10.1002/adma.200502772 (Pubitemid 46080224)
23. W.B. Tan Y. Zhang 2005 Multifunctional quantum-dot-based magnetic chitosan nanotubes Adv Mater 17 2375 2279 10.1002/adma.200401650 (Pubitemid 41454645)
24. S.R. Hall 2006 Biomimetic synthesis of high-Tc, type-II superconductor nanowires Adv Mater 18 487 490 10.1002/adma.200501971
25. Cornell RM, Schwermann U. The iron oxide structure, properties, reactions, occurrence and uses. VCH: Weinheim, 1996
26. X.H. Chang D.R. Chen X.L. Jiao 2008 Chitosan-based aerogels with high adsorption performance J Phys Chem B 112 7721 7725 10.1021/jp8011359