Understanding Li-ion battery processes at the atomic- to nano-scale

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 7683, Issue , 2010, Pages

  Sullivan, J P ^a   Huang, J ^a   Shaw, M J ^a   Subramanian, A ^a   Hudak, N ^a   Zhan, Y ^b   Lou, J ^b  

^a SANDIA NATIONAL LABORATORIES   (United States)

^b RICE UNIVERSITY   (United States)

Author keywords

battery characterization; battery diagnostics; energy storage; Li ion battery; MEMS; TEM

Indexed keywords

BATTERY CHARACTERIZATION; BATTERY CYCLING; BATTERY MATERIALS; BATTERY PERFORMANCE; DEGRADATION MECHANISM; DIELECTROPHORESIS; ELECTROCHEMICAL MEASUREMENTS; ELECTRODE CONFIGURATIONS; ELECTRONIC CONDUCTANCE; FLIP CHIP ASSEMBLIES; IN-SITU TEM; IONIC LIQUID ELECTROLYTES; LATTICE DISORDERS; LI-ION BATTERIES; LITHIATION; MICROELECTROMECHANICAL SYSTEMS; NANO SCALE; NEW MATERIAL; PLATFORM CONCEPT; STRUCTURAL CHANGE; TEM; TRANSMISSION ELECTRON MICROSCOPE; VOLATILE ELECTROLYTES;

COST REDUCTION; DEGRADATION; ELECTRIC WIRE; ELECTROLYTES; ELECTROPHORESIS; ENERGY STORAGE; FLYWHEELS; HARVESTING; IONIC LIQUIDS; IONIZATION OF LIQUIDS; IONS; LITHIUM BATTERIES; MANGANESE OXIDE; MICROELECTROMECHANICAL DEVICES; NANOSTRUCTURED MATERIALS; NANOWIRES; TRANSMISSION ELECTRON MICROSCOPY;

ENERGY HARVESTING;

EID: 77953762897     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.849530     Document Type: Conference Paper

References (28)

1. see "USABC Goals for Advanced Batteries for EVs," http://www.uscar.org/guest/article-view.php?articles-id=85.
2. Nagaura, T. and Tozawa, K., "Lithium ion rechargeable battery," Prog. Batteries Solar Cells 9, 209 (1990).
3. Note that the USABC goals for specific energy are for a complete battery pack module, and this would require specific energies per cell probably substantially greater than 150 Wh/kg.
4. Tarascon, J.-M. and Armand, M., "Issues and challenges facing rechargeable lithium batteries," Nature 414, 359 (2001). (Pubitemid 33100023)
5. Arico, S. A., Bruce, P, Scrosati, B., Tarascon, J.-M., and van Schalkwijk, W. "Nanostructured materials for advanced energy conversion and storage devices," Nature Mater. 4, 366 (2005). (Pubitemid 40557887)
6. Aurbach, D., "Surface Films in Lithium-Ion Batteries," in Advances in Lithium-Ion Batteries, pp. 7-77, van Schalkwijk, W. A. and Scrosati, B. eds. (Kluwer Academic, New York, 2002).
7. Aurbach, D., Makovsky, B., Levi, M. D., Levi, E., Schechter, A., Moshkovich, M., and Cohen, Y., J. Power Sources 81-82, 95 (1999).
8. Broussely, M., "Aging mechanisms and calendar-life predictions in lithium-ion batteries," in Advances in Lithium-Ion Batteries, pp. 393-432, van Schalkwijk, W. A. and Scrosati, B. eds. (Kluwer Academic, New York, 2002).
9. Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., and Cui, Y., "High-performance lithium battery anodes using silicon nanowires," Nature Nanotech. 3, 31 (2008).
10. Graetz, J., Ahn, C. C., Yazami, R., and Fultz, B., "Highly reversible lithium storage in nanostructured silicon," Electrochem. Solid-State Lett. 6, A194 (2003).
11. Chung, S.-Y., Bloking, J. T., and Chiang, Y.-M., "Electronically conductive phosphor-olivines as lithium storage electrodes," Nature Mater. 1, 123 (2002).
12. Shao-Horn, Y., "Understanding phase transformations in lithium battery materials by transmission electron microscopy," in Lithium Batteries: Science and Technology, pp. 478-506, Nazri, G.-A. and Pistoia, G. eds. (Springer, New York, 2009).
13. New-generation environmental TEMs permit pressures at the sample up to 10 Torr, for example, see Hoffman, S., Sharma, R., Wirth, C. T., Cervantes-Sodi, F., Ducati, C., Kasama, T., Dunin-Borkowski, R. E., Drucker, J., Bennett, P., and Robertson, J., "Ledge-flow-controlled catalyst interface dynamics during Si nanowire growth," Nature Mater. 7, 372 (2008).
14. Williamson, M. J., Tromp, R. M., Vereecken, P. M., Hull, R., and Ross, F. M., "Dynamic microscopy of nanoscale cluster growth at the solid-liquid interface," Nature Mater. 2, 532 (2003).
15. Ross, F. M., "Growth processes and phase transformations studied by in situ transmission electron microscopy," IBM J. Res. Develop. 44, 489 (2000).
16. Thiberge, S., Nechushtan, A., Sprinzak, D., Gileadi, O., Behar, V., Zik, O., Chowers, Y., Michaeli, S., Schlessinger, J., and Moses, E., "Scanning electron microscopy of cells and tissues under fully hydrated conditions," Proc. Natl. Acad. Sci. 101, 3346 (2004).
17. Liu, K.-L., Wu, C.-C., Huang, Y.-J., Peng, H.-L., Chang, H.-Y., Chang, P., Hsu, L., and Yew, T.-R., "Novel microchip for in situ TEM imaging of living organisms and bio-reactions in aqueous conditions," Lab Chip 8, 1915 (2008).
18. de Jong, N., Peckys, D. B., Kremers, G. J., and Piston, D. W., "Electron microscopy of whole cells in liquid with nanometer resolution," Proc. Natl. Acad. Sci. 106, 2159 (2009).
19. Zheng, H., Smith, R. K., Jun, Y.-W., Kisielowski, C., Dahmen, U., and Alivisatos, A. P., "Observation of single colloidal platinum nanocrystal growth trajectories," Science 324, 1309 (2009).
20. We have used Epotec 310 epoxy.
21. Thackeray, M. M., "Manganese oxides for lithium batteries," Prog. Solid St. Chem. 25, 1 (1997).
22. Huang, J. Y., Chen, S., Ren, Z. F., Wang, Z., Kempa, K., Naughton, M. J., Chen, G., and Dresselhaus, M. S., "Enhanced ductile behavior of tensile-elongated individual double-walled and triple-walled carbon nanotubes at high temperatures," Phys. Rev. Lett. 98, 185501 (2007). (Pubitemid 46693402)
23. Huang, J. et al., to be published.
24. Webber, A. and Blomgren, G. E., "Ionic liquids for lithium ion and related batteries," pp 185-232 in Advances in Lithium-Ion Batteries, van Schalkwijk, W. A. and Scrosati, B. eds. (Kluwer, New York, 2002).
25. Thackeray, M. M., Shao-Horn, Y., Kahaian, A. J., Kepler, K. D., Skinner, E., Vaughey, J. T., and Hackney, S. A., "Structural fatigue in spinel electrodes in high voltage (4 V) Li/LixMn2O4 cells," Electrochem. Solid-State Lett. 1, 7 (1998).
26. 2 single crystal nanowires," J. Am. Chem. Soc. 124, 2880 (2002).
27. 4," J. Power Sources 26, 355 (1989).
28. Goodenough, J. B., in Progress in Solid State Chemistry, Vol. 5, Reiss, H. ed. (Pergamon Press, Oxford, 1971).