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Volumn 13, Issue 6, 2010, Pages 733-736

A cadmium(II)- and a nickel(II)-polymer with azide and 1,3-bis(4-pyridyl) propane ligands showing neutral pentanuclear cluster-based 3D MOF and self-interpenetrated 2D undulated layer

Author keywords

1,3 bis(pyridyl) propane; Metal organic framework; Neutral pentanuclear cluster; Secondary building units; Two fold interpenetration

Indexed keywords


EID: 77954213193     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2010.03.033     Document Type: Article
Times cited : (24)

References (54)
  • 30
    • 77954214234 scopus 로고    scopus 로고
    • note
    • -1): 3450(s), 2925(m), 2036(vs), 1613(vs), 1558(w), 1500(w), 1423(m), 1337(w), 1221(m), 1068(w), 1018(w), 849(w), 809(m), 760(w), 613(w), 559(w), 518(m).
  • 37
    • 77954218273 scopus 로고    scopus 로고
    • note
    • max = 0.8638/0.9018). X-ray data collection was carried out using a Bruker APEX II diffractometer with a CCD area detector. The structure was solved by direct methods and refined with the full-matrix least-squares technique using the SHELXS-97 and SHELXL-97 programs. All nonhydrogen atoms were treated anisotropically. C-bound H atoms of the ligands were placed geometrically refined as riding atoms. In 2, the lattice water molecule (O(1)), the tail of one azide anions (N18 - N19 - N20) and one of the methylene group (C47) of bpp are site occupancy disordered and varied between two positions with the occupancy that refined to 0.622 and 0.378 for N19, N20 and N19' and N20', 0.524 and 0.476 for C47 and C47', respectively. No attempts have been performed to locate hydrogen atoms of the splitting water molecules.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.