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Volumn 34, Issue 8, 2010, Pages 1774-1782

Reduction of base-stabilized difluoroboranes to induce rearrangement reactions

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; DIFLUOROBORANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 77955084203     PISSN: 11440546     EISSN: 13699261     Source Type: Journal    
DOI: 10.1039/c0nj00363h     Document Type: Article
Times cited : (14)

References (93)
  • 88
    • 0011419664 scopus 로고
    • There is another possibility for a mechanism involving the formation of borylene 11 by reduction. A subsequent hydrogen abstraction from its resonance form, biradical 12, could afford diaminoborylradical species 9. However, the borylene mechanism can be ruled out based on the formation of dimeric compound 6.There is another possibility for an initial elimination of alkoxide from intermediate 8, followed by the nucleophilic attack of alkoxide towards the B-F moiety to form intermediate 10.
    • G. Leroy M. Sana C. Wilante Theor. Chim. Acta 1993 85 155 166
    • (1993) Theor. Chim. Acta , vol.85 , pp. 155-166
    • Leroy, G.1    Sana, M.2    Wilante, C.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.