Accuracy of perturbation theory for nonadiabatic effects in adsorbate-surface dynamics

Journal of Chemical Physics

Volumn 132, Issue 18, 2010, Pages

  Mizielinski, M S ^a,b   Bird, D M ^a  

^a University of Bath   (United Kingdom)

^b MET OFFICE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ARBITRARY ORDER; ELECTRONIC FRICTION; FORCED-OSCILLATOR MODEL; HOLE DISTRIBUTION; METAL SURFACES; NON-ADIABATIC; NON-ADIABATIC EFFECT; NONPERTURBATIVE; PERTURBATION EXPANSIONS; PERTURBATION THEORY; QUANTITATIVE AGREEMENT; SECOND ORDER PERTURBATION; SEMI-QUANTITATIVE; SURFACE DYNAMICS; TIGHT BINDING MODEL;

ADSORBATES; ENERGY DISSIPATION; HOT ELECTRONS; OSCILLATORS (ELECTRONIC); PERTURBATION TECHNIQUES; SURFACE STRUCTURE;

DISTRIBUTION FUNCTIONS;

EID: 77952709379     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3424765     Document Type: Article

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43. We note that this discussion refers only to the initial part of the trajectory of the H atom. As discussed in Ref., the effects of a complete round-trip in the surface potential well are complicated by the repolarization of the atom that should occur. The correct way to handle this repolarization remains an open question.