A lipophilic, fluorine-free, thermostable, inexpensive, S 4-Symmetric, highly soluble, weakly coordinating, protolabile aluminate

European Journal of Inorganic Chemistry

Volumn , Issue 13, 2010, Pages 1907-1911

  Straub, Bernd F ^a   Wrede, Michael ^a   Schmid, Karin ^a   Rominger, Frank ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Aluminum; Anions; Carbocations; Density functional calculations; Lipophilicity

Indexed keywords

COST EFFECTIVENESS; NEGATIVE IONS; PARAFFINS; SALTS; SINGLE CRYSTALS; SODIUM ALUMINATE; X RAY DIFFRACTION;

CARBOCATIONS; COST EFFECTIVE; DENSITY-FUNCTIONAL CALCULATIONS; EFFECTIVE PROPERTY; EFFECTIVE SYNTHESIS; FLUORINE-FREE; LIPOPHILICITY; SALT EXTRACTION; SYMMETRICS; TETRABUTYLAMMONIUM SALTS;

ALUMINUM;

EID: 77952341491     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201000197     Document Type: Article

References (29)

1. I. Krossing, I. Raabe, Angew. Cham. 2004, 116, 2116-2142
2. Angew. Chem. Int. Ed. 2004, 43, 2066-2090.
3. a) B. T. King, Z. Janousek, B. Grüner, M. Trammell, B. C. Noll, J. Michl, J. Am. Chem. Soc. 1996, 118, 3313-3314;
4. b)B. T. King, B. C. Noll, J. Michl, Collect. Czech. Chem. Commun. 1999, 64, 1001-1012;
5. c) I. Zharov, B. T. King, Z. Havias, A. Pardi, J. Michl, J. Am. Chem. Soc. 2000, 122, 10253-20253.
6. a) M. Hirano, S. Yakabe, H. Chikamori, J. H. Clark, T. Morimoto, J. Chem. Res. S 1998, 770-771.
7. For electrolytic oxidation of phenols to biphenols at borate ester anions, see: b) I. M. Malkowsky, U. Griesbach, H. Pütter, S. R. Waldvogel, Chem. Eur. J. 2006, 7482-7488;
8. c) I. M. Malkowsky, R. Fröhlich, U. Griesbach, H. Pütter, S. R. Waldvogel, Eur. J. lnorg. Chem. 2006, 1690-1697;
9. d) A. Kirste, M. Nieger, I. M. Malkowsky, F. Stecker, A. Fischer, S. R. Waldvogel, Chem. Eur. J. 2009, 15, 2273-2277.
10. a) A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652;
11. b) S. H.Volko, L. WiIk, M. Nusair, Can. J. Phys. 1980, 58, 1200-1211;
12. c) C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785-789;
13. d) P. J. Hay, W R. Wadt, J. Chem. Phys. 1985, 82, 299-310;
14. e)The LACV3P basis set developed by Schrödinger, Inc. is a triple-zeta contraction of the LACVP basis set;
15. f) Jaguar, version 7.6, Schrödinger, LLC, New York, NY, 2009.
16. a) ORTEP-3 for Windows: L. J. Farrugia, J. Appl. Crystallogr. 1997, 30, 565-565;
17. b) POV-Ray version 3.6, www.povray.org.
18. For substituted tetraphenylboride salts in hexanes, see: J. van der Brocke, M. Lutz, H. Kooijman, A. L. Spek, B.-J. Deelman, G. van Koten, Organometallks 2001, 20, 2114-2117.
19. T. J. Barbarich, S. T. Handy, S. M. Miller, O. P. Anderson, P. A. Grieco, S. H. Strauss, Organometallks 1996, 15, 3776-3778.
20. I. Krossing, Chem. Ew. J. 2001, 7, 490-502.
21. For bis(3,6-di-/er/-butylcatecholato)borate ester anions, see: J. Rôder, U. Etelmann, H. Vitze, W. Lerner, M. Wagner WO/ 2009/027541 A2.
22. a) R-O. Löwdin, Phys. Rev. 1955, 97, 1474-1489;
23. b) E. D. Glendening, J. K. Badenhoop, A. E. Reed, J. E. Carpenter, J. A. Bohmann, C. M. Morales, F. Weinhold, NBO 5.0., Theoretical Chemistry Institute, University of Wisconsin, 2001.
24. a) K Koppe, V. Bilir, H.-J. Frohn, H. P. A. G. J. Schrobilgen, Inorg. Chem. 2007, 46, 9425-9437;
25. b) D. Alberti, K.-R. Pörschke, Organometallks 2004, 23, 1459-1460.
26. N.A.Yakelis, R. G. Bergman, Organometallks 2005, 24, 3579-3581.
27. T. Küppers, E. Bernhardt, R. Eujen, H. Willner, CW Lehmann, Angew. Chem. Int. Ed, 2007, 46, 6346-6349.
28. 0C, leading to a brown powder.
29. [3a]