Reducing the print-through phenomenon and increasing the curing degree of UP/ST/organo-montmorillonite nanocomposites

Applied Clay Science

Volumn 49, Issue 3, 2010, Pages 224-228

  Tsai, Tsung Yen ^a   Kuo, Chien Hung ^a   Chen, Wen Chi ^a   Hsu, Chia Hao ^b   Chung, Cheng Hsien ^b  

^a CHUNG YUAN CHRISTIAN UNIVERSITY   (Taiwan)

^b United Ship Design and Development Center Taipei   (Taiwan)

Author keywords

Montmorillonite; Nanocomposite; Print through phenomenon; Unsaturated polyester

Indexed keywords

BIFUNCTIONAL MATERIALS; CURING DEGREE; DENSITY MEASUREMENTS; DIMENSION STABILITY; FLAME-RESISTANT; GLASS FIBER COMPOSITES; INJECTION METHOD; LOW PROFILE ADDITIVES; MATRIX; MONTMORILLONITE NANOCOMPOSITES; ORGANO-MONTMORILLONITE; TEM; THERMAL CONTRACTION; UNSATURATED POLYESTER; UNSATURATED POLYESTER RESIN; VINYL ESTERS; VOLUME SHRINKAGE; WIDE-ANGLE X-RAY DIFFRACTION;

CLAY MINERALS; CURING; DIMENSIONAL STABILITY; ESTERS; FREE RADICAL POLYMERIZATION; GLASS FIBERS; NANOCOMPOSITES; POLYESTER RESINS; RESINS; SCANNING ELECTRON MICROSCOPY; SHIPS; SHRINKAGE; SILICATE MINERALS; STYRENE; TRANSMISSION ELECTRON MICROSCOPY; VINYL RESINS; X RAY DIFFRACTION; YACHTS;

UNSATURATED POLYMERS;

COMPOSITE; ESTER; EXPERIMENTAL MINERALOGY; MATRIX; MONTMORILLONITE; ORGANOCLAY; POLYMERIZATION; RESIN; SHRINKAGE; TRANSMISSION ELECTRON MICROSCOPY; VOLUME; X-RAY DIFFRACTION;

EID: 77955049013     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2010.05.010     Document Type: Article

References (24)

1. Chekanov Y.A.*., Korotkov V.N., Rozenberg B.A., Dhzavadyan E.A., Bogdanova L.M. Cure shrinkage defects in epoxy resins. Polymer 1995, 36:2013-2017.
2. Fischbein R.A. Method for the determination of the cure shrinkage of epoxy formulations. J. Sci. Instrum. 1966, 43:480-487.
3. Fong H., Liu W., Wang C.S., Vaia R.A. Generation of electrospun fibers of nylon 6 and nylon 6-montmorillonite nanocomposite. Polymer 2001, 43:775-780.
4. Giannelis E. Polymer layered silicate nanocomposites. Adv. Mater. 1996, 8:29-35.
5. Kornmann X., Lindberg H., Berglund L.A. Synthesis of epoxy-clay nanocomposites. Influence of the nature of the curing agent on structure. Polymer 2001, 42:4493-4499.
6. Lan T., Kaviratna P.D., Pinnavaia T.J. On the nature of polyimide-clay hybrid composites. Chem. Mater. 1994, 6:573-575.
7. Lan T., Wang Z., Shi H., Pinnavaia T.J. Clay-epoxy nanocomposites: relationships between reinforcement properties and the extent of clay layer exfoliation. Polym. Mater. Sci. Eng. 1995, 73:296-297.
8. Nguyen Q.T., Baird D.G. Preparation of polymer-clay nanocomposites and their properties. Adv. Polym. Technol. 2006, 25:270-285.
9. Novak B.M. Hybrid nanocomposite materials-between inorganic glasses and organic polymers. Adv. Mater. 1993, 5:422-433.
10. Pinnavaia T.J., Lan T., Wang Z., Shi H., Kaviratna P.D. Nanotechnology molecularly designed materials. ACS Symposium Series 1996, 622:250. Washington DC. G.M. Chow, K.E. Gonsalves (Eds.).
11. Theng B.K.G. Formation and properties of clay-polymer complexes. Soil Sci. 1979, 9:362-368.
12. Tsai T.Y., Li C.H., Chang C.H., Cheng W.H., Hwang C.L., Wu R.J. Preparation of exfoliated polyester/clay nanocomposites. Adv. Mater. 2005, 17:1769-1773.
13. Tsai T.Y., Lu S.T. The properties and application of epoxy/clay nanocomposites in the copper-clad laminar. Clay Sci. 2005, 12:74-78.
14. Tsai T.Y., Lu S.T., Huang C.J., Liu J.X., Li C.H. The preparation and characterization of a novolac cured epoxy-clay nanocomposites. Mater. Res. Soc. Symp. Proc. 2006, 939E.
15. Tsai T.Y., Lu S.T., Huang C.J., Liu J.X., Li C.H., Chen L.C., Ray U.S. The structure-property relationship of novolac cured epoxy resin/clay nanocomposites. Polym. Eng. Sci. 2008, 48:467-476.
16. Tsai T.Y., Lu S.T., Li C.H., Huang C.J., Liu J.X., Chen L.C. Effect of bifunctional modifiers of the clay on the morphology of novolac cured epoxy resin/clay nanocomposites. Chem. Polym. Compos. 2008, 29:1098-1105.
17. Tsai T.Y., Lu S.W., Li F.S. Preparation and characterization of epoxy/layered double hydroxides nanocomposites. J. Phys. Chem. Solids 2008, 69:1386-1390.
18. Tsai T.Y. Book: polymer-clay nanocomposites 2000, 173-189. John Wiley & Sons Ltd, New York. T.J. Pinnavaia, G.W. Beall (Eds.).
19. Tsai T.Y., Wu Y.J., Hsu F.J. Synthesis and properties of epoxy/layered zzirconium phosphonate (Zr-P) nanocomposites. J. Phys. Chem. Solids 2008, 69:1379-1382.
20. Utracki L.A., Sepehr M., Boccaleri E. Synthetic, layered nanoparticles for polymeric nanocomposites (PNCs). Polym. Adv. Technol. 2007, 18:1-37.
21. Vaia R.A., Jandt K.D., Kramer E.J., Giannelis E.P. Microstructural evolution of melt intercalated polymer-organically modified layered silicates. Nano. Chem. Mater. 1996, 8:2628-2635.
22. Wang W.S., Chen H.S., Wu Y.W., Tsai T.Y., Chen-Yang Y.W. Properties of novel epoxy/clay nanocomposites prepared with a reactive phosphorus-containing organoclay. Polymer 2008, 49:4826-4836.
23. Wang Z., Massam J., Pinnavaia T.J. Polymer-clay nanocomposites 2000, 127-133. John Wiley & Sons Ltd, New York. T.J. Pinnavaia, G.W. Beall (Eds.).
24. Zhiqiang Z., Bangkun J., Pingsheng H. Copolymerization behavior and kinetics of an epoxy copolymer with zero shrinkage. J. Appl. Polym. Sci. 2002, 84:1457-1464.