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Volumn 46, Issue 33, 2007, Pages 6346-6349

[Me3Si][R-CB11F11] - Synthesis and properties

Author keywords

Boron cluster; Carboranes; Crystal structure; Ionic liquids; Silyl cations

Indexed keywords

BORON; CRYSTAL STRUCTURE; IONIC LIQUIDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SALTS; STABILIZATION;

EID: 34548280245     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200701136     Document Type: Article
Times cited : (103)

References (27)
  • 5
    • 34548225544 scopus 로고    scopus 로고
    • S. H. Strauss, S. V. Ivanov Colorado State University Research Foundation, Fort Collins, CO, WO 02/36557A2, 2002
    • S. H. Strauss, S. V. Ivanov (Colorado State University Research Foundation, Fort Collins, CO), WO 02/36557A2, 2002.
  • 9
    • 0000034575 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2000, 39, 3772-3789.
    • (2000) Chem. Int. Ed , vol.39 , pp. 3772-3789
    • Angew1
  • 17
    • 34548240248 scopus 로고    scopus 로고
    • Gaussian 03 (Revision B.04), M. J. Frisch et al., see the Supporting Information.
    • Gaussian 03 (Revision B.04), M. J. Frisch et al., see the Supporting Information.
  • 20
    • 34548240858 scopus 로고    scopus 로고
    • Crystallographic details for, CH3)3Si][C 2H5CB11F11, 2, C 6H14B11F11Si, Bruker AXS Proteum2, CuKα radiation (λ, 1.54178 Å, T, 100 K, colorless crystals obtained by sublimation at 70°C, monoclinic, space group P21/c (No. 14, a, 7.384(1, b, 25.491(4, c, 10.037(1) Å, β, 110.063(2)°, V, 1774.6(4) Å3, Z, 4, ρcalcd, 1.655 g cm-3, μ(CuKα, 2.131 mm-1, F(000, 872, 16057 observed reflections (3.47° ≤ θ ≤ 64.71°, integration with Proteum2/SAINT (V7.23A, 1997-2005 Bruker Analytical X-ray Systems, structure solution by direct methods and refinement on F2 using 2888 independent reflections 1275 reflections with I > 2 σ
    • 2 using 2888 independent reflections (1275 reflections with I > 2 σ(I)) with 262 variables and 0 restraints (SHELXS-97). All non-hydrogen atoms were refined anisotropically. R1 = 0.0666 (I > 2 σ(I)).
  • 21
    • 34548223752 scopus 로고    scopus 로고
    • Crystallographic details for, CH3)3Si][HCB 11F11, C4H10B11F 11Si, Bruker AXS Proteum2, CuKα radiation (λ, 1.54178 Å, T, 100 K, colorless crystals obtained by sublimation at 85°C, monoclinic, space group P21/c (No. 14, a, 11.923(3, b, 7.611(2, c, 17.945(4) Å, β, 103.487(2)°, V, 1583.6(6) Å3, Z, 4, ρcalcd, 1.737 g cm-3, μ(CuKα, 2.342 mm-1, F(000, 808, 14184 observed reflections (3.81° ≤ 0 ≤ 65.32°, integration with Proteum2/SAINT, structure solution by direct methods and refinement on F2 using 2658 independent reflections (960 reflections with I > 2 σ(I, with 249 variables and 0 restraints SHELXS-97, All non-hydrogen atoms w
    • 2 using 2658 independent reflections (960 reflections with I > 2 σ(I)) with 249 variables and 0 restraints (SHELXS-97). All non-hydrogen atoms were refined anisotropically R1 = 0.0726 (I > 2 σ(I)). CCDC 638665 (2) and CCDC 638666 (1) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.