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Volumn 352, Issue 10, 2010, Pages 1625-1629

Supported sulfonic acid as green and efficient catalyst for Baeyer-Villiger oxidation with 30% aqueous hydrogen peroxide

Author keywords

1,1,1,3,3,3 hexafluoro 2 propanol; Baeyer Villiger oxidation; Hydrogen peroxide; Lactones; Supported catalysts

Indexed keywords


EID: 77954767482     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000076     Document Type: Article
Times cited : (18)

References (34)
  • 3
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  • 8
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    • Eds.: L. A. Paquette et al. Wiley & Sons, New York
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    • (1993) Organic Reactions , pp. 251-798
    • Krow, G.R.1
  • 12
    • 77954807414 scopus 로고    scopus 로고
    • 2 has been removed from the commercial market because of the possible dangers involved in transport and handling
    • 2 has been removed from the commercial market because of the possible dangers involved in transport and handling.
  • 18
    • 77954812223 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2002, 47, 4481-4484.
    • (2002) Angew. Chem. Int. Ed. , vol.47 , pp. 4481-4484
  • 31
    • 77954793058 scopus 로고    scopus 로고
    • This results in a lowering of the conversion rate of intermediate 2a into product 3a. Indeed by performing the model reaction with the sol-gel catalyst and Amberlyst-15 for 6 h, product 3a can be obtained in 68 and 66% yields, respectively. In addition, by using a lower amount of Amberlyst-15 (2 mg), the corresponding product was isolated in lower yield (31%) but with the same modest selectivity (46%)
    • This results in a lowering of the conversion rate of intermediate 2a into product 3a. Indeed by performing the model reaction with the sol-gel catalyst and Amberlyst-15 for 6 h, product 3a can be obtained in 68 and 66% yields, respectively. In addition, by using a lower amount of Amberlyst-15 (2 mg), the corresponding product was isolated in lower yield (31%) but with the same modest selectivity (46%).
  • 32
    • 77954808206 scopus 로고    scopus 로고
    • [9])
    • [9]).
  • 34
    • 84952935272 scopus 로고    scopus 로고
    • It has been reported that this reaction showed poor selectivity when performed under homogeneous condition with meta-chloroperbenzoic acid: Wiley-VCH, Weinheim, However, it is important to underline that the model reagent 5 shows a marked preference for the BV oxidation
    • It has been reported that this reaction showed poor selectivity when performed under homogeneous condition with meta-chloroperbenzoic acid: D. R. Kelly, P. W. H. Wan, J. Tang, in: Biotechnology, Wiley-VCH, Weinheim, 1998, 8a, pp 535-587. However, it is important to underline that the model reagent 5 shows a marked preference for the BV oxidation.
    • (1998) Biotechnology , vol.8 A , pp. 535-587
    • Kelly, D.R.1    Wan, P.W.H.2    Tang, J.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.