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Volumn 48, Issue 14, 2010, Pages 1658-1667

Structure and dynamics of polymer chains in hydrophilic nanocomposites

Author keywords

Clay; Confinement; Dynamics; Glass transition; Hydrophilic polymers; Nanocomposites; Quasielastic neutron scattering

Indexed keywords

BULK POLYMER; CONFINED SYSTEMS; CONFINEMENT; ENHANCED MOBILITY; EQUILIBRIUM STRUCTURES; GLASS TRANSITION TEMPERATURE; HYDROPHILIC POLYMERS; INTERLAYER DISTANCE; MEAN SQUARE DISPLACEMENT; MELT INTERCALATION; POLYMER CHAINS; POLYMER CONTENT; PURE POLYMERS; QUASI ELASTIC NEUTRON SCATTERING; QUASIELASTIC; SODIUM MONTMORILLONITE; SOLUTION MIXING; STRUCTURE AND DYNAMICS; THERMAL-ANNEALING; WAVE VECTOR;

EID: 77953922230     PISSN: 08876266     EISSN: 10990488     Source Type: Journal    
DOI: 10.1002/polb.21974     Document Type: Article
Times cited : (26)

References (82)
  • 2
    • 0032182230 scopus 로고    scopus 로고
    • (a) Sharp, K. G. Adv Mater 1998, 10, 1243-1248;
    • (1998) Adv. Mater , vol.10 , pp. 1243-1248
    • Sharp, K.G.1
  • 34
    • 0141593871 scopus 로고    scopus 로고
    • (a) Li, Y.; Ishida, H. Polymer 2003, 44, 6571-6577;
    • (2003) Polymer , vol.44 , pp. 6571-6577
    • Li, Y.1    Ishida, H.2
  • 40
    • 3242690732 scopus 로고    scopus 로고
    • (a) Arbe, A. Physica B 2004, 350, 178-185;
    • (2004) Physica B , vol.350 , pp. 178-185
    • Arbe, A.1
  • 44
    • 0036590805 scopus 로고    scopus 로고
    • Special Issue on "Properties of Thin Polymer Films"; Reiter, G.; Forrest, J. A., Eds.
    • (b) Special Issue on "Properties of Thin Polymer Films"; Reiter, G.; Forrest, J. A., Eds.; Eur Phys J E 2002, 8, 101-266.
    • (2002) Eur. Phys. J. E , vol.8 , pp. 101-266
  • 46
    • 33748289663 scopus 로고    scopus 로고
    • Special Issue on "Dynamics in Confinement"; Frick, B.; Koza, M.; Zorn, R., Eds.
    • (a) Special Issue on "Dynamics in Confinement"; Frick, B.; Koza, M.; Zorn, R., Eds.; Eur Phys J E 2003, 12, 5-194;
    • (2003) Eur. Phys. J. E , vol.12 , pp. 5-194
  • 60
    • 77953934898 scopus 로고    scopus 로고
    • Southern Clay Products, Inc. Available at:, Accessed on October
    • Southern Clay Products, Inc. Available at: www.scprod.com. Accessed on October 2009.
    • (2009)
  • 62
    • 77953954160 scopus 로고    scopus 로고
    • http://www.ill.fr/YellowBook/IN16/BS-review/index.htm.
  • 65
    • 77953922931 scopus 로고    scopus 로고
    • 2/3, that is, with a 3 instead of a 6, is used for the calculation of the mean square displacement
    • 2/3), that is, with a 3 instead of a 6, is used for the calculation of the mean square displacement.
  • 66
    • 77953936619 scopus 로고    scopus 로고
    • 3, can be used to estimate that ∼20.7 wt % PHEGMA can completely fill the inorganic galleries, in agreement with our experimental data
    • 3), can be used to estimate that ∼20.7 wt % PHEGMA can completely fill the inorganic galleries, in agreement with our experimental data.
  • 69
    • 77953942338 scopus 로고    scopus 로고
    • heat capacity is calculated by dividing the measured heat flow with the heating rate and with the polymer mass. It is noted that, in the nanocomposites, it is only the polymer that undergoes the transition. The contribution of the inorganic material to the heat capacity would be a constant factor that would not influence the step of the glass transition
    • The heat capacity is calculated by dividing the measured heat flow with the heating rate and with the polymer mass. It is noted that, in the nanocomposites, it is only the polymer that undergoes the transition. The contribution of the inorganic material to the heat capacity would be a constant factor that would not influence the step of the glass transition.
  • 80
    • 77953929359 scopus 로고    scopus 로고
    • It is noted that, no attempt has been made to separate any side chain motion from the segmental dynamics. This is because the geometry of the motion of such a bulky side chain is unknown whereas no discontinuity in the temperature or in the wavevector dependence of the segmental motion is observed herein, see ref. 39
    • It is noted that, no attempt has been made to separate any side chain motion from the segmental dynamics. This is because the geometry of the motion of such a bulky side chain is unknown whereas no discontinuity in the temperature or in the wavevector dependence of the segmental motion is observed herein, see ref. 39.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.