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Volumn 6, Issue 12, 2006, Pages 2637-2639

A NaCl-like metal-organic framework constructed by unprecedented tetrahedral Cd4O6 and Cd5O6 units

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EID: 33846181321     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg060408t     Document Type: Article
Times cited : (49)

References (39)
  • 27
    • 33846164518 scopus 로고    scopus 로고
    • -1): 3440s, 3368s, 3130s, 2455w, 1669s, 1621s, 1478m, 1391s, 1288w, 1248w, 1129s, 1081s, 1002s, 963s, 867s, 812m, 669m, 613m, 542m.
    • -1): 3440s, 3368s, 3130s, 2455w, 1669s, 1621s, 1478m, 1391s, 1288w, 1248w, 1129s, 1081s, 1002s, 963s, 867s, 812m, 669m, 613m, 542m.
  • 28
    • 33846158557 scopus 로고    scopus 로고
    • Crystal data for 1 C26.67H5.33Cd9N 10.67O25.33S: cubic, space group F43m, Mr, 1924.08, a, 20.3386(4) Å, V, 8413.2(3) Å3, Z, 4, Dc, 1.519 g cm-3, μ, 2.306 mm-1, F(000, 3563, Tmin, 0.5964, Tmax, 0. 6191, 2θmax, 54°, S, 1.207, R1, 0.0493, wR2, 0.1343. Data were collected on a Bruker SMART APEX CCD diffractometer at 298(2) K using Mo Kα radiation λ, 0.71073 Å, The program SAINT was used for integration of the diffraction profiles. The structure was solved by direct methods using the SHELXS program of the SHELXTL package and refined by full-matrix least-squares methods with SHELXL.17 The hydrogen atoms of ligands were generated theoretically onto the specific atoms and refined is
    • 17 The hydrogen atoms of ligands were generated theoretically onto the specific atoms and refined isotropically with fixed thermal factors. The DMF solvent molecules in 1 could not be located in the Fourier map, but their presence was deduced by means of elemental analysis and TGA. It should be noted that the split of site occupancy was performed due to the dual disorder of dcbi group. The correctness of the space group was checked using PLATON. We attempted to solve the structure in a lower symmetry space group to obtain an ordered structure, but we were unsuccessful.
  • 39
    • 33846136509 scopus 로고    scopus 로고
    • Sheldrick, G. M. SHELXTL, Crystallographic Software Package, SHELXTL, Version 5.1; Bruker-AXS, Madison, WI, 1998
    • Sheldrick, G. M. SHELXTL, Crystallographic Software Package, SHELXTL, Version 5.1; Bruker-AXS, Madison, WI, 1998.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.