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-1): 3440s, 3368s, 3130s, 2455w, 1669s, 1621s, 1478m, 1391s, 1288w, 1248w, 1129s, 1081s, 1002s, 963s, 867s, 812m, 669m, 613m, 542m.
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-1): 3440s, 3368s, 3130s, 2455w, 1669s, 1621s, 1478m, 1391s, 1288w, 1248w, 1129s, 1081s, 1002s, 963s, 867s, 812m, 669m, 613m, 542m.
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Crystal data for 1 C26.67H5.33Cd9N 10.67O25.33S: cubic, space group F43m, Mr, 1924.08, a, 20.3386(4) Å, V, 8413.2(3) Å3, Z, 4, Dc, 1.519 g cm-3, μ, 2.306 mm-1, F(000, 3563, Tmin, 0.5964, Tmax, 0. 6191, 2θmax, 54°, S, 1.207, R1, 0.0493, wR2, 0.1343. Data were collected on a Bruker SMART APEX CCD diffractometer at 298(2) K using Mo Kα radiation λ, 0.71073 Å, The program SAINT was used for integration of the diffraction profiles. The structure was solved by direct methods using the SHELXS program of the SHELXTL package and refined by full-matrix least-squares methods with SHELXL.17 The hydrogen atoms of ligands were generated theoretically onto the specific atoms and refined is
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17 The hydrogen atoms of ligands were generated theoretically onto the specific atoms and refined isotropically with fixed thermal factors. The DMF solvent molecules in 1 could not be located in the Fourier map, but their presence was deduced by means of elemental analysis and TGA. It should be noted that the split of site occupancy was performed due to the dual disorder of dcbi group. The correctness of the space group was checked using PLATON. We attempted to solve the structure in a lower symmetry space group to obtain an ordered structure, but we were unsuccessful.
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