Curing reaction of o-cresol-formaldehyde epoxy/LC epoxy(p-PEPB)/ anhydride(MeTHPA): Cure kinetics and molecular mechanism

Journal of Thermal Analysis and Calorimetry

Volumn 100, Issue 1, 2010, Pages 225-232

  Gao, Jungang ^a   Zhang, X ^a   Huo, L ^a   Zhao, H ^a  

^a HEBEI UNIVERSITY   (China)

Author keywords

Activation energy; Curing kinetics; Epoxy resins; Liquid crystal; Reaction mechanism

Indexed keywords

APPARENT ACTIVATION ENERGY; COMPONENT SYSTEMS; CURE KINETICS; CURE PROCESS; CURE REACTIONS; CURING AGENTS; CURING KINETICS; CURING REACTIONS; DIFFERENTIAL SCANNING CALORIMETRY METHODS; INITIAL STAGES; ISO-CONVERSIONAL METHOD; KINETIC EQUATIONS; LIQUID-CRYSTALLINE; MOLECULAR MECHANISM; NONISOTHERMAL; O-CRESOL; P-PHENYLENE; PHASE FORMATIONS; REACTION MECHANISM;

ACTIVATION ENERGY; DIFFERENTIAL SCANNING CALORIMETRY; EPOXY RESINS; FORMALDEHYDE; INTEGRAL EQUATIONS; LIQUID CRYSTALS; PHASE SEPARATION; REACTION KINETICS; RESINS;

CURING;

EID: 77951252927     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-009-0629-8     Document Type: Article

References (28)

1. Akira I, Takeaki S, Yoshiji M, Haruhiko F, Hiroshi U. Hardening organic resin composition. Jpn Kokai Tokkyo Koho 2002;2002080727.
2. J López M Rico B Montero J Díez C Ramírez 2009 Polymer blends based on an epoxy-amine thermoset and a thermoplastic: Effect of thermoplastic on cure reaction and thermal stability of the system J Therm Anal Calorim 95 369 376 10.1007/s10973-008-9237-2
3. C Ramírez M Rico L Barral J Díez S García-Garabal B Montero 2007 Organic/inorganic hybrid materials from an epoxy resin cured by an amine silsesquioxane J Therm Anal Calorim 87 69 72 10.1007/s10973-006-7815-8 (Pubitemid 46219048)
4. P Sharma V Choudhary AK Narula 2008 Curing kinetics and thermal stability of diglycidyl ether of bisphenol: Mixture of aromatic imide-amines of benzophenone 3,3′,4,4′-tetra-carboxylic acid dianhydride and 4,4′-diaminodiphenylsulfone J Therm Anal Calorim 91 231 236 10.1007/s10973-006-7749-1 1:CAS:528:DC%2BD1cXhsFansrk%3D (Pubitemid 351199244)
5. M Villanueva JL Martín-Iglesias JA Rodríguez- Añón J Proupín-Castiñeiras 2009 Thermal study of an epoxy system DGEBA (n = 0)/mXDA modified with POSS J Therm Anal Calorim 96 575 582 10.1007/s10973-008-9213-x 1:CAS:528:DC%2BD1MXmsVOrsLs%3D
6. S Jahromi WAG Kuipers B Norder WJ Mijs 1995 Liquid crystalline epoxide thermosets: dynamic mechanical and thermal properties Macromolecules 28 2201 2211 10.1021/ma00111a014 1:CAS:528:DyaK2MXktlektrg%3D
7. CE Hoyle T Watanab J Whitehead 1994 Anisotropic network formation by photopolymerization of liquid crystal monomers in a low magnetic field Macromolecules 27 6581 6588 10.1021/ma00100a050 1:CAS:528:DyaK2cXmtlajtLc%3D
8. S Kurihara K Iwamoto T Nonaka 1998 Preparation and structure of polymer networks by polymerization of liquid crystalline monomers in DC electric field Polymer 39 3565 3569 10.1016/S0032-3861(97)10268-3 1:CAS:528:DyaK1cXjsVyhsbc%3D (Pubitemid 128396624)
9. H Zhao JG Gao YF Li SG Shen 2003 Curing kinetics and thermal property characterization of bisphenol-F epoxy resin and MeTHPA system J Therm Anal Calorim 74 227 236 10.1023/A:1026346323733 1:CAS:528:DC%2BD3sXosVGgtr0%3D
10. D Braun G Frick M Grell M Klimes JH Wendorff 1992 Liquid crystal/liquid-crystalline network composite systems structure formation and electro-optic properties Liq Cryst 11 929 939 10.1080/02678299208030696 1:CAS:528:DyaK38XksFyks7g%3D
11. S Kurihara A Sakamoto T Nonaka 1999 Liquid-crystalline polymer networks: effect of cross-linking on the stability of macroscopic molecular orientation Macromolecules 32 3150 3153 10.1021/ma9819081 1:CAS:528:DyaK1MXit12htLk%3D
12. M Giamberini E Amendola C Carfagna 1995 Liquid crystalline epoxy thermosets Mol Cryst Liq Cryst 266 9 22 10.1080/10587259508033628 1:CAS:528:DyaK2MXoslSrsbk%3D
13. BL Zhang GL Tang KY Shi YC You ZJ Du J Huang 1999 A study on the properties of epoxy resin toughened by a liquid crystal-type oligomer J Appl Polym Sci 71 177 184 10.1002/(SICI)1097-4628(19990103)71:1<177::AID- APP20>3.0.CO;2-P 1:CAS:528:DyaK1cXnslyju70%3D
14. J Bae J Jang SH Yoon 2002 Cure behavior of the liquid-crystalline epoxy/carbon nanotube system and the effect of surface treatment of carbon fillers on cure reaction Macromol Chem Phys 203 2196 3204 10.1002/1521- 3935(200211)203:15<2196::AID-MACP2196>3.0.CO;2-U 1:CAS:528: DC%2BD38Xptlaksb8%3D
15. FX Perrin TH Nguyen JL Vernet 2007 Kinetic analysis of isothermal and nonisothermal epoxy-amine cures by model-free isoconversional methods Macromol Chem Phys 208 718 729 10.1002/macp.200600614 1:CAS:528:DC%2BD2sXkvVeiu70%3D (Pubitemid 47234215)
16. S Vyazovkin N Sbirrazzuoli 1999 Kinetic methods to study isothermal and nonisothermal epoxy-anhydride cure Macromol Chem Phys 200 2294 3303 10.1002/(SICI)1521-3935(19991001)200:10<2294::AID-MACP2294>3.0.CO;2-V 1:CAS:528:DyaK1MXmslCmt78%3D
17. A Atarsia R Boukhili 2000 Relationship between isothermal and dynamic cure of thermosets via the isoconversion representation Polym Eng Sci 40 607 620 10.1002/pen.11191 1:CAS:528:DC%2BD3cXisVSntLg%3D
18. J Málek 1992 The kinetic analysis of non-isothermal data Thermochim Acta 200 257 269 10.1016/0040-6031(92)85118-F
19. J Šesták G Berggren 1971 Study of the kinetics of the mechanism of solid-state reactions at increasing temperatures Thermochim Acta 3 1 12 10.1016/0040-6031(71)85051-7
20. S Jahromi J Lub GN Mol 1994 Synthesis and photoinitiated polymerization of liquid crystalline diepoxides Polymer 35 622 629 10.1016/0032-3861(94)90521-5 1:CAS:528:DyaK2cXhvFagtro%3D
21. XD Liu JG Gao QJ Luo XN Zhang YY Wang 2007 Synthesis and characterization of p-phenylene di-4-(allyloxy) benzoate J Hebei Univ (nature) 27 54 58
22. D Rosu A Mititelu CN Cascaval 2004 Cure kinetics of a liquid-crystalline epoxy resin studied by non-isothermal data Polym Test 23 209 215 10.1016/S0142-9418(03)00082-5 1:CAS:528:DC%2BD3sXovF2rt7w%3D
23. A Catalani MG Bonicelli 2005 Kinetics of the curing reaction of a diglycidyl ether of bisphenol A with a modified polyamine Thermochim Acta 438 126 129 10.1016/j.tca.2005.07.017 1:CAS:528:DC%2BD2MXhtFKhs77K (Pubitemid 41543015)
24. S Vyazoykin A Mititelu N Sbirrazzuoli 2003 Kinetics of epoxy-amine curing accompanied by the formation of liquid crystalline structure Macromol Rapid Commun 24 1060 1065 10.1002/marc.200300023
25. D Rosu CN Cascaval F Mustata C Ciobanu 2002 Cure kinetics of epoxy resins studied by non-isothermal DSC data Thermochim Acta 383 119 127 10.1016/S0040-6031(01)00672-4 1:CAS:528:DC%2BD38XktlOksA%3D%3D
26. G Xu WF Shi SJ Shen 2004 Curing kinetics of epoxy resins with hyperbranched polyesters as toughening agents J Polym Sci Part B Polym Phys 42 2649 2656 10.1002/polb.20143 1:CAS:528:DC%2BD2cXlsFWktrw%3D
27. KC Cole JJ Hechler D Noel 1991 A new approach to modeling the cure kinetics of epoxy/amine thermosetting resins. 2. Application to a typical system based on bis[4-(diglycidylamino)phenyl]methane and bis(4-aminophenyl) sulfone Macromolecules 24 3098 4010 10.1021/ma00011a012 1:CAS:528:DyaK3MXitlSjsL4%3D
28. ZG Ma J Gao 2006 Curing kinetics of o-cresol formaldehyde epoxy resin and succinic anhydride system catalyzed by tertiary amine J Phys Chem B 110 12380 12383 10.1021/jp060243z 1:CAS:528:DC%2BD28XlsFarsL0%3D (Pubitemid 44139422)