Living polymerization of phenylacetylene with tetrafluorobenzobarrelene ligand-containing rhodium catalyst systems featuring the synthesis of high molecular weight polymer

Macromolecules

Volumn 39, Issue 25, 2006, Pages 8567-8573

  Saeed, Irfan ^a   Shiotsuki, Masashi ^a   Masuda, Toshio ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; LIVING POLYMERIZATION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; MOLECULAR WEIGHT DISTRIBUTION; SYNTHESIS (CHEMICAL); TERNARY SYSTEMS;

LIVING POLYMERIZATION CATALYSTS; MOLECULAR WEIGHT POLYMERS; MULTISTAGE POLYMERIZATION; PHENYLACETYLENE;

ACETYLENE;

EID: 33846140146     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma062075e     Document Type: Article

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76. 18b
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79. p) probably due to different steric environments in the initiating and propagating species. The trisubstituted vinylrhodium moiety in the initiating species is sterically more demanding than the disubstituted vinylrhodium moiety in the propagating species. Hence, coordination of PA to the propagating species should be more facile than to the initiating species, causing broadening of MWD in the initial stage of polymerization (see Chart 2).
80. n and polymer yield was far from linear ruling out the possibility of living polymerization. Monomer 3c afforded polymer only in low yield (≤20%) with bimodal GPC curve, suggesting a nonliving polymerization.