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This results in a lowering of the conversion rate of intermediate 2a into product 3a. Indeed by performing the model reaction with the sol-gel catalyst and Amberlyst-15 for 6 h, product 3a can be obtained in 68 and 66% yields, respectively. In addition, by using a lower amount of Amberlyst-15 (2 mg), the corresponding product was isolated in lower yield (31%) but with the same modest selectivity (46%)
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This results in a lowering of the conversion rate of intermediate 2a into product 3a. Indeed by performing the model reaction with the sol-gel catalyst and Amberlyst-15 for 6 h, product 3a can be obtained in 68 and 66% yields, respectively. In addition, by using a lower amount of Amberlyst-15 (2 mg), the corresponding product was isolated in lower yield (31%) but with the same modest selectivity (46%).
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[9])
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[9]).
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It has been reported that this reaction showed poor selectivity when performed under homogeneous condition with meta-chloroperbenzoic acid: Wiley-VCH, Weinheim, However, it is important to underline that the model reagent 5 shows a marked preference for the BV oxidation
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