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47
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77955242910
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We thank Wyatt Technology Inc. of Santa Barbara, CA, for a generous loan of this equipment to the Instituto Universitario de Catálisis Homogénea.
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We thank Wyatt Technology Inc. of Santa Barbara, CA, for a generous loan of this equipment to the Instituto Universitario de Catálisis Homogénea.
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48
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24944584172
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For degradation of PPA in solution and the bulk state see
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For degradation of PPA in solution and the bulk state see: Percec, V.; Rudick, J. G. Macromolecules 2005, 38, 7241-7250
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See:;;, and references therein
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See: Podzimek, S.; Vlcek, T.; Johann, C. J. Appl. Polym. Sci. 2001, 81, 1588-1594 and references therein
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Podzimek, S.1
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0033719510
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It should be noted that the slope of the linear portions of these conformation plots varied between 0.55 and 0.65 in THF solution. Normally, one would expect a slope of ca. 0.58 for a linear polymer in a good solvent. We suspect the variation reflects the complexity of PPA behavior seen in dilute solution where both mass and size can be time and solvent dependent, reflecting s-trans to s-cis isomerization accompanied by changes to solvent-polymer and polymer-polymer interactions. See
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It should be noted that the slope of the linear portions of these conformation plots varied between 0.55 and 0.65 in THF solution. Normally, one would expect a slope of ca. 0.58 for a linear polymer in a good solvent. We suspect the variation reflects the complexity of PPA behavior seen in dilute solution where both mass and size can be time and solvent dependent, reflecting s-trans to s-cis isomerization accompanied by changes to solvent-polymer and polymer-polymer interactions. See: Cametti, C.; Codastefano, P.; D'Amato, R.; Furlani, A.; Russo, M. V. Synth. Met. 2000, 114, 173-179
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51
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77955254744
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Since the MALS detector signal is divided by the signal from the DRI detector to produce a signal proportional to molar mass, large and systematic errors can be expected whenever the former signal is nonzero and the latter signal very close to zero and/or dominated by noise.
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Since the MALS detector signal is divided by the signal from the DRI detector to produce a signal proportional to molar mass, large and systematic errors can be expected whenever the former signal is nonzero and the latter signal very close to zero and/or dominated by noise.
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52
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77955235447
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The origins of these bimodal MMD are not known. Evidently, there are two species that independently propagate, but since the relative amounts did not obviously correlate with the experimental conditions (solvent, T, or presence of water), it is a matter of speculation as to what the two species may be.
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The origins of these bimodal MMD are not known. Evidently, there are two species that independently propagate, but since the relative amounts did not obviously correlate with the experimental conditions (solvent, T, or presence of water), it is a matter of speculation as to what the two species may be.
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See Supporting Information for details
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