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max = 0.8638/0.9018). X-ray data collection was carried out using a Bruker APEX II diffractometer with a CCD area detector. The structure was solved by direct methods and refined with the full-matrix least-squares technique using the SHELXS-97 and SHELXL-97 programs. All nonhydrogen atoms were treated anisotropically. C-bound H atoms of the ligands were placed geometrically refined as riding atoms. In 2, the lattice water molecule (O(1)), the tail of one azide anions (N18 - N19 - N20) and one of the methylene group (C47) of bpp are site occupancy disordered and varied between two positions with the occupancy that refined to 0.622 and 0.378 for N19, N20 and N19' and N20', 0.524 and 0.476 for C47 and C47', respectively. No attempts have been performed to locate hydrogen atoms of the splitting water molecules.
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