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As for the plausible process concerning the generation of iminium ion C, please see the scheme below. The platinum catalyst first coordinated to the nitrogen atom, followed by insertion into the α C-H bond, leading to an iminium ion coordinated to a platinum metal hydride C - (see:;;;;;) The platinum hydride was then oxidized by oxygen to regenerate the platinum catalyst with release of water (see:; Inorg. Chim. Acta 1990, 175, 41)
-
As for the plausible process concerning the generation of iminium ion C, please see the scheme below. The platinum catalyst first coordinated to the nitrogen atom, followed by insertion into the α C-H bond, leading to an iminium ion coordinated to a platinum metal hydride C - (see: Anguille, S.; Brunet, J.-J.; Chu, N.-C.; Diallo, O.; Pages, C.; Vincendeau, S. Organometallics 2006, 25, 2943) The platinum hydride was then oxidized by oxygen to regenerate the platinum catalyst with release of water (see: Chen, L.; Davies, J. A. Inorg. Chim. Acta 1990, 175, 41)
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