Transient inverted metastable iron hydroperoxides in fenton chemistry. A nonenzymatic model for cytochrome P450 hydroxylation

Journal of Organic Chemistry

Volumn 75, Issue 11, 2010, Pages 3705-3714

  Bach, Robert D ^a   Dmitrenko, Olga ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; C-H BOND CLEAVAGE; CYTOCHROME P450; FENTON CHEMISTRY; HYDROCARBON OXIDATION; HYDROGEN ABSTRACTION; HYDROPEROXIDE GROUP; HYDROPEROXIDES; NON-ENZYMATIC; QUANTUM-MECHANICAL CALCULATION; TRANSITION STRUCTURES;

ABSTRACTING; DYES; ELECTRON TRANSITIONS; HYDROCARBONS; HYDROXYLATION; IRON OXIDES; ISOMERIZATION; ISOMERS; OXIDATION; PORPHYRINS; QUANTUM THEORY;

CHEMICAL BONDS;

CYTOCHROME P450; HYDROGEN; HYDROPEROXIDE; IRON HYDROPEROXIDE; PORPHYRIN; RADICAL; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; CHEMICAL MODEL; FENTON REACTION; HYDROXYLATION; ISOMERIZATION; OXIDATION; REACTION ANALYSIS;

CYTOCHROME P-450 ENZYME SYSTEM; FERRIC COMPOUNDS; HYDROGEN PEROXIDE; HYDROXYLATION; IRON; OXIDATION-REDUCTION; PORPHYRINS; QUANTUM THEORY; THERMODYNAMICS;

EID: 77953018833     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1004668     Document Type: Article

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