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1
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The addition was first discovered by Hantzsch, Komnenos, Crismer and Claisen. Later on, it was summarized by Michael, in 1.887: a) T. Purdie, Ber. Dtsch. Chem. Ges. 1881, 14, 2238-2286;
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77954726394
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For Michael addition reactions catalyzed by nucleophilic phosphane Lewis base, see: D. Bhuniya, S. Mohan, S. Narayanan, Synthesis 2003, 1018-1024.
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Phosphane-catalyzed hydration and hydroalkoxylation of activated olefins have been reported: a) I. C Stewart, R. G. Bergman, F. D. Toste, J. Am. Chem. Soc. 2003, 125, 8696-8697 and references cited therein;
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for some representative reviews in nitrogen-containing base-catalyzed Michael addition reactions, see: d) A. Alexakis, S. Sulzer-Mossé, Chem. Commun. 2007, 3123-3135;
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[6g] and the references cited therein
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[6s] and the references cited therein
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77954739872
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