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The shell thickness was determined by subtracting the core diameter, estimated according to ref 28, from the core-shell diameter, measured by transmission electron microscopy
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The shell thickness was determined by subtracting the core diameter, estimated according to ref 28, from the core-shell diameter, measured by transmission electron microscopy.
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77951104638
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The differential pulse voltammogram of n -decanethiol, recorded under otherwise identical conditions, shows only an irreversible oxidation at +0.54 V vs Ag/AgCl (3 M KCl). Thus, the peaks (Figure 3) observed for dispersions of the quantum dots cannot be assoiated with free organic ligands present in solution and must be a result of the participation of the inorganic components in the redox proesses
-
The differential pulse voltammogram of n -decanethiol, recorded under otherwise identical conditions, shows only an irreversible oxidation at +0.54 V vs Ag/AgCl (3 M KCl). Thus, the peaks (Figure 3) observed for dispersions of the quantum dots cannot be assoiated with free organic ligands present in solution and must be a result of the participation of the inorganic components in the redox proesses.
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41
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77951115999
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For reports on the voltammetric response of dispersions of CdSe quantum dots, see refs 24 and 27 and the following
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For reports on the voltammetric response of dispersions of CdSe quantum dots, see refs 24 and 27 and the following
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For reports on the voltammetric response of films of CdSe quantum dots, see refs 24 and 25 and the following
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For reports on the voltammetric response of CdSe-ZnSe and CdSe-ZnS core-shell quantum dots, see
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For an investigation on ligand effects on the electrohemical response of CdSe quantum dots, see ref 25.
-
-
-
-
53
-
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0004132708
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-
The free energy changes for the photoinduced electron transfer proesses were estimated with eq (; VCH: New York), using the redox potentials and optical band gap energies reported in Table 2 and a nanoparticle-quencher distance of 1.4 nm. Δ G° = e E Ox - e E Red - Δ E 00 - e 2 4 π ε 0 ε r d
-
The free energy changes for the photoinduced electron transfer proesses were estimated with eq (Kavarnos, G. J. Fundamentals of Photoinduced Electron Transfer; VCH: New York, 1993), using the redox potentials and optical band gap energies reported in Table 2 and a nanoparticle-quencher distance of 1.4 nm. Δ G° = e E Ox - e E Red - Δ E 00 - e 2 4 π ε 0 ε r d
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Fundamentals of Photoinduced Electron Transfer
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Kavarnos, G.J.1
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54
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77951118113
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55
-
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77951123410
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-
note
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C for each complex was approximated to that of I measured at the highest c. I 0 I = 1 + K c k q = I 0 τ 0 I C - 1 τ 0
-
-
-
-
56
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77951129643
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3rd ed. Eds.; CRC Press: Boa Raton, FL,; Chapter 10
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Handbook of Photohemistry, 3rd ed.; Montalti, M.; Credi, A.; Prodi, L.; Gandolfi, M. T., Eds.; CRC Press: Boa Raton, FL, 2006; Chapter 10.
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Montalti, M.1
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