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77951671769
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This might play a role in sintering processes. Sintering typically involves small particles, but often they may not be small enough to directly affect the melting behavior due to the "usual" Gibbs-Thompson effect. In powders of heterogeneous composition, for instance, interfacial premelting might induce that one component wets the adjacent particle of the other component even without any curvature effect, leading to some mechanical cohesion between the two particles
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This might play a role in sintering processes. Sintering typically involves small particles, but often they may not be small enough to directly affect the melting behavior due to the "usual" Gibbs-Thompson effect. In powders of heterogeneous composition, for instance, interfacial premelting might induce that one component wets the adjacent particle of the other component even without any curvature effect, leading to some mechanical cohesion between the two particles.
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-3 mol/L leads to a coverage equivalent to one closed monolayer. A closed monolayer means a closed layer with all molecules densely packed (as a solid). In the case of alkanes, in a closed monolayer all the molecules are oriented normal to the interface and the thickness of the monolayer is roughly equal to the all-trans length of the molecules (see ref (13)). The alcohol molecules are tilted in a closed monolayer. Accordingly, the monolayer thickness is somewhat less than the alcohol all-trans length
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-3 mol/L leads to a coverage equivalent to one closed monolayer. A closed monolayer means a closed layer with all molecules densely packed (as a solid). In the case of alkanes, in a closed monolayer all the molecules are oriented normal to the interface and the thickness of the monolayer is roughly equal to the all-trans length of the molecules (see ref (13)). The alcohol molecules are tilted in a closed monolayer. Accordingly, the monolayer thickness is somewhat less than the alcohol all-trans length.
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13244249781
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Knüfing, L. Langmuir 2005, 21, 992-1000
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This is valid even for fractal shaped domains because the fractality breaks down below the micrometer scale. The domain edges are smooth in the submicron range
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This is valid even for fractal shaped domains because the fractality breaks down below the micrometer scale. The domain edges are smooth in the submicron range.
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0001220074
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77951694699
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According to recent X-ray reflectivity and AFM measurements from us, to be published
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According to recent X-ray reflectivity and AFM measurements from us, to be published.
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See movie in Supporting Information
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See movie in Supporting Information.
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77951688565
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For alcohols this relaxation is orders of magnitude slower than for the alkanes. Typically it takes minutes instead of seconds to establish equilibrium
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For alcohols this relaxation is orders of magnitude slower than for the alkanes. Typically it takes minutes instead of seconds to establish equilibrium.
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77951688729
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The term "non-solid" is used here to express the state of the molecules which form the film between the solid domains. The molecules can be in a liquid-like or a gaseous-like state depending on the overall coverage and temperature (see below)
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The term "non-solid" is used here to express the state of the molecules which form the film between the solid domains. The molecules can be in a liquid-like or a gaseous-like state depending on the overall coverage and temperature (see below).
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0000801010
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A 2d gas behavior in this range of coverages has been suggested before already for the alkanes (see ref (1)). However, the data presented here corroborate this assumption quantitatively
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A 2d gas behavior in this range of coverages has been suggested before already for the alkanes (see ref (1)). However, the data presented here corroborate this assumption quantitatively.
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Verdaguer, A.1
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