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Crystallographic details for, CH3)3Si][C 2H5CB11F11, 2, C 6H14B11F11Si, Bruker AXS Proteum2, CuKα radiation (λ, 1.54178 Å, T, 100 K, colorless crystals obtained by sublimation at 70°C, monoclinic, space group P21/c (No. 14, a, 7.384(1, b, 25.491(4, c, 10.037(1) Å, β, 110.063(2)°, V, 1774.6(4) Å3, Z, 4, ρcalcd, 1.655 g cm-3, μ(CuKα, 2.131 mm-1, F(000, 872, 16057 observed reflections (3.47° ≤ θ ≤ 64.71°, integration with Proteum2/SAINT (V7.23A, 1997-2005 Bruker Analytical X-ray Systems, structure solution by direct methods and refinement on F2 using 2888 independent reflections 1275 reflections with I > 2 σ
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2 using 2888 independent reflections (1275 reflections with I > 2 σ(I)) with 262 variables and 0 restraints (SHELXS-97). All non-hydrogen atoms were refined anisotropically. R1 = 0.0666 (I > 2 σ(I)).
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21
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34548223752
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Crystallographic details for, CH3)3Si][HCB 11F11, C4H10B11F 11Si, Bruker AXS Proteum2, CuKα radiation (λ, 1.54178 Å, T, 100 K, colorless crystals obtained by sublimation at 85°C, monoclinic, space group P21/c (No. 14, a, 11.923(3, b, 7.611(2, c, 17.945(4) Å, β, 103.487(2)°, V, 1583.6(6) Å3, Z, 4, ρcalcd, 1.737 g cm-3, μ(CuKα, 2.342 mm-1, F(000, 808, 14184 observed reflections (3.81° ≤ 0 ≤ 65.32°, integration with Proteum2/SAINT, structure solution by direct methods and refinement on F2 using 2658 independent reflections (960 reflections with I > 2 σ(I, with 249 variables and 0 restraints SHELXS-97, All non-hydrogen atoms w
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2 using 2658 independent reflections (960 reflections with I > 2 σ(I)) with 249 variables and 0 restraints (SHELXS-97). All non-hydrogen atoms were refined anisotropically R1 = 0.0726 (I > 2 σ(I)). CCDC 638665 (2) and CCDC 638666 (1) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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