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Volumn 321, Issue 5893, 2008, Pages 1191-1194

Inverse velocity dependence of vibrationally promoted electron emission from a metal surface

Author keywords

[No Author keywords available]

Indexed keywords

METAL; NITRIC OXIDE;

EID: 50649095898     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1160040     Document Type: Article
Times cited : (65)

References (33)
  • 18
    • 50649113458 scopus 로고    scopus 로고
    • Here, one ML is defined as one-to-one stoichiometric equivalence of Cs to surface Au atoms
    • Here, one ML is defined as one-to-one stoichiometric equivalence of Cs to surface Au atoms.
  • 22
    • 50649092404 scopus 로고    scopus 로고
    • Under our conditions, the work function does not change over this time scale
    • Under our conditions, the work function does not change over this time scale.
  • 27
    • 50649122712 scopus 로고    scopus 로고
    • The quantum yield reported here is larger than previously reported in (16) and (17) due to detector saturation problems in the previous experiment.
    • The quantum yield reported here is larger than previously reported in (16) and (17) due to detector saturation problems in the previous experiment.
  • 28
    • 50649109597 scopus 로고    scopus 로고
    • The energetics for electron transfer to the surface become only more favorable as the molecule approaches the surface
    • The energetics for electron transfer to the surface become only more favorable as the molecule approaches the surface.
  • 29
    • 50649099904 scopus 로고    scopus 로고
    • One may estimate tunneling distances based on principles set forth in (31).
    • One may estimate tunneling distances based on principles set forth in (31).
  • 30
    • 50649105944 scopus 로고    scopus 로고
    • Energetically, the electron can originate from as much as 0.6 eV below the Fermi level, but this does not meaningfully alter the analysis presented here.
    • Energetically, the electron can originate from as much as 0.6 eV below the Fermi level, but this does not meaningfully alter the analysis presented here.
  • 32
    • 50649121371 scopus 로고    scopus 로고
    • Equation 1 is valid only in the limit of negligible depletion of the initial NO(V = 18) population and thus small quantum yield. In the more general case, we must solve the differential equation for the population of NO(V = 18). Equation 1 is then the first term of a Taylor series expansion of the solution.
    • Equation 1 is valid only in the limit of negligible depletion of the initial NO(V = 18) population and thus small quantum yield. In the more general case, we must solve the differential equation for the population of NO(V = 18). Equation 1 is then the first term of a Taylor series expansion of the solution.
  • 33
    • 50649104790 scopus 로고    scopus 로고
    • We gratefully acknowledge financial support from the NSF (grant CHE-0454806) and the Partnership for International Research and Education - for Electron Chemistry and Catalysis at Interfaces (NSF grant OISE-0530268). N.H.N. acknowledges financial support through a Feodor-Lynen fellowship provided by the Alexander von Humboldt Foundation. We thank D. Matsiev for many useful discussions and suggestions and a critical reading of this manuscript.
    • We gratefully acknowledge financial support from the NSF (grant CHE-0454806) and the Partnership for International Research and Education - for Electron Chemistry and Catalysis at Interfaces (NSF grant OISE-0530268). N.H.N. acknowledges financial support through a Feodor-Lynen fellowship provided by the Alexander von Humboldt Foundation. We thank D. Matsiev for many useful discussions and suggestions and a critical reading of this manuscript.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.